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CaO2 적용에 따른 퇴적물의 P fraction 변화와 수질에 미치는 영향

The Effect of CaO2 Application on the Change of Sedimentary Phosphorus Fraction and Water Quality

  • 김범근 (경상대학교 해양과학대학 해양시스템공학과) ;
  • 모하메드아케트키룰 (경상대학교 해양과학대학 해양시스템공학과) ;
  • 권성현 (경상대학교 해양과학대학 해양환경공학과 공학연구원)
  • Kim, Beom-geun (Department of Ocean system Engineering, College of Marine Science, Gyeongsang National University) ;
  • Khirul, Md Akhte (Department of Ocean system Engineering, College of Marine Science, Gyeongsang National University) ;
  • Kwon, Sung-Hyun (Department of Marine Environmental Engineering, College of Marine Science, Engineering Research Institute, Gyeongsang National University)
  • 투고 : 2019.03.08
  • 심사 : 2019.04.17
  • 발행 : 2019.05.31

초록

This study was investigated to improve the phosphorus release and water quality by transformation of sedimentary P fraction for application of $CaO_2$. For the experiment, 0.5% (w/w) of $CaO_2$ was homogenized in the sediment and incubated with the control for 20 days. The analytical results showed that pH increased with $CaO_2$ and redox potential (ORP) was improved in the sediment of the reactor. The growth rate of chlorophyll-a was lower in the $CaO_2$ reactor and Dissolved Oxygen (DO) of overlying water maintained higher than that of the control. Total phosphorus (T-P) concentration in the overlying water increased from the initial concentration to 0.304mg/L in the control at 20 days. The reactor of $CaO_2$ was lowered by 29.3%. Ex-P, Fe-P and Ca-P in sediment P fraction were increased with the $CaO_2$. The formation of bound Fe-P and Ca-P in the sediments seemed to control the release of P by removing the Soluble Reactive Phosphorus (SRP) presented in the pore water. From the result, this indicated that the reduction of P release from the sediments seems to be effective in suppressing the eutrophication of P and improving the oxygen condition in the water quality with the application of $CaO_2$.

키워드

참고문헌

  1. Boers, P. C., 1991, The influence of pH on phosphate release from lake sediments, Water Res., 25, 309-311. https://doi.org/10.1016/0043-1354(91)90010-N
  2. Bostrom, B., 1982, Phosphorus release from lake sediment, Arch.Hydrobiol.Beih.Ergebn.Limn., 18, 5-59.
  3. Cha, H. J., Lee, C. B., Kim, B. S., Choi, M. S., Ruttenberg K. C., 2005, Early diagenetic redistribution and burial of phosphorus in the sediments of the southwestern east sea (japan sea), Mar. Geol., 216, 127-143. https://doi.org/10.1016/j.margeo.2005.02.001
  4. Chapra, S. C., 2008, Surface water-quality modeling, Waveland press.
  5. Cho, D. C., Bae, H. J., Lee, J. Y., Kwon, S. H., 2010, Environmental change and its enhancement of a bay sediment by using useful microbial and chemical treatments, J. Environ. Sci. Int., 19, 1355-1362.
  6. Fisher, T. R., Carlson, P. R., Barber, R. T., 1982, Sediment nutrient regeneration in three north carolina estuaries, Estuar. Coast. Shelf Sci., 14, 101-116. https://doi.org/10.1016/S0302-3524(82)80069-8
  7. Froelich, P. N., Bender, M. L., Luedtke, N. A., Heath, G. R., DeVries, T. D., 1982, The marine phosphorus cycle, Am. J. Sci., 282, 474-511. https://doi.org/10.2475/ajs.282.4.474
  8. Hieltjes, A. H., Lijklema, L., 1980, Fractionation of inorganic phosphates in calcareous sediments 1, J. Environ. Qual., 9, 405-407. https://doi.org/10.2134/jeq1980.00472425000900030015x
  9. Hyun, J. H., 2005, Significance of dissimilatory fe (III) reduction in organic matter oxidation and bioreme-diation of environmental contaminants in anoxic marine environments, The Sea, 10, 145-153.
  10. Jensen, H. S., Thamdrup, B., 1993, Iron-bound phosphorus in marine sediments as measured by bicarbonate-dithionite extraction, 47-59.
  11. Lee, Y. S., Choi, E. J., Park, M. D., Park, S. S., 1992, Determination of dissolved oxygen change caused by aquatic plant and sediment: A Stream model approach, Korea J.Limnol, 25, 215-223.
  12. Lu, S., Zhang, X., Xue, Y., 2017, Application of calcium peroxide in water and soil treatment: A review, J. Hazard. Mater., 337, 163-177. https://doi.org/10.1016/j.jhazmat.2017.04.064
  13. Matijevic, S., Kuspilic, G., Kljakovic-Gaspic, Z., 2007, The redox potential of sediment from the middle adriatic region, Acta Adriat., 48, 191-204.
  14. Mort, H. P., Slomp, C. P., Gustafsson, B. G., Andersen, T. J., 2010, Phosphorus recycling and burial in baltic sea sediments with contrasting redox conditions, Geochim. Cosmochim. Acta, 74, 1350-1362. https://doi.org/10.1016/j.gca.2009.11.016
  15. Murray, L., Wetzel, R. L., 1987, Oxygen production and consumption associated with the major autotrophic components in two temperate seagrass communities, Mar. Ecol. Prog. Ser., 38, 231-239. https://doi.org/10.3354/meps038231
  16. Nealson, K. H., Saffarini, D., 1994, Iron and manganese in anaerobic respiration: Environmental significance, physiology, and regulation, Annu. Rev. Microbiol., 48, 311-343. https://doi.org/10.1146/annurev.mi.48.100194.001523
  17. Ruttenberg, K. C., 1992, Development of a sequential extraction method for different forms of phosphorus in marine sediments, Limnol. Oceanogr., 37, 1460-1482. https://doi.org/10.4319/lo.1992.37.7.1460
  18. Ruttenberg, K. C., Berner, R. A., 1993, Authigenic apatite formation and burial in sediments from non-upwelling, continental margin environments, Geochim. Cosmochim. Acta, 57, 991-1007. https://doi.org/10.1016/0016-7037(93)90035-U
  19. Ruttenberg, K., Ogawa, N., Tamburini, F., Briggs, R., Colasacco, N., Joyce, E., 2009, Improved, high-throughput approach for phosphorus speciation in natural sediments via the SEDEX sequential extraction method, Limnology and Oceanography: Methods, 7, 319-333. https://doi.org/10.4319/lom.2009.7.319
  20. Sondergaard, M., Jensen, J. P., Jeppesen, E., 1999, Internal phosphorus loading in shallow danish lakes, Springer, 145pp.
  21. Wang, Y., Wang, W. H., Yan, F. L., Ding, Z., Feng, L. L., Zhao, J. C., 2019, Effects and mechanisms of calcium peroxide on purification of severely eutrophic water, Sci. Total Environ., 650, 2796-2806. https://doi.org/10.1016/j.scitotenv.2018.10.040
  22. WATANABE, F. T., Olsen, S. R., 1962, Colorimetric determination of phosphorus in water extracts of soil, Soil Sci., 93, 183-188. https://doi.org/10.1097/00010694-196203000-00005
  23. Yang, J., Lin, F. K., Yang, L., Hua, D. Y., 2015, A Bench-scale assessment for phosphorus release control of sediment by an Oxygen-Releasing Compound (ORC), Journal of Environmental Science and Health, Part A, 50, 49-59. https://doi.org/10.1080/10934529.2015.964608