DOI QR코드

DOI QR Code

A Near Real-Time Wind Tunnel System for Studying Evaporation of Chemical Agents(HD)

준실시간 소형 풍동 시스템을 이용한 화학작용제(HD) 증발특성 연구

  • Kah, Dong-Ha (The 4th Research and Development Institute, Agency for Defense Development) ;
  • Jung, Hyunsook (The 4th Research and Development Institute, Agency for Defense Development) ;
  • Seo, Jiyun (The 4th Research and Development Institute, Agency for Defense Development) ;
  • Lee, Juno (The 4th Research and Development Institute, Agency for Defense Development) ;
  • Lee, Hae Wan (The 4th Research and Development Institute, Agency for Defense Development)
  • 가동하 (국방과학연구소 제4기술연구본부) ;
  • 정현숙 (국방과학연구소 제4기술연구본부) ;
  • 서지윤 (국방과학연구소 제4기술연구본부) ;
  • 이준오 (국방과학연구소 제4기술연구본부) ;
  • 이해완 (국방과학연구소 제4기술연구본부)
  • Received : 2018.07.26
  • Accepted : 2018.12.07
  • Published : 2019.02.05

Abstract

Upon chemical agent release, it is of importance to study the characteristic persistence and evaporation of chemical agents from surfaces for the prediction of dispersion hazard. We have recently developed a fast and near real-time wind tunnel system proving the controlled environment(air flow, temperature, and humidity), continuously collects agent vapor and analyzes it. A thermal sorber/desorber is unnecessary to collect the vapor in the system we have developed. Instead, a tandem thermal sorber collects the vapor, which is then directly transferred to a fast gas chromatography(GC) for analysis. As a proof of concept, the evaporation of sulfur mustard agent(HD) was studied from glass, sand and concrete. The results were in an excellent agreement with those obtained from the conventional wind tunnel system.

Keywords

GSGGBW_2019_v22n1_135_f0001.png 이미지

Fig. 1. Schematic of a near real-time wind tunnel system

GSGGBW_2019_v22n1_135_f0002.png 이미지

Fig. 2. Velocity profiles in wind tunnel

GSGGBW_2019_v22n1_135_f0003.png 이미지

Fig. 3. Calibration curve of HD standard solution

GSGGBW_2019_v22n1_135_f0004.png 이미지

Fig. 4. HD concentration of glass as function of time

GSGGBW_2019_v22n1_135_f0005.png 이미지

Fig. 5. Photographs of HD droplet in wind tunnel as function of time

GSGGBW_2019_v22n1_135_f0006.png 이미지

Fig. 6. Vaporizing rate of HD from sand as function of time

GSGGBW_2019_v22n1_135_f0007.png 이미지

Fig. 7. HD vaporizing rate of concrete substrate as function of time

Table 1. Parameters of detector system

GSGGBW_2019_v22n1_135_t0001.png 이미지

References

  1. Balali-Mood. and hefazi, M., "Comparison of Early and Late Toxic Effects of Sulfur Mustard in Iranian Veterans," Basic Clin. Pharmacol. Toxicol., 99, pp. 273-282, 2006. https://doi.org/10.1111/j.1742-7843.2006.pto_429.x
  2. Suzuki T., et al., "Sarin Poisoning in Tokyo Subway," Lancet, 345, pp. 980-981, 1995. https://doi.org/10.1016/S0140-6736(95)90726-2
  3. Dan Weber and Mary Scudder, "Laboratory Evaporation and Desorption Instrumentation Systems (Wind Tunnels) for Measuring the Environmental Fate of Toxic Chemicals: Comparison of Velocity Profiles with the Earth Surface Layer Profiles," 2004 Scientific Conference on Chemical and Biological Defense Research, 2004.
  4. Yang Y. C., et al., "Decontamination of Chemical Warfare Agents," Chem. Rev., 92, pp. 1729-1743, 1992. https://doi.org/10.1021/cr00016a003
  5. Tang H., et al., "A Preliminary Study on Sorption, Diffusion, and Degradation of Mustard(HD) in Cement," J. Hazard Mater. B, 128, pp. 227-232, 2006. https://doi.org/10.1016/j.jhazmat.2005.08.045
  6. Weber, D. J., et al., Development of the 5 cm Agent Fate Wind Tunnel, ECBC-TR-327(ADA 464938), U.S. Army Edgewood Chemical Biological Center, 2006.
  7. Hyunsook Jung and Seungki Choi, "VX Evaporation and Degradation from Urban Land Surfaces," Environmental Engineering Science, Vol. 35, No. 6, pp. 645-653, 2018. https://doi.org/10.1089/ees.2017.0342
  8. Jiyun Seo, et al., "Analysis of Velocity Profile Charateristics for the 5 cm Agent Fate Wind Tunnels," KIMST Annual Conference Proceedings, Vol. 2016, pp. 1887-1888, 2016.
  9. Kah, et al., "Development of Small-Size Wind Tunnel for Chemical Agent Fate," KIMST Annual Conference Proceedings, Vol. 2015, pp. 1803-1804, 2015.
  10. Kah, et al., "Research of Nerve and Blister Agent Fate on Porous Material in Wind Tunnel," KIMST Annual Conference Proceedings, Vol. 2018, pp. 2386-2387, 2018.
  11. DOE HANDBOOKS, "Temporary Emergency Exposure Limits for Chemicals: Methods and Practice, DOE-HDBK-1046-2008, Aug. 2008.
  12. J. Leppert, et al., "Near Real Time Detection of Hazardous Airborne Substances," Talanta, 101, pp. 440-446, 2012. https://doi.org/10.1016/j.talanta.2012.09.056