DOI QR코드

DOI QR Code

이산화티탄 광촉매의 효율적 적용을 위한 LEFC 블록 제작에 관한 연구

A Study on the Development of Light Emotion Friendly Concrete Block for Efficient Application of Titan-oxide Photocatalyst

  • 김병일 (서울과학기술대학교 건축공학과) ;
  • 오상근 (서울과학기술대학교 건축공학과) ;
  • 서승훈 (서울과학기술대학교 나노IT디자인융합대학원 디자인기술융합 전공)
  • 투고 : 2019.09.30
  • 심사 : 2019.10.28
  • 발행 : 2019.11.01

초록

본 연구에서는 빛 감성친화형 콘크리트에 광촉매를 적용하여 대기질 및 실내공기질을 개선하기 위한 LEFC 블록을 개발하고자 하였다. LEFC에 광촉매를 적용하게 되면 자외선 입사면 반대편에서도 투과로 인한 자외선이 존재하여 광촉매가 반응함으로써 일반 건축 자재를 적용한 경우보다 광촉매 반응효율이 크게 상승한다. 따라서 광촉매를 LEFC에 적용하기 위해 슬럼프, J-ring, L-box 테스트를 통한 자기충전성능을 평가하여 최적 배합을 결정하였고, 압축 및 휨 강도 시험을 통해 역학성능을 평가하였다. 그리고 TiO2 분포도를 확인하기 위해 SEM과 EDS 분석을 실시하였다. ALC골재와 단열재 적용으로 광촉매 사용량을 줄이고 단위중량을 감소시키는 방안을 활용하여 광촉매 효율을 증가시키는 빛투과 콘크리트 블록을 제작하였고, 향후 건조수축 등의 문제점 개선 및 NOx 제거 실험을 통한 LEFC 블록 성능 평가를 진행하고자 한다.

Recently, the level of fine dust and ultrafine dust has reached its highest level, threatening the public's health. If the air purifier was not operated indoors, natural ventilation would not be possible. In this study, photocatalyst is applied to building materials to purify air in a passive manner. In order to use photocatalyst for LEFC(Light Emotion Friendly Concrete), it is necessary to secure self-consolidating capability. Therefore, self-consolidating performance was evaluated by slump test, J-ring test and L-box test with UHPC materials applied. Based on these results, the mixture proportion was determined, and the mechanical performance was evaluated by compressive and flexural tests. Concrete blocks were constructed with a fabrication method that improved the existing process of making LEFC. Also, the concrete block was emptied as a way to reduce the use of expensive photocatalyst. Finally, in order to identify the distribution of TiO2, an EDS analysis was performed.

키워드

참고문헌

  1. Fujishima Aand Honda K. (1972), Electrochemical photolysis of water at a semiconductor electrode, Nature, 238(5358), 37-38. https://doi.org/10.1038/238037a0
  2. Adachi T, Latthe S, Gosavi S, Roy N, Suzuki N, Ikari H, Kato K, Katsumata KI, Nakata K, Furudate M, Inoue T, Kondo T, Yuasa M, Fujishima A and Terashima C. (2018), Photocatalytic, superhydrophilic, self-cleaning $TiO_2$ coating on cheap, light-weight, flexible polycarbonate substrates. Applied Surface Science, 458, 917-923. https://doi.org/10.1016/j.apsusc.2018.07.172
  3. Hayashi M, Ochiai T, Tago S, Tawarayama H, Hosoya T, Yahagi T and Fujishima A. (2017), Influence of Dissolved Ions on the Water Purification Performance of $TiO_2$-Impregnated Porous Silica Tubes. Catalysts, 7(5), 158-167. https://doi.org/10.3390/catal7050158
  4. Magudieshwaran R, Ishii J, Raja K, Terashima C, Venkatachalam R and Fujishima A. (2019), Pitchaimuthu S. Green and chemical synthesized $CeO_2$ nanoparticles for photocatalytic indoor air pollutant degradation. Materials Letters, 239, 40-44. https://doi.org/10.1016/j.matlet.2018.11.172
  5. Han H, Riboni F, Karlicky F, Kment S, Goswami A, Sudhagar P, Yoo J, Wang L, Tomanec O, Petr M, Haderka O, Terashima C, Fujishima A, Schmuki P and Zboril R. (2017), ${\alpha}-Fe_2O_3/TiO_2$ 3D hierarchical nanostructures for enhanced photoelectrochemical water splitting. Nanoscale, 1, 134-143.
  6. Kim W, Jung J and Jeon K. (2009), Development of Visible Ray Photocatalyst for Reinforcement of Air Cleaning Fuction Indoors and Outdoors. Journal of the Architectural Institute of Korea Structure & Construction, 25(12), 121-128.
  7. Kim W, Jeon K, Son S, Lee C and Kim K. (2012), A Study to Improve Photocatalysts for Purification NOx. Journal of the Architectural Institute of Korea Structure & Construction, 28(3), 51-58. https://doi.org/10.5659/JAIK_SC.2012.28.3.51
  8. Park J, Kim H, Jung B, Choi Y, Kim Y and Kim W. (2001), An Experimental Study on the NOx Removal Properties of photocatalystic paint. Proceedings of the Korea Concrete Institute, 13(2), 1123-1128.
  9. Kim B. (2017), Light Transmitting Lightweight Concrete with Transparent Plastic Bar. The Open Civil Engineering Journal, 11, 615-626. https://doi.org/10.2174/1874149501711010615
  10. Kim B and Seo S. (2019) Prediction Model of Flexural Properties of LEFC using Foaming agent. J. Korea Institute of Building and Construction, 19(1), 009-018. https://doi.org/10.5345/JKIBC.2019.19.1.009
  11. KIM T. (2018) Study on Optimum Mixing and Strength Improvement of Concrete for Light weighting of Light Emotion Friendly Concrete, M.E. Thesis, Seoul, Korea: Seoul National University of Science and Technology, Department of Architecture.
  12. Kim B and Han Y. (2018), Flexural Performance of Transparent Plastic Bar Reinforced Concrete. Applied Sciences, 8(3), 325-341. https://doi.org/10.3390/app8030325
  13. Ryu D. (2017), A Review on Mechanical Properties of Ultra-High-Performance Fiber-Reinforced Concrete. Magazine of the Korea Concrete Institute, 29(2), 38-44.
  14. Choi J, Koh K and Lee B. (2015), Tensile Behavior of Ultra-High Performance Concrete According to Combination of Fibers. Journal of the Korea Institute for Structural Maintenance and Inspection, 19(4), 49-56. https://doi.org/10.11112/jksmi.2015.19.4.049
  15. Shin Y, Noh S and Suh K. (1993), Synthesis of Acrylic-Diene Block Copolymer and Physical Properties of PMMA Resin Containing Block Copolymer. Polymer(Korea), 18(1), 28-37.
  16. Oh S, Lee T, Park J, Kim D, Park W and Choi S. (2018), A Study on Solar Reflectance of Cool-Roof Coating Material with Heat Barrier and Waterproofing Performance According to Color Type. Proceedings of the Korea Institute of Building Construction, 18(1), 251-252.

피인용 문헌

  1. Effect of Cu, Cr, S Doped TiO2 for Transparent Plastic Bar Reinforced Concrete vol.10, pp.20, 2019, https://doi.org/10.3390/app10207334