Advances in environmental research

  • 제8권1호
  • /
  • Pages.23-38
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  • 2019
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  • 2234-1722(pISSN)
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  • 2234-1730(eISSN)
테크노프레스 (Techno-Press)
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DOI QR코드

DOI QR Code

Isotherm, kinetic and thermodynamic studies of dye removal from wastewater solution using leach waste materials

  • DEN, Muhammed Kamil O (Department of Environmental Protect Technology, University of Selcuk) ;
  • ONGAR, Sezen KUC UKC (Department of Environmental Engineering, Engineering and Natural Sciences Faculty, Konya Technical University)
  • 투고 : 2019.01.14
  • 심사 : 2019.06.07
  • 발행 : 2019.09.25
⟨ 이전 논문 다음 논문 ⟩

초록

In this study, Malachite Green (MG) dye removal from synthetic wastewaters by adsorption process using raw boron enrichment waste (BEW) and it's modifications (with acid and ultrasound) were aimed. 81% MG removal was obtained by BEW at optimum equilibrium conditions (time: 40 min., dosage: 500 mg/dm3, pH: 5-6, speed: 200 rpm, 298 K). MG removal from wastewaters using acid modified boron enrichment waste (HBEW) was determined as 82% at optimum conditions (time: 20 min., dosage: 200 mg/dm3, pH: 10, speed: 200 rpm, 298 K). For ultrasound modified BEW (UBEW), the highest MG removal percent was achieved as 84% at optimum conditions (time: 30 min, dosage: 375 mg/ dm3, pH: 8, speed: 200 rpm, 298 K). The equilibrium data of Malachite Green was evaluated for BEW, HBEW and UBEW adsorbents by using sorption isotherms such as Langmuir, Freundlich and Temkin models, out of which Langmuir model (R2 = 0.971, 0.987 and 0.984) gave better correlation and maximum adsorption capacity was found to be 147.05, 434.78 and 192.30 mg/g, respectively. The adsorption kinetics followed the pseudo-second-order kinetic equation for sorption of MG onto wastes. A look at thermodynamic data reveals that natural sorption is spontaneous and endothermic because of free negative energy exchange and positive change in enthalpy, respectively. The results indicated that boron enrichment waste, and HCl and ultrasound-modified boron enrichment waste served as good alternative adsorbents in dye removal from wastewater.

키워드

과제정보

연구 과제 주관 기관 : Selcuk University

This study was supported by Selcuk University, coordinatorship of scientific research projects (BAP) with the Project no 13101005. Some parts of this research study were presented in different conferences and were located in congress materials as abstract or full text. We also thank the late Assoc. Prof. Dr. Celalettin OZDEMİR for his contribution and support.

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