Journal of Industrial and Engineering Chemistry

  • Volume 65
  • /
  • Pages.137-145
  • /
  • 2018
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  • 1226-086X(pISSN)
  • /
  • 1876-794X(eISSN)
The Korean Society of Industrial and Engineering Chemistry (한국공업화학회)
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Performance of EMIMFSI ionic liquid based gel polymer electrolyte in rechargeable lithium metal batteries

  • Balo, Liton (Ionic Liquid and Solid State Ionics Lab, Department of Physics, Banaras Hindu University) ;
  • Gupta, Himani (Ionic Liquid and Solid State Ionics Lab, Department of Physics, Banaras Hindu University) ;
  • Singh, Shishir Kumar (Ionic Liquid and Solid State Ionics Lab, Department of Physics, Banaras Hindu University) ;
  • Singh, Varun Kumar (Ionic Liquid and Solid State Ionics Lab, Department of Physics, Banaras Hindu University) ;
  • Kataria, Shalu (Centre of Material Sciences, IIDS, University of Allahabad) ;
  • Singh, Rajendra Kumar (Ionic Liquid and Solid State Ionics Lab, Department of Physics, Banaras Hindu University)
  • Received : 2017.11.17
  • Accepted : 2018.04.16
  • Published : 2018.09.25
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Abstract

Flexible gel polymer electrolytes based on polymer polyethylene oxide, salt lithium bis(fluorosulfonyl) imide and ionic liquid 1-ethyl-3-methylimidazolium bis(fluorosulfonyl)imide are synthesized. Prepared samples show high thermal stability, high ionic conductivity at room temperature and an electrochemical stability window of ~3.51V vs. $Li/Li^+$. Lithium deposition-striping voltage profiles show the formation of a stable solid electrolyte interface. A $Li/GPE/LiFePO_4$ cell was assembled by low cost thermal lamination technique. This cell can deliver $143mAh\;g^{-1}$ capacity at room temperature at C/20 rate with good discharge efficiency. Use of micro grid mesh type Al current collector in cathode exhibits significant improvement in capacity retention.

Keywords

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