Nano

  • 제13권12호
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  • Pages.1850139.1-1850139.10
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  • 2018
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  • 1793-2920(pISSN)
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  • 1793-7094(eISSN)
성균관대학교 성균나노과학기술원 (SKKU Advanced Institute of Nano Technology)
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DOI QR코드

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2D Coordination Polymer Derived Co3O4 Nanocrystals as High Performance Anode Material of Lithium-Ion Batteries

  • Wen, Hao (School of Petrochemical Engineering and Jiangsu Key Laboratory of Fine Petro-chemical Technology Changzhou University) ;
  • Shi, Changdong (School of Petrochemical Engineering and Jiangsu Key Laboratory of Fine Petro-chemical Technology Changzhou University) ;
  • Gao, Yuanrui (Department of Chemistry, College of Science Shanghai University) ;
  • Rong, Hongren (School of Petrochemical Engineering and Jiangsu Key Laboratory of Fine Petro-chemical Technology Changzhou University) ;
  • Sha, Yanyong (School of Petrochemical Engineering and Jiangsu Key Laboratory of Fine Petro-chemical Technology Changzhou University) ;
  • Liu, Hongjiang (Department of Chemistry, College of Science Shanghai University) ;
  • Liu, Qi (School of Petrochemical Engineering and Jiangsu Key Laboratory of Fine Petro-chemical Technology Changzhou University)
  • 투고 : 2018.07.09
  • 심사 : 2018.10.30
  • 발행 : 2018.12.31
⟨ 이전 논문 다음 논문 ⟩

초록

$Co_3O_4$ nanocrystals have been synthesized via an ordinary one-step calcination of a cobalt-based 2D coordination polymer [Co(tfbdc)(4,4'-bpy)$(H_2O)_2$]. As an anode material for lithium-ion batteries, the obtained $Co_3O_4$ nanocrystals exhibit high reversible capacity, excellent cyclic stability and better rate capability. The reversible capacity of the $Co_3O_4$ nanocrystals maintains $713mA\;h\;g^{-1}$ after 50 cycles at a current density of $50mA\;g^{-1}$. Our results confirm that searching for metal oxides nanomaterials used as anode materials of lithium ion batteries via the calcinations of 2D coordination polymer is a new route.

키워드

과제정보

연구 과제 주관 기관 : National Natural Science Foundation of China, Jiangsu Colleges and Universities

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