Korean Chemical Engineering Research

The Korean Institute of Chemical Engineers (한국화학공학회)
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Optical and Acoustic Properties of Binary Mixtures of Butanol Isomers as Oxygenates with Cyclohexane, Benzene and Toluene at 308.15 K

  • Verma, Sweety (Department of Chemistry, Deenbandhu Chhotu Ram University of Science and Technology) ;
  • Gahlyan, Suman (Department of Chemistry, Deenbandhu Chhotu Ram University of Science and Technology) ;
  • Rani, Manju (Department of Chemical Engineering, Deenbandhu Chhotu Ram University of Science and Technology) ;
  • Maken, Sanjeev (Department of Chemistry, Deenbandhu Chhotu Ram University of Science and Technology)
  • Received : 2018.05.14
  • Accepted : 2018.08.31
  • Published : 2018.10.01
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Abstract

Refractive index and speeds of sound for the binary mixture of isomer of butanol (1) + cyclohexane, benzene and toluene (2) were measured at 308.15 K. The measured data were used to calculate deviation in refractive index ${\Delta}n$, ultrasonic speed ${\Delta}u$, isentropic compressibility $K_s^E$, available volume $V_a$, excess intermolecular free length $L_f$ and molecular association $M_A$. All the derived properties were correlated with polynomial equation. Ultrasonic speed data were predicted using various empirical correlations like Nomoto, van Dael, impedance dependence and theoretically with Schaaff's collision factor theory (CFT). Jacobson free length theory (FLT) was used to calculate $L_f$. The measured refractive index was also correlated with various mixing rules. The deviation in refractive index Δn and ultrasonic speed ${\Delta}u$ was used to determine the intermolecular interactions.

Keywords

References

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