Journal of Industrial and Engineering Chemistry

  • 제67권
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  • Pages.72-79
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  • 2018
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  • 1226-086X(pISSN)
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  • 1876-794X(eISSN)
한국공업화학회 (The Korean Society of Industrial and Engineering Chemistry)
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DOI QR코드

DOI QR Code

Synthesis, interfacial property, and application of new hybrid anion surfactant containing fluorocarbon and hydrocarbon chains

  • Kang, Eun-kyung (Advanced Materials and Chemical Engineering, University of Science and Technology) ;
  • Sohn, Eun-Ho (Advanced Materials and Chemical Engineering, University of Science and Technology) ;
  • Jung, Ga Young (Advanced Materials and Chemical Engineering, University of Science and Technology) ;
  • Jung, Seon Hwa (Center for Interface Chemistry and Engineering, Korea Research Institute of Chemical Technology) ;
  • Ha, Jong-Wook (Center for Interface Chemistry and Engineering, Korea Research Institute of Chemical Technology) ;
  • Lee, Soo-Bok (Center for Interface Chemistry and Engineering, Korea Research Institute of Chemical Technology) ;
  • Park, In Jun (Advanced Materials and Chemical Engineering, University of Science and Technology) ;
  • Lee, Byung Min (Advanced Materials and Chemical Engineering, University of Science and Technology)
  • 투고 : 2018.04.11
  • 심사 : 2018.06.16
  • 발행 : 2018.11.25
⟨ 이전 논문 다음 논문 ⟩

초록

Hybrid F2HX surfactants bearing a sulfate moiety and both hydrocarbon and fluorocarbon chains were prepared by the reaction of alkyl glycidyl ethers with fluoro-alcohol, and subsequent sulfation. The fluorocarbon number in F2HX was fixed at the shortest number possible (i.e., 2), while the hydrocarbon number (X) in the second chain was varied between 2, 4, 6, and 8. Their surface-active properties and emulsion stabilities were systematically estimated as a function of the X. Among them, F2H8 exhibited the optimal surfactant performance, which was comparable to previously reported surfactants and it was successfully applied in the emulsion polymerization of vinylidene fluoride.

키워드

과제정보

연구 과제번호 : Development of manufacturing process with environmental affinity for fluorinated copolymer based on VDF, Development of biocompatible materials with separation properties for artificial organs

연구 과제 주관 기관 : Korea Research Institute of Chemical Technology (KRICT)

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피인용 문헌

  1. Synthesis and Interface Activity of a Series of Carboxylic Quaternary Ammonium Surfactants in Hydraulic Fracturing vol.2019, pp.None, 2019, https://doi.org/10.1155/2019/4258643
  2. Surface activity, salt and pH tolerance, and wettability of novel nonionic fluorinated surfactants with a short fluorocarbon chain vol.42, pp.1, 2018, https://doi.org/10.1080/01932691.2020.1768862
  3. Synthesis and application of non-bioaccumulable fluorinated surfactants: a review vol.3, pp.1, 2021, https://doi.org/10.1186/s42825-020-00048-7