Journal of Industrial and Engineering Chemistry

  • Volume 68
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  • Pages.168-172
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  • 2018
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  • 1226-086X(pISSN)
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  • 1876-794X(eISSN)
The Korean Society of Industrial and Engineering Chemistry (한국공업화학회)
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Influence of ionic liquid structures on polyimide-based gel polymer electrolytes for high-safety lithium batteries

  • Kim, Jae-Kwang (Department of Solar & Energy Engineering, Cheongju University)
  • Received : 2017.12.17
  • Accepted : 2018.07.26
  • Published : 2018.12.25
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Abstract

This study first investigates the effect of the choice of cation on three different ionic-liquid-based gel polymer electrolytes (ILPEs) with polyimide membranes. The preparation of three ILPEs based on electrospun membranes of PI and incorporating a room-temperature ionic liquid, 1-alkyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide complexed with lithium bis(trifluoromethylsulfonyl)imide, is described. ILPE-EMImTFSI has an ionic conductivity as high as $5.3{\times}10^{-3}S\;cm^{-1}$ at $30^{\circ}C$. Furthermore, it shows higher thermal stability and electrochemical oxidation stability compared to the other two ILPEs because of its stronger bonds. These results indicate that polyimide-based ILPE-EMImTFSI is a good candidate for use in high-safety rechargeable lithium metal batteries.

Keywords

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