Journal of Industrial and Engineering Chemistry

  • Volume 68
  • /
  • Pages.1-5
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  • 2018
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  • 1226-086X(pISSN)
  • /
  • 1876-794X(eISSN)
The Korean Society of Industrial and Engineering Chemistry (한국공업화학회)
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Novel thermal radical initiators based on a triazene moiety for radical polymerization

  • Kang, Seokwoo (Department of Chemical Engineering, Kyung Hee University) ;
  • Kim, Taemin (Department of Chemical Engineering, Kyung Hee University) ;
  • Kim, Beomjin (Department of Chemical Engineering, Kyung Hee University) ;
  • Jeong, Yeonkyu (Department of Chemical Engineering, Kyung Hee University) ;
  • Park, Young Il (Research Center for Green Fine Chemicals, Korea Research Institute of Chemical Technology) ;
  • Noh, Seung Man (Research Center for Green Fine Chemicals, Korea Research Institute of Chemical Technology) ;
  • Park, Jongwook (Department of Chemical Engineering, Kyung Hee University)
  • Received : 2018.02.15
  • Accepted : 2018.08.18
  • Published : 2018.12.25
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Abstract

In this study, we designed and synthesized novel thermal radical initiators of BTAP (1-phenyl-3,3-dipropyltriazene), BTACP (1-(phenyldiazenyl)pyrrolidine), BTACH (1-(phenyldiazenyl)piperidine), and BTACH7 (1-(phenyldiazenyl)azepane) based on a triazene moiety to provide a thermal initiator for radical polymerization. The synthetic method is valuable due to the simplicity. In addition, the synthesized thermal initiator did not affect the color of the polymer. Among the four initiators, the polymerization time for the BTACH of the 6-membered ring decreased by 67%, as opposed to the polymerization time without initiator. Conversion after polymerization was over 92%. DSC experiments also showed that the initiator with hexagonal rings had the lowest peak polymerization temperature of $160^{\circ}C$. Our study suggests a promising new initiator system that is effective for radical polymerization.

Keywords

Acknowledgement

Supported by : Ministry of Trade, Industry & Energy (MOTIE)

References

  1. T. Endo, F. Sanda, Macromol. Symp. 107 (1996) 237.
  2. E. Ghassemieh, C. Marcello, Materials in Automotive Application, State of the Art and Prospects. 20 (2011) 365.
  3. M. Kamigaito, T. Ando, M. Sawamoto, Chem. Rev. 101 (2001) 3689. https://doi.org/10.1021/cr9901182
  4. B. Cantor, P. Grant, C. Johnston, Authomotive Enginnering: Lightweight, (2008), pp. 1.
  5. P. Kardar, M. Ebrahimi, S. Bastani, Prog. Org. Coat. 62 (2008) 321. https://doi.org/10.1016/j.porgcoat.2008.01.015
  6. S. Roche, S. Pavan, J.L. Loubet, Ph. Barbeau, B. Magny, Prog. Org. Coat. 47 (2003) 37. https://doi.org/10.1016/S0300-9440(03)00017-1
  7. A. Valet, Prog. Org. Coat. 35 (1999) 223. https://doi.org/10.1016/S0300-9440(99)00018-1
  8. C.M. Seubert, M.E. Nichols, Prog. Org. Coat. 49 (2004) 218. https://doi.org/10.1016/j.porgcoat.2003.10.002
  9. K. Maag, W. Lenhard, H. Loffels, Prog. Org. Coat. 40 (2000) 93. https://doi.org/10.1016/S0300-9440(00)00144-2
  10. G. Odian, Principles of Polymerization, fourth ed., Staten Island, New York, 2004.

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