Journal of Electrochemical Science and Technology

The Korean Electrochemical Society (한국전기화학회)
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Chitosan-Cu-salen/Carbon Nano-Composite Based Electrode for the Enzyme-less Electrochemical Sensing of Hydrogen Peroxide

  • Jirimali, Harishchandra Digambar (Department of Chemistry and Interdisciplinary Program of Integrated Biotechnology, Sogang University) ;
  • Saravanakumar, Duraisamy (Department of Chemistry and Interdisciplinary Program of Integrated Biotechnology, Sogang University) ;
  • Shin, Woonsup (Department of Chemistry and Interdisciplinary Program of Integrated Biotechnology, Sogang University)
  • Received : 2017.11.10
  • Accepted : 2018.04.21
  • Published : 2018.09.30
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Abstract

Cu-Salen complex was prepared and attached into chitosan (Cs) polymer backbone. Nanocomposite of the synthesized polymer was prepared with functionalized carbon nano-particles (Cs-Cu-sal/C) to modify the electrode surface. The surface morphology of (Cs-Cu-sal/C) nanocomposite film showed a homogeneous distribution of carbon nanoparticles within the polymeric matrix. The cyclic voltammogram of the modified electrode exhibited a redox behavior at -0.1 V vs. Ag/AgCl (3 M KCl) in 0.1 M PB (pH 7) and showed an excellent hydrogen peroxide reduction activity. The Cs-Cu-sal/C electrode displays a linear response from $5{\times}10^{-6}$ to $5{\times}10^{-4}M$, with a correlation coefficient of 0.993 and detection limit of $0.9{\mu}M$ (at S/N = 3). The sensitivity of the electrode was found to be $0.356{\mu}A\;{\mu}M^{-1}\;cm^{-2}$.

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References

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