DOI QR코드

DOI QR Code

Corrosion of Fe-17%Cr Steels in (Na2SO4+NaCl) Salts at 800 and 900℃

  • Lee, Dong Bok (School of Advanced Materials Science & Engineering, Sungkyunkwan University) ;
  • Xiao, Xiao (School of Advanced Materials Science & Engineering, Sungkyunkwan University)
  • Received : 2018.06.20
  • Accepted : 2018.08.01
  • Published : 2018.08.31

Abstract

Stainless steel grade 430 with a composition of Fe-17%Cr was corroded in $Na_2SO_4$ and ($Na_2SO_4+NaCl$) salts at 800 and at $900^{\circ}C$ for up to 20 h. It corroded mainly to $Cr_2O_3$, along with a small amount of $Fe_2O_3$ and $Fe_3O_4$. The formed oxide scales were neither dense nor compact enough owing to their ensuing dissolution into the salt during corrosion, which facilitated internal corrosion. Corrosion occurred faster at $900^{\circ}C$ than $800^{\circ}C$. NaCl in $Na_2SO_4$ aggravated the scale adherence.

Keywords

References

  1. D. Young, High Temperature Oxidation and Corrosion of Metals, Elsevier, USA (2008) 383.
  2. R. Y. Chen and W. Y. D. Yuen, Review of the high-temperature oxidation of iron and carbon steels in air or oxygen, Oxid. Met. 59 (2003) 433-468. https://doi.org/10.1023/A:1023685905159
  3. B. K. Choi and D. J. Lockwood, Peculiarities of the structural phase transitions in $Na_2SO_4$ (V): a Raman scattering study, J. Phys: Condens. Mater. 17 (2005) 6095-6108. https://doi.org/10.1088/0953-8984/17/38/013
  4. N. Birks, G. H. Meier and F. S. Pettit, High-Temperature Oxidation of Metals, Cambridge University Press, UK (2006) 205.
  5. F. S. Pettit and C. S. Giggins, Hot Corrosion in: Superalloys II, edtied by C. T. Sims, N. S. Stoloff and W. C. Hagel, John Wiley & Sons, NY (1987) 327.