DOI QR코드

DOI QR Code

A Study on the Change of Optical and Mechanical Properties by Reprocessing for High Melt-Indexed Polycarbonate Used in Injection Molded Optical Parts

광학용 사출성형품에 사용되는 고유동성 폴리카보네이트의 재사용에 따른 광학적, 기계적 물성 변화에 대한 연구

  • 이준한 (단국대학교 기계공학과) ;
  • 강정진 (한국생산기술연구원 금형기술그룹) ;
  • 윤경환 (단국대학교 기계공학과) ;
  • 김종선 (한국생산기술연구원 금형기술그룹)
  • Received : 2018.04.06
  • Accepted : 2018.07.17
  • Published : 2018.08.01

Abstract

To estimate the recycling feasibility of high melt-indexed polycarbonate, 3.5 inch LGP, tensile, flexural and impact specimens were injection-molded and the LGP was shredded into scraps. The scraps were injection-molded again and this process was repeated for 4 times. Properties of the sample, i.e., optical properties, mechanical properties and number average molecular weight were measured at each cycle. Based on the results, as the number of reprocessing increased, transmittance decreased at low wavelength and color coordinate was changed systematically to yellow. Yellow index increased more than twofold during 4 recycling processes. On the other hand, the number average molecular weight decreased during recycling processes. Flexural and impact strength showed no tendency according to the number of recycling, but tensile strength decreased sharply after the third recycling process. Based on these properties, it was concluded that the number of recycling for high melt-indexed polycarbonate allowed in this study was one.

Keywords

References

  1. A. Jansson, K. Moller, T. Gevert, 2003, Degradation of post-consumer polypropylene materials exposed to simulated recycling - mechanical properties, Polym. Degrad. Stab, Vol. 82, No. 1, pp.37-46. https://doi.org/10.1016/S0141-3910(03)00160-5
  2. J. W. Choi, S. K. Lim, D. J. Choi, S. K. Cha, 2006, The study of physical properties of virgin and recycled HIPS resin, J. Appl. Chem., Vol. 10, No. 2, pp.437-440.
  3. B. S. No, G. H. Lee, Y. D. Jeong, 2007, Mechanical properties and morphology of the recycled thermoplastic elastomer molding, Trans. Mater. Process., Vol. 16, No. 1, pp.31-35. https://doi.org/10.5228/KSPP.2007.16.1.031
  4. H. I. Lee, J. S. Lee, 1993, Properties and Applications of Polycarbonate, Polym. Sci. Tech., Vol. 4, No. 6, pp.423-431.
  5. Y. M. Won, 2011, Technology development trend and properties of methacrylate resins, ReSEAT Report, Korea, Inst. Sci. Technol. Inf.
  6. P. S. Nunes, P. D. Ohlsson, O. Ordeig, J. P. Kutter, 2010, Cyclic olefin polymers: emerging materials for lab-on-a-chip applications, Microfluid. Nanofluid., Vol. 9, No. 2-3, pp.145-161. https://doi.org/10.1007/s10404-010-0605-4
  7. S. J. Kwak, J. H. Shim, H. G. Yoon, K. H. Lee, 2003, Inorganic Thin Film Coating on the Display Plastic Substrate, Polym. Sci. Tech., Vol. 14, No. 2, pp.181-191
  8. W. C. Jung, Y. M. Heo, K. H. Shin, G. S. Yoon, S. H. Chang, 2006, Injection Molding Characteristics of COC and PP in Micro Rib Structure, Trans. Mater. Process., Vol. 15, No. 2, pp.158-163. https://doi.org/10.5228/KSPP.2006.15.2.158
  9. O. Matthew, S. Matumoto, K. tomita, M Egawa, 2014, ANTEC 2014 proceedings, Society of Plastics Engineers, Las Vegas & Nevada, USA, pp.794-797.
  10. J. M. Perez, J. L. Vilas, J. M. Laza, S. Amaiz, F. Mijangos, E. Bilbao, M. Rodriguez, L. M. Leon, 2010, Effect of reprocessing and accelerated ageing on thermal and mechanical polycarbonate properties, J. Mater. Process. Technol., Vol. 210, No. 5, pp.727-733. https://doi.org/10.1016/j.jmatprotec.2009.12.009
  11. Z. Q. Liu, A. M. Cunha, X. -S. Yi, A. C. Bernardo, 2000, Key properties to understand the performance of polycarbonate reprocessed by injection molding, J. Appl. Polym. Sci., Vol. 77, No. 6, pp.1393-1400. https://doi.org/10.1002/1097-4628(20000808)77:6<1393::AID-APP27>3.0.CO;2-4
  12. F. Ronkay, 2013, Effect of recycling on the rheological, mechanical and optical properties of polycarbonate, Acta. Polytech. Hungarica., Vol. 10, No. 1, pp.209-220.
  13. M. Y. Mehr, W. D. van Driel, K. M. B. Jansen, P. Deeben, M. Boutlje, G. Q. Zhang, 2013, Photodegradation of bisphenol A polycarbonate under blue light radiation and its effect on optical properties, Opt. Mater., Vol. 35, No. 3, pp.504-508. https://doi.org/10.1016/j.optmat.2012.10.001
  14. G. Lu, M. Y. Mehr, W. D. van Driel, X. Fan, J. Fan, K. M. B. Jansen, 2015, Color shift investigations for LED secondary optical designs: comparison between BPAPC and PMMA, Opt. Mater., Vol. 45, pp.37-41. https://doi.org/10.1016/j.optmat.2015.03.005
  15. I. K. Min, S. J. Lee, J. S. Kim, K. H. Yoon, 2016, An experimental study of yellow shift in injection-molded light guide plate, Korea Aust. Rheol. J., Vol. 28, No. 3, pp.187-196. https://doi.org/10.1007/s13367-016-0019-2
  16. B. C. Kim, C. G. Choi, S. P. Han, 2002, Physical and Optical Properties of PMMA/PVDF Blends, Polym. Korea., Vol. 26, No. 4, pp.462-467.
  17. J. S. Hong, S. R. Park, M. Y. Lyu, 2011, Measurement of Residual Stress Using Photoelasticity and Computer Simulation of Optical Characteristics in a Transparent Injection Molded Article, Polym. Korea., Vol.35, No.1, pp.1-6. https://doi.org/10.7317/pk.2011.35.1.1
  18. B. H. Lee, Y. W. Chang, H. M. Lim, 2015, Preparation and Characterizations of Polymethylmethacrylate (PMMA)/Acrylate Rubber (ACM) Blend for Light Diffuser Applications, Elastomers. Compos., Vol. 50, No.1, pp.49-54. https://doi.org/10.7473/EC.2015.50.1.049
  19. Mitsubishi Engineering-Plastics Corporation, Basic properties of lupilon HL-8000, https://www.m-ep.co.jp
  20. Reiloy Westland Corporation, 2012, Barrel & Screw Handbook, Reiloy Westland Corporation, 1735 S. Maize Rd. Wichita, KS 67209, pp.21-23.