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A Study of Upgrading Real Biogas via CO2 Precipitation Route Under Indian Scenario

  • Gehlaut, Avneesh Kumar (Department of Chemical Engineering, Motilal Nehru National Institute of Technology) ;
  • Gaur, Ankur (Department of Chemical Engineering, Motilal Nehru National Institute of Technology) ;
  • Hasan, Shabih Ul (Department of Chemical Engineering, Motilal Nehru National Institute of Technology) ;
  • Park, Jin-Won (Department of Chemical and Biomolecular Engineering, Yonsei University)
  • Received : 2017.09.25
  • Accepted : 2018.03.08
  • Published : 2018.06.01

Abstract

Our study focuses on upgrading real biogas obtained under Indian scenario using carbon capture and utilization (CCU) technology to remove carbon dioxide ($CO_2$) and utilize it by forming metal carbonate. Amines such as monoethanolamine (MEA), diethanolamine (DEA), and sodium hydroxide (NaOH) were used to rapidly convert gaseous $CO_2$ to aqueous $CO_2$, and $BaCl_2$ was used as an additive to react with the aqueous $CO_2$ and rapidly precipitating the aqueous $CO_2$. All experiments were conducted at $25^{\circ}C$ and 1 atm. We analyzed the characteristics of the $BaCO_3$ precipitates using X-ray diffractometry (XRD), scanning electron microscopy - Energy dispersive spectroscopy (SEM-EDS) and Fourier-transform infrared spectroscopy (FT-IR) analyses. The precipitates exhibited witherite morphology confirmed by the XRD results, and FT-IR confirmed that the metal salt formed was $BaCO_3$, and EDS showed that there were no traces of impurities present in it. The quantity of the $BaCO_3$ was larger when formed with DEA. Also, a comparison was done with a previous study of ours conducted in Korean conditions. Finally, we observed that the carbonate obtained using real biogas showed similar properties to carbonates available in the market. An economic analysis was done to show the cost effectiveness of the method employed by us.

Keywords

References

  1. Sorrell, S., Reducing Energy Demand: A Review of Issues, Challenges and Approaches. Renew. Sustainable Energy Rev., 47, 74-82(2015). https://doi.org/10.1016/j.rser.2015.03.002
  2. Cho, J. K., Park, S. C. and Chang, H. N., "Biochemical Methane Potential and Solid State Anaerobic Digestion of Korean Food Wastes," Bioresour. Technol., 52, 245-53(1995). https://doi.org/10.1016/0960-8524(95)00031-9
  3. Bundhoo, Z. M. A., Mauthoor, S. and Mohee, R., "Potential of Biogas Production from Biomass and Waste Materials in the Small Island Developing State of Mauritius," Renew. Sustainable Energy Rev., 56, 1087-1100(2016). https://doi.org/10.1016/j.rser.2015.12.026
  4. Bond, T. and Templeton, M. R., "History and Future of Domestic Biogas Plants in the Developing World," Energy Sustain. Dev. 15, 347-354(2011). https://doi.org/10.1016/j.esd.2011.09.003
  5. Miah, M. R., Rahman, A. K. M. L., Akanda, M. R., Pulak, A., and Rouf, M. A., "Production of Biogas from Poultry Litter Mixed with the co-substrate Cow Dung," J. Taibah Univ. Sci., 10, 497-504(2016). https://doi.org/10.1016/j.jtusci.2015.07.007
  6. Kim, D. J. and Kim, H., "Sludge Solubilization by Pre-treatment and its Effect on Methane Production and Sludge Reduction in Anaerobic Digestion," Korean Chem. Eng. Res., 48(1), 103-109(2010).
  7. El-Mashad, H. M. and Zhang, R., "Biogas Production from Codigestion of Dairy Manure and Food Waste," Bioresoure. Technol., 101, 4021-4028(2010). https://doi.org/10.1016/j.biortech.2010.01.027
  8. Gaur, A., Park, J. W. and Jung, J. H., "Metal-Carbonate Formation from Ammonia Solution by Addition of Metal Salts - An Effective Method for $CO_2$ Capture from Landfill Gas (LFG)," Fuel Process. Technol., 91, 1500-1504(2010). https://doi.org/10.1016/j.fuproc.2010.05.027
  9. Gaur, A., Park, J. W., Jang, H. J. and Song, H. J., "Precipitation of Barium Carbonate from Alkanolamine Solution - study of $CO_2$ Absorption from Landfill Gas (LFG), J. Chem. Technol. Biotechnol., 86, 153-156(2011). https://doi.org/10.1002/jctb.2502
  10. Gaur, A., Park, J. W., Jang, J. W., Maken, S., Lee, J. and Song, H. S., "Characteristics of Alkaline Wastewater Neutralization for $CO_2$ Capture from Landfill Gas (LFG)," Energy Fuels, 23, 5467-73(2009). https://doi.org/10.1021/ef900615h
  11. Park, S., Min, J., Lee, M. G., Jo, H. and Park, J., "Characteristics of $CO_2$ Fixation by Chemical Conversion to Carbonate Salts," Chem. Eng. J., 231, 287-93(2013). https://doi.org/10.1016/j.cej.2013.07.032
  12. Sanna, A, Uibu, M., Caramanna, G., Kuusik, R. and Valer, M. M V., "A Review of Mineral Carbonation Technologies to Sequester $CO_2$," Chem. Soc. Rev., 43, 8049-80(2014). https://doi.org/10.1039/C4CS00035H
  13. Arenas, C., Leidy, R., Manuel, F. and Martha, C., "$CO_2$ Capture via Barium Carbonate Formation After its Absorption with Ammonia in a Pilot Scale Column," Chem. Eng. J., 254, 220-229(2014). https://doi.org/10.1016/j.cej.2014.05.108
  14. Cao, X., Hong, T., Yang, R., Tian, J., Xia, R. C., Dong, C J. and Li, J., "Insights into the Catalytic Activity of Barium Carbonate for Oxygen Reduction Reaction," J. Phys. Chem. C., 120, 22895-902(2016). https://doi.org/10.1021/acs.jpcc.6b08267
  15. Song, H. J., Park, S., Kim, H., Gaur, A., Park, J. W. and Lee, S. W., "Carbon Dioxide Absorption Characteristics of Aqueous Amino Acid Salt Solutions," Int. J. Greenhouse Gas Control, 11, 64-72(2012). https://doi.org/10.1016/j.ijggc.2012.07.019
  16. Santos, S. P., Duarte, A. P., Bordado, J. C. and Gomes, J. F., "New process for Simultaneous Removal of $CO_2$, SOx and NOx," Ciencia Tecnol. Dos Mater., 28, 106-111(2016). https://doi.org/10.1016/j.ctmat.2016.12.002
  17. Gomes, S., Santos, S. P. and Bordado, J. C., "Choosing Amine-based Absorbents for $CO_2$ Capture," Environ. Technol., 36, 19-25 (2015). https://doi.org/10.1080/09593330.2014.934742
  18. Kim, J. H., Kwak, N. S., Lee, I. Y., Jang, K. R. and Sim, J. G., Performance and Economic Analysis of Domestic Supercritical Coal-Fired Power Plant with Post-Combustion $CO_2$ Capture Process," Korean Chem. Eng. Res., 55(3), 419-425(2017). https://doi.org/10.9713/KCER.2017.55.3.419
  19. Yoo, J. G., Park, H. S., Hong, W. H., Park, J. K. and Kim, J. N., "Effect of Precipitation on Operation Range of the $CO_2$ Capture Process using Ammonia Water Absorbent," Korean Chem. Eng. Res., 45(3), 258-263(2007).
  20. Kumar, S., Cho, J. H. and Moon, I., "Ionic Liquid-amine Blends and $CO_2BOLs$: Prospective Solvents for Natural gas Sweetening and $CO_2$ Capture Technology - A Review," Int. J. Greenhouse Gas Control, 20, 87-116(2014). https://doi.org/10.1016/j.ijggc.2013.10.019