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Fundamental Study of Unit Proton Exchange Membrane Electrolysis for Realtime Detection of Tritium

실시간 삼중수소 검출을 위한 단위 양성자 교환 막 전기분해 기초연구

  • CHAE, JONGMIN (Graduate School of Mechanical Engineering, Chungnam University) ;
  • YU, SANGSEOK (School of Mechanical Engineering, Chungnam University)
  • Received : 2018.04.09
  • Accepted : 2018.04.30
  • Published : 2018.04.30

Abstract

Even though the nuclear power plants has many advantages, safety issues of nuclear power plants are crucial factors of reliable operation. A tritium detector is a useful sensor to analyze amount of exposed radiation from the nuclear power plants. Currently, concentration of underwater tritium is measured precisely but it takes very long time. Since electrolysis is extracted hydrogen from the coolant of nuclear power plant, it can motivate to develop new type of real-time sensor. In this study, Proton Exchange Membrane (PEM) electrolyzer is studied for candidate as preprocessor of real-time tritium detector. Characteristics of the unit PEM electrolyzer were experimentally investigated. A simulation model is developed to understand physical behavior of unit PEM electrolyzer under dynamic operation.

Keywords

References

  1. S. J. Hahn, "Victimization of the Bodily Health of Residents in Nuclear Power Plant Areas with Respect to Environmental Justice of Capabilities", Korean Sociological Association, Vol. 20, No. 1, 2016, pp. 283-315.
  2. H. J. Choi, H. Lee, K. S. Suh, and H. S. Kang, "Prediction of the tritium concentration in the soil water after the operation of wolsong tritium removal facility", Nuclear Engineering and Technology, Vol. 37, No. 4, 2005, pp. 385-390.
  3. A. Soreefan "Development of an original laboratory prototype for a field tritium detector containing a PEM electrolyzer mounted in series with a gas proportional counter", TigerPrints, USA, 2009.
  4. H. Takata, M. Nishikawa, T. Egawa, and N. Mizuno, "HTO electrolysis methode by using proton exchange membrane fuel cell", Journal of Nuclear Materials, Vol. 367-370, Part B, 2007, pp. 1102-1106. https://doi.org/10.1016/j.jnucmat.2007.03.196
  5. A. S. Tijani, N. A. B. Kamarudin, F. A. B. Mazlan, "Investigation of the effect of charge transfer coefficient (CTC) on the operating voltage of polymer electrolyte membrane (PEM) electrolyzer", International Journal of Hydrogen Energy, 2018, pp. 1-14, In press.
  6. K. S. Sim, "Hydrogen production by water electrolysis", Korea Institute of Energy Research, Korea, 2006.
  7. O. F. Selamet, F. Becerikli, M. D. Mat, and Y. Kaplan, "Development and testing of highly efficient proton exchange membrane (PEM) electrolyzer stack", International Journal of Hydrogen Energy, Vol. 36, No. 17, 2011, pp. 11480-11487. https://doi.org/10.1016/j.ijhydene.2011.01.129
  8. A. Awasthi, K. Scott, and S. Basu, "Dynamic modeling and simulation of a proton exchange membrane electrolyzer for hydrogen production", International Journal of Hydrogen Energy, Vol. 36, No. 22, 2011, pp. 14779-14786. https://doi.org/10.1016/j.ijhydene.2011.03.045
  9. M. Chandesris, V. Medeau, N. Guillet, S. Chelghoum, D. Thoby, and F. Fouda-Onana, "Membrane degradation in PEM water electrolyzer: Numerical modeling and experimental evidence of the influence of temperature and current density", International Journal of Hydrogen Energy, Vol. 40, No. 3, 2015, pp. 1353-1366. https://doi.org/10.1016/j.ijhydene.2014.11.111
  10. F. Marangio, M. Santarelli, and M. Cali, "Theoretical model and experimental for hydrogen production", International Journal of Hydrogen Energy, Vol. 34, No. 3, 2009, pp. 1143-1158. https://doi.org/10.1016/j.ijhydene.2008.11.083
  11. B. Han, S. M. Seen, J. Mo, and F. Y. Zhang, "Electrochemical performance modeling of a proton exchange membrane electrolyzer cell for hydrogen energy", International Journal of Hydrogen Energy, Vol. 40, No. 22, 2015, pp. 7006-7016. https://doi.org/10.1016/j.ijhydene.2015.03.164
  12. T. Yigit, O. F. Selamet, "Mathematical modeling and dynamic Simulink simulation of high-pressure PEM electrolyzer system", International Journal of Hydrogen Energy, Vol. 41, No. 32, 2016, pp. 13901-13914. https://doi.org/10.1016/j.ijhydene.2016.06.022
  13. H. Gorgun, "Dynamic modelling of a proton exchange membrane (PEM) electrolyzer", International Journal of Hydrogen Energy, Vol. 31, No. 1, 2006, pp. 29-38. https://doi.org/10.1016/j.ijhydene.2005.04.001
  14. J. Fort, Z. Pavlik, J. Zumar, M. Pavlikova, and R. Cerny, "Effect of temperature on water vapor transport properties", Journal of Building Physics, Vol. 38, No. 2, 2014, pp. 156-169. https://doi.org/10.1177/1744259114532612