Membrane and Water Treatment

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Acid green-25 removal from wastewater by anion exchange membrane: Adsorption kinetic and thermodynamic studies

  • Khan, Muhammad Imran (CAS Key Laboratory of Soft Matter Chemistry, Lab of Functional Membranes, School of Chemistry and Material Science, University of Science and Technology of China) ;
  • Ansari, Tariq Mahmood (Institute of Chemical Sciences, Bahauddin Zakariya University) ;
  • Zafar, Shagufta (Department of Chemistry, The Govt Sadiq College Women University) ;
  • Buzdar, Abdul Rehman (Department of CSE, HITEC University) ;
  • Khan, Muhammad Ali (Institute of Chemical Sciences, Bahauddin Zakariya University) ;
  • Mumtaz, Fatima (CAS Key Laboratory of Soft Matter Chemistry, Lab of Functional Membranes, School of Chemistry and Material Science, University of Science and Technology of China) ;
  • Prapamonthon, Prasert (Department of Thermal Science & Energy Engineering, University of Science and Technology of China) ;
  • Akhtar, Mehwish (Department of Chemistry, The Govt Sadiq College Women University)
  • Received : 2016.10.26
  • Accepted : 2017.06.03
  • Published : 2018.03.25
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Abstract

In this work, batch adsorption of anionic dye acid green-25 (AG-25) from aqueous solution has been carried out at room temperature using anion exchange membrane (DF-120B) as a noval adsorbent. The effect of various experimental parameters such as contact time, membrane dosage, ionic strength and temperature on the adsorption of dye were investigated. Kinetic models namely pseudo-first-order, pseudo-second-order, Elovich, liquid film diffusion, Bangham and modified freundlich models were employed to evaluate the experimental data. Parameters like adsorption capacities, rate constant and related correlation coefficients for every model are calculated and discussed. It showed that adsorption of AG-25 onto DF-120B followed pseudo-first-order rate expression. Thermodynamic study indicates that adsorption of AG-25 onto DF-120B is an exothermic and spontaneous process.

Keywords

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