Membrane and Water Treatment

  • 제9권1호
  • /
  • Pages.17-21
  • /
  • 2018
  • /
  • 2005-8624(pISSN)
  • /
  • 2092-7037(eISSN)
테크노프레스 (Techno-Press)
권호 표지
DOI QR코드

DOI QR Code

Treatment of natural rubber wastewater by membrane technologies for water reuse

  • 투고 : 2016.07.26
  • 심사 : 2017.07.31
  • 발행 : 2018.01.25
⟨ 이전 논문 다음 논문 ⟩

초록

A series of laboratory scale experiments were performed to investigate the feasibility of membrane separation technology for natural rubber (NR) wastewater treatment and reuse. Three types of spiral wound membranes were employed in the cross-flow experiments. The NR wastewater pretreated by sand filtration and cartridge filtration was forced to pass through the ultrafiltration (UF), nanofiltration (NF) and reverse osmosis (RO) membranes successively. The UF retentate, which containing abundant proteins, can be used to produce fertilizer, while the NF retentate is rich in quebrachitol and can be used to extract quebrachitol. The permeate produced by the RO module was reused in the NR processing. Furthermore, about 0.1wt% quebrachitol was extracted from the NR wastewater. Besides, the effluent quality treated by the membrane processes was much better than that of the biological treatment. Especially for total dissolved solids (TDS) and total phosphorus (T-P), the removal efficiency improved 53.11% and 49.83% respectively. In addition, the removal efficiencies of biological oxygen demand (BOD) and chemical oxygen demand (COD) exceeded 99%. The total nitrogen (T-N) and ammonia nitrogen (NH4-N) had approximately similar removal efficiency (93%). It was also found that there was a significant decrease in the T-P concentration in the effluent, the T-P was reduced from 200 mg/L to 0.34 mg/L. Generally, it was considered to be a challenging problem to solve for the biological processes. In brief, highly resource utilization and zero discharge was obtained by membrane separation system in the NR wastewater treatment.

키워드

참고문헌

  1. Bernardes, A.M. (2014), Electrodialysis and Water Reuse, Springer-Verlag, Heidelberg, Germany.
  2. Cartinella, J.L., Cath, T.Y., Flynn, M.T., Miller, G.C., Hunter, K. W. and Childress, A.E. (2006), "Removal of natural steroid hormones from wastewater using membrane contactor processes", Environ. Sci. Technol., 40(23), 7381-7386. https://doi.org/10.1021/es060550i
  3. Collins, J.H., Salmen, K.S., Musale D.A., Yoon, S.H. and Ward, W.J. (2005), Method of Using Water Soluble Polymers in a Membrane Biological Reactor, U.S. Patent No. 6,926,832, U.S. Patent and Trademark Office, Washington, D.C., U.S.A.
  4. Dong, K. (2007), "Membrane characterization and pilot study of the nanofiltration membrane", M.Sc. Dissertation, Jiangnan University, Wuxi, Jiangsu, China.
  5. Fersi, C. and Dhahbi, M. (2008), "Treatment of textile plant effluent by ultrafiltration and/or nanofiltration for water reuse", Desalination, 222(1-3), 263-271. https://doi.org/10.1016/j.desal.2007.01.171
  6. Fersi, C., Gzara, L. and Dhahbi, M. (2005), "Treatment of textile effluents by membrane technologies", Desalination, 185(1-3), 399-409. https://doi.org/10.1016/j.desal.2005.03.087
  7. Ghaffour, N., Naceur, M.W., Drouiche, N., and Mahmoudi, H. (2009), "Use of ultrafiltration membranes in the treatment of refinery wastewaters", Desalin. Water Treat., 5(1-3), 159-166. https://doi.org/10.5004/dwt.2009.580
  8. Gonder, Z.B., Arayici, S. and Barlas, H. (2011), "Advanced treatment of pulp and paper mill wastewater by nanofiltration process: Effects of operating conditions on membrane fouling", Sep. Purif. Technol., 76(3), 292-302. https://doi.org/10.1016/j.seppur.2010.10.018
  9. Gopal, R., Kaur, S., Ma, Z., Chan, C., Ramakrishna, S. and Matsuura T. (2006), "Electrospun nanofibrous filtration membrane", J. Membr. Sci., 281(1), 581-586. https://doi.org/10.1016/j.memsci.2006.04.026
  10. Gopalakrishnan, J., Thomas, M. and Jacob, J. (2010), A Process for Obtaining Pure L-Quebrachitol from Rubber Latex Serum, India Patent No. 238511, Rubber Research Institute of India.
  11. He, Y.P. (2007), Natural Rubber Processing, Hainan Press, Haikou, China.
  12. Jiang, S.K., Zhang, G.M., Wu, Y., Meng, Z.H. and Xue, M. (2014), "Isolation and characterization of L-quebrachitol from rubber factory wastewater", J. Rubb. Res., 17(1), 23-23.
  13. Judd, S. and Judd, C. (2011), The MBR Book: Principles and Applications of Membrane Bioreactors for Water and Wastewater Treatment, Elsevier, Amsterdam, The Netherlands.
  14. Kiddle, J.J. (1995), "Quebrachitol: A versatile building block in the construction of naturally occurring bioactive materials", Chem. Rev., 95(6), 2189-2196. https://doi.org/10.1021/cr00038a016
  15. Kumar, R.S., Arthanareeswaran, G., Paul, D. and Kweon, J.H. (2015), "Modification methods of polyethersulfone membranes for minimizing fouling-review", Membr. Water Treat., 6(4), 323-337. https://doi.org/10.12989/mwt.2015.6.4.323
  16. Melita, L., Gumrah, F., and Amareanu, M. (2014). "Porous polymer membranes used for wastewater treatment", Membr. Water Treat., 5(2), 147-170. https://doi.org/10.12989/mwt.2014.5.2.147
  17. Mohammadi, M., Man, H.C., Hassan, M.A. and Yee, P.L. (2013), "Treatment of wastewater from rubber industry in Malaysia", Afr. J. Biotechnol., 9(38), 6233-6243.
  18. Qin, J.J., Oo, M.H. and Coniglio, B. (2005), "Relationship between feed pH and permeate pH in reverse osmosis with town water as feed", Desalination, 177(1-3), 267-272. https://doi.org/10.1016/j.desal.2004.11.022
  19. State Environmental Protection Administration (2009), Water and Wastewater Monitoring and Analysis Methods, China Environmental Science Press, Beijing, China.
  20. Sulaiman, N.M.N., Ibrahim, S. and Abdullah, S.L. (2010), "Membrane bioreactor for the treatment of natural rubber wastewater", J. Environ. Eng., 2(1-3), 92-109.
  21. White, J.R. and De, S.K. (2001), Rubber Technologist's Handbook, Rapra Technology Limited, U.K.
  22. Wu, Y., Jiang, S.K., Li, G.H., Zhang, G.M., Zou, J.Y. and Xu, R. (2016), Method for Large-scale Extraction of L-quebrachitol from Natural Rubber Industry Waste Water, U.S. patent No. 94,22,214, U.S. Patent and Trademark Office, Washington, DC, U.S.A.
  23. Yahiaoui, O., Lounici, H., Abdi, N., Drouiche, N., Ghaffour, N., Pauss, A. and Mameri, N. (2011), "Treatment of olive mill wastewater by the combination of ultrafiltration and bipolar electrochemical reactor processes", Chem. Eng. Process. Proc. Intens., 50(1), 37-41. https://doi.org/10.1016/j.cep.2010.11.003

피인용 문헌

  1. Developing a composite vertical flow constructed wetlands for rainwater treatment vol.11, pp.2, 2018, https://doi.org/10.12989/mwt.2020.11.2.087
  2. Performance of thin film composite membranes for ammonium removal and reuse of ammonium-enriched solution for plant growth vol.21, pp.1, 2018, https://doi.org/10.2166/ws.2020.295
  3. Monosodium glutamate as a draw solute for sewage thickening by forward osmosis-nanofiltration vol.12, pp.4, 2021, https://doi.org/10.12989/mwt.2021.12.4.165