DOI QR코드

DOI QR Code

Study of chemical coagulation conditions for a disperse red dye removal from aqueous solutions

  • Tiaiba, Mohammed (Laboratoire d'Hydrologie Appliquee et Environnement, Centre Universitaire d'Ain Temouchent) ;
  • Merzouk, Belkacem (Departement Hydraulique, Faculte de Technologie, Universite Mohamed Boudiaf de M'sila) ;
  • Mazour, Mohammed (Laboratoire d'Hydrologie Appliquee et Environnement, Centre Universitaire d'Ain Temouchent) ;
  • Leclerc, Jean P. (Laboratoire Reactions et Genie des Procedes (LRGP) UMR 7274, CNRS, Universite de Lorraine) ;
  • Lapicque, Francois (Laboratoire Reactions et Genie des Procedes (LRGP) UMR 7274, CNRS, Universite de Lorraine)
  • 투고 : 2016.06.23
  • 심사 : 2017.05.25
  • 발행 : 2018.01.25

초록

Coagulation process using aluminum sulfate ($Al_2(SO_4)_3$) and ferric chloride ($FeCl_3$) was employed as a treatment method for decolorization of a synthetic textile wastewater containing red dye in this paper. Factors such as initial pH, coagulant dosage, initial concentration, conductivity and mixing conditions that influence color removal efficiency were experimentally tested. It was found that $Al_2(SO_4)_3$ is more efficient than $FeCl_3$ as coagulant. When $40mgL^{-1}$ aluminum sulfate was used, results showed that color induced by the red dye was efficiently removed (> 90 %) and was obtained in a large range of initial pH from 4 to 8 with, and for a dye concentration lower than $235mg\;L^{-1}$. After addition of the coagulant, the medium had to be mixed for 30 min at 60 rpm, then allowed to settle for 40 min. The effects of water conductivity in the range $0.035-2.42mS\;cm^{-1}$ and dye concentration up to $380mg\;L^{-1}$ were also followed and discussed.

키워드

참고문헌

  1. Adjeroud, N., Dahmoune, F., Merzouk, B., Leclerc, J.P. and Madani, K. (2015), "Improvement of electrocoagulationelectroflotation treatment of effluent by addition of Opuntia ficus indica pad juice", Sep. Purif. Technol., 144, 168-176. https://doi.org/10.1016/j.seppur.2015.02.018
  2. Alinsafi, A., Khemis, M., Pons, M.N., Leclerc, J.P., Yaacoubi, A., Benhammou, A. and Nejmeddine, A. (2005), "Electrocoagulation of reactive textile dyes and textile wastewater", Chem. Eng. Process. 44(4), 461-470. https://doi.org/10.1016/j.cep.2004.06.010
  3. Amokrane, A., Cornel, C. and Veron, J. (1997), "Landfill leachates pretreatment by coagulation-flocculation", Water Res., 31(11), 2775-2782. https://doi.org/10.1016/S0043-1354(97)00147-4
  4. Arslan, I.A., Isil, A.B. and Detlef, W.B. (2002), "Advanced oxidation of a reactive dye bath effluent: Comparison of $O_3$, $H_2O_2$/UV-C and $TiO_2$/UV-A processes", Water Res., 36(5), 1143-1154. https://doi.org/10.1016/S0043-1354(01)00335-9
  5. Attour, A., Touati, M., Tlili, M., Ben Amor, M., Lapicque, F. and Leclerc, J.P. (2014), "Influence of operating parameters on phosphate removal from water by electrocoagulation using aluminum electrodes", Sep. Purif. Technol., 123, 124-129. https://doi.org/10.1016/j.seppur.2013.12.030
  6. Barka, N., Qourzal, S., Assabbane, A., Nounah, A. and Ait-Ichou, Y. (2011), "Removal of reactive yellow 84 from aqueous solutions by adsorption onto hydroxyapatite", J. Saudi Chem. Soc., 15(3), 263-267. https://doi.org/10.1016/j.jscs.2010.10.002
  7. Bayramoglu, M., Eyvaz, M. and Kobya, M. (2007), "Treatment of the textile wastewater by electrocoagulation: Economical evaluation", Chem. Eng. J., 128, 155-161. https://doi.org/10.1016/j.cej.2006.10.008
  8. Can, O.T., Kobya, M., Demirbas, E. and Bayramoglu, M. (2006), "Treatment of the textile wastewater by combined electrocoagulation", Chemosphere, 62(2), 181-187. https://doi.org/10.1016/j.chemosphere.2005.05.022
  9. Canizares, P., Jimenez, C., Martinez, F., Rodrigo, M.A. and Saez, C. (2009), "The pH as a key parameter in the choice between coagulation and electrocoagulation for the treatment of wastewaters", J. Hazard. Mater., 163(1), 158-164. https://doi.org/10.1016/j.jhazmat.2008.06.073
  10. Chafi, M., Gourich, B., Essadki, A.H., Vial, C., and Fabregat, A. (2011), "Comparison of electrocoagulation using iron and aluminium electrodes with chemical coagulation for the removal of a highly soluble acid dye", Desalination, 281, 285-292. https://doi.org/10.1016/j.desal.2011.08.004
  11. Cook, W.G. and Olive, R.P. (2012), "Pourbaix diagrams for the iron-water system extended to high-subcritical and lowsupercritical conditions", Corros. Sci., 55, 326-331. https://doi.org/10.1016/j.corsci.2011.10.034
  12. Daneshvar, N., Oladegaragoze, A. and Djafarzadeh, N. (2006), "Decolorization of basic dye solutions by electrocoagulation: An investigation of the effect of operational parameters", J. Hazard. Mater., 129(1), 116-122. https://doi.org/10.1016/j.jhazmat.2005.08.033
  13. Drouiche, N., Aoudj, S., Lounici, H., Drouiche, M., Ouslimane, T. and Ghaffour, N. (2012), "Fluoride removal from pretreated photovoltaic wastewater by electrocoagulation: An investigation of the effect of operational parameters", Proc. Eng., 33, 385-391. https://doi.org/10.1016/j.proeng.2012.01.1218
  14. Duan, J. and Gregory, J. (2003), "Coagulation by hydrolysing metal salts", Adv. Colloid Interfac. Sci., 100, 475-502.
  15. Essadki, A.H., Bennajah, M., Gourich, B., Vial, Ch., Azzi, M. and Delmas, H. (2007), "Electrocoagulation/electroflotation in an external-loop airlift reactor - application to the decolorization of textile dye wastewater: A case study", Chem. Eng. Process., 47(8), 1211-1223. https://doi.org/10.1016/j.cep.2007.03.013
  16. Guida, M., Mattei, M., Rocca, C.D., Melluso, G. and Meric, S. (2007), "Optimization of alum-coagulation/flocculation for COD and TSS removal from five municipal wastewater", Desalination, 211(1-3), 113-127. https://doi.org/10.1016/j.desal.2006.02.086
  17. Holt, P.K., Barton, G.W., Wark, M. and Mitchell, C.A. (2002), "A quantitative comparison between chemical dosing and electrocoagulation", Colloid. Surface. A, 211(2), 233-248. https://doi.org/10.1016/S0927-7757(02)00285-6
  18. Jiang, J.Q. and Graham, J.D. (1996), "Enhanced coagulation using Al/Fe(III) coagulants: Effect of coagulant chemistry on the removal of color-causing NOM", Environ. Technol., 17(9), 937-950. https://doi.org/10.1080/09593330.1996.9618422
  19. Joo, D.J., Shin, W.S., Choi, J.H., Choi, S.J., Kim, M.C., Han, M.H., Ha, T.W. and Kim, Y.H. (2007), "Decolorization of reactive dyes using inorganic coagulants and synthetic polymer", Dyes Pigments, 73(1), 59-64. https://doi.org/10.1016/j.dyepig.2005.10.011
  20. Joseph, L., Flora, Joseph R.V., Park, Y.G., Badawy, M., Yoon, Y. and Saleh, H. (2012), "Removal of natural organic matter from potential drinking water sources by combined coagulation and adsorption using carbon nanomaterials", Sep. Purif. Technol., 95, 64-72. https://doi.org/10.1016/j.seppur.2012.04.033
  21. Kim, S., Park, C., Kim, T.H., Lee, J. and Kim, S.W. (2003), "COD reduction and decolorization of textile effluent using a combined process", J. Biosci. Bioeng., 95(1), 102-105. https://doi.org/10.1016/S1389-1723(03)80156-1
  22. Kim, T.H., Park, C., Shin, E. and Kim, S. (2002), "Decolorization of disperse and reactive dyes by continuous electrocoagulation process", Desalination, 150(2), 165-175. https://doi.org/10.1016/S0011-9164(02)00941-4
  23. Kim, T.H., Park, C., Shin, E.B. and Kim, S. (2004), "Decolorization of disperse and reactive dye solutions using ferric chloride", Desalination, 161(1), 49-58. https://doi.org/10.1016/S0011-9164(04)90039-2
  24. Kobya, M., Can, O.T. and Bayramoglu, M. (2003), "Treatment of textile wastewaters by electrocoagulation using iron and aluminum electrodes", J. Hazard. Mater., 100(1), 163-178. https://doi.org/10.1016/S0304-3894(03)00102-X
  25. Lee, J.W., Choil, S.P., Thiruvenkatachari, R. and Shim, W.G. (2006), "Submerged microfiltration membrane coupled with alum coagulation/powdered activated carbon adsorption for complete decolorization of reactive dyes", Water Res., 40(3), 435-444. https://doi.org/10.1016/j.watres.2005.11.034
  26. Lefebvre, E. and Legube, B. (1990), "Coagulation par Fe(III) de substances humiques extraites d'eaux de surface: Effet du pH et de la concentration en substances humiques", Water Res., 24(5), 591-606. https://doi.org/10.1016/0043-1354(90)90192-9
  27. Li, W., Hua, T., Zhou, Q., Zhang, S. and Fengxiang, L. (2010), "Treatment of stabilized landfill leachate by the combined process of coagulation/flocculation and powder activated carbon adsorption", Desalination, 264(1), 56-62. https://doi.org/10.1016/j.desal.2010.07.004
  28. Lin, S.H. and Peng, C.F. (1994), "Treatment of textile wastewater by electrochemical method", Water Res., 28 (2), 277-283. https://doi.org/10.1016/0043-1354(94)90264-X
  29. Lin, S.H. and Peng, C.F. (1996), "Continuous treatment of textile wastewater by combined coagulation, electrochemical oxidation and activated sludge", Water Res., 30(3), 587-592. https://doi.org/10.1016/0043-1354(95)00210-3
  30. Matilainen, A., Vepsalainen, M. and Sillanpaa, M. (2010), "Natural organic matter removal by coagulation during drinking water treatment: A review", Adv. Colloid Interfac. Sci., 159(2), 189-197. https://doi.org/10.1016/j.cis.2010.06.007
  31. Merzouk, B., Gourich, B., Sekki, A., Madani, K., Vial, C. and Barkaoui, M. (2009), "Studies on the decolorization of textile dye wastewater by continuous electrocoagulation process", Chem. Eng. J., 149(1), 207-214. https://doi.org/10.1016/j.cej.2008.10.018
  32. Merzouk, B., Gourich, B., Sekki, A., Madani, K. and Chibane, M. (2009), "Removal turbidity and separation of heavy metals using electrocoagulation-electroflotation technique: A case study", J. Hazard. Mater., 164(1), 215-222. https://doi.org/10.1016/j.jhazmat.2008.07.144
  33. Mo, J., Hwang, J.E., Jegal, J. and Kim, J. (2007), "Pretreatment of a dyeing wastewater using chemical coagulants, Dyes Pigments, 72(2), 240-245. https://doi.org/10.1016/j.dyepig.2005.08.022
  34. Moghaddam, S.S., Moghaddam, M.R. and Arami, M. (2010), "Coagulation/flocculation process for dye removal using sludge from water treatment plant: Optimization through response surface methodology", J. Hazard. Mater., 175(1), 651-657. https://doi.org/10.1016/j.jhazmat.2009.10.058
  35. Mollah, M.Y.A., Pathak, S.R., Patil, P.K., Vayuvegula, M., Agrawal, T.S., Gomes, J.A.G., Kesmez, M. and Cocke, D.L. (2004), "Treatment of orange II azo-dye by electrocoagulation (EC) technique in a continuous flow cell using sacrificial iron electrodes", J. Hazard. Mater., 109(1), 165-171. https://doi.org/10.1016/j.jhazmat.2004.03.011
  36. Olthof, M. and Eckenfelder, W.W. (1976), "Coagulation of textile wastewater", Text. Chem. Color., 8(7), 18-22.
  37. Papic, S. Koprivanac, N., Bozic, A.L. and Metes, A. (2004), "Removal of some reactive yes from synthetic wastewater by combined Al(III) coagulation/carbon adsorption process", Dyes Pigments, 62(3), 291-298. https://doi.org/10.1016/S0143-7208(03)00148-7
  38. Pela, A. and Tokat, E. (2002), "Color removal from cotton textile industry wastewater in an activated sludge system with various additives", Water Res., 36(11), 2920-2925. https://doi.org/10.1016/S0043-1354(01)00529-2
  39. Rasorio, L.C., Abel, G.E. and Marta, I.L. (2002), "Photo degradation of an azo dye of the textile industry", Chemosphere, 48(4), 393-399. https://doi.org/10.1016/S0045-6535(02)00117-0
  40. Rossini, M., Garrido, J.G. and Galluzo, M. (1999), "Optimization of the coagulation-flocculation treatment: Influence of rapid mix parameters, Water Res., 33(8), 1817-1826. https://doi.org/10.1016/S0043-1354(98)00367-4
  41. Sanchez Calvo, L., Leclerc, J.P., Tanguy, G., Cames, M.-C., Paternotte, G., Valentin, G., Rostan, A. and Lapicque, F. (2003), "An electrocoagulation unit for the purification of soluble oil wastes of high COD", Environ. Prog., 22(1), 57-65. https://doi.org/10.1002/ep.670220117
  42. Selcuk, H., Kaptan, D. and Meric, S. (2004), "Coagulation of textile wastewater using alum and Fe(III) salts", Fresen. Environ. Bull., 13(10), 1045-1048.
  43. Semmens, M.J. and Field, T.K. (1980), "Coagulation: Experiences in organics removal", J. Am. Water Works. Assoc., 72(8), 476-483. https://doi.org/10.1002/j.1551-8833.1980.tb04557.x
  44. Sengil, I.A. and Ozdemir, A. (2012), "Simultaneous decolorization of binary mixture of blue disperse and yellow basic dyes by electrocoagulation", Des. Water Treat., 46 (1-3), 215-226. https://doi.org/10.1080/19443994.2012.677554
  45. Shen, Y.S. and Wang, D.K. (2002), "Development of photoreactor design equation for the treatment of dye wastewater by UV/$H_2O_2$ process", J. Hazard. Mater., 89(2), 267-277. https://doi.org/10.1016/S0304-3894(01)00317-X
  46. Stanislaw, L., Monika, S. and Renata, Z. (2001), "Biodegradation, decolorization and detoxification of textile wastewater enhanced by advanced oxidation processes", J. Biotechnol., 89(2), 175-184. https://doi.org/10.1016/S0168-1656(01)00296-6
  47. Szygu1a, A., Guibal, E., Palacin, M.A. Ruiz, M. and Sastre, A.M. (2009), "Removal of an anionic dye (Acid Blue 92) by coagulation-flocculation using chitosan", J. Environ. Manage., 90(10), 2979-2986. https://doi.org/10.1016/j.jenvman.2009.04.002
  48. Tahri, N., Masmoudi, G., Ellouze, E., Jrad, A., Drogui, P. and Ben Amar, R. (2012), "Coupling microfiltration and nanofiltration processes for the treatment at source of dyeing-containing effluent", J. Clean. Prod., 33, 226-235. https://doi.org/10.1016/j.jclepro.2012.03.025
  49. Tan, B.H., Teng, T.T. and Mohd Omar, A.K. (2000), "Removal of dyes and industrial dye wastes by magnesium chloride", Water Res., 34(2), 597-601. https://doi.org/10.1016/S0043-1354(99)00151-7
  50. Van der Bruggen, B., Curcio, E. and Drioli, E. (2004), "Process intensification in the textile industry: The role of membrane technology", J. Environ. Manage., 73(3), 267-274. https://doi.org/10.1016/j.jenvman.2004.07.007
  51. Verma, A.K., Bhunia, P. and Dash, R.R. (2014), "Chemical coagulation and sonolysis for total aromatic amines removal from anaerobically pre-treated textile wastewater: A comparative study", Adv. Environ. Res., 3(4), 293-306. https://doi.org/10.12989/aer.2014.3.4.293
  52. Verma, A.K., Dash, R.R. and Bhunia, P. (2012), "A review on chemical coagulation/flocculation technologies for removal of colour from textile wastewaters", J. Environ. Manage., 93(1), 154-168. https://doi.org/10.1016/j.jenvman.2011.09.012
  53. Zerrouki, D., Benhadji, A., Taleb Ahmed, M., Djelal, H. and Maachi, R. (2014), "Treatment of a dye solophenyle 4GE by coupling electrocoagulation/nanofiltration", Membr. Water Treat., 5(4), 251-263. https://doi.org/10.12989/mwt.2014.5.4.251
  54. Zodi, S., Potier, O., Lapicque, F. and Leclerc, J.P. (2010), "Treatment of the industrial wastewaters by electrocoagulation: Optimization of coupled electrochemical and sedimentation processes", Desalination, 261(1), 186-190. https://doi.org/10.1016/j.desal.2010.04.024
  55. Zodi, S., Potier, O., Michon, C., Poirot, H., Valentin, G., Leclerc, J.P. and Lapicque, F. (2011), "Removal of arsenic and COD from industrial wastewaters by electrocoagulation", J. Electrochem. Sci. Eng., 1(1), 53-63.

피인용 문헌

  1. Amphiphilic Calcium Alginate Carbon Aerogels: Broad-Spectrum Adsorbents for Ionic and Solvent Dyes with Multiple Functions for Decolorized Oil-Water Separation vol.8, pp.34, 2020, https://doi.org/10.1021/acssuschemeng.0c00129
  2. Fluoride removal using Alum & PACl in batch & continuous mode with subsequent microfiltration vol.12, pp.2, 2018, https://doi.org/10.12989/mwt.2021.12.2.083