DOI QR코드

DOI QR Code

Characterization of PVDF/PU fibers prepared by electrospinning

  • Rho, Jeongwon (Department of Biomedical Engineering, Daelim University) ;
  • Lee, Deuk Yong (Department of Biomedical Engineering, Daelim University) ;
  • Lee, Myung-Hyun (Energy and Environmental Division, KICET) ;
  • Kim, Bae-Yeon (Department of Materials Science and Engineering, Incheon National University) ;
  • Jeong, Heeseok (Convergence Institute of Biomedical Engineering and Biomaterials, Seoul National University of Science and Technology)
  • Received : 2018.01.03
  • Accepted : 2018.01.19
  • Published : 2018.02.28

Abstract

The 23 wt% polyvinylidene fluoride (PVDF)/15 wt% polyurethane (PU) fibers were electrospun using the conjugated nozzle at a flow rate of 1.0 mL/h and an electric field of 1 kV/cm. The formation of ${\beta}$ crystal phase in the PVDF and the PVDF/PU fibers was confirmed by Fourier transform infrared spectroscopy. After electrospinning, the asspun fibers were immersed in a boiling water and then dried at $100^{\circ}C$ in a convection oven to make a crimp phenomenon. The crimps with a diameter of $2.0{\pm}0.08{\mu}m$ were observed for the PVDF/PU fibers after hydrothermal treatment without sacrificing the extent of ${\beta}$ crystal phase. All the PU, PVDF and PVDF/PU fibers exhibited average cell viability of more than 98 %. The cell proliferation results suggested that L-929 cells adhered well to the PU, PVDF and PVDF/PU fibers and proliferated continuously with increasing time, indicating that the PVDF/PU fibers are highly applicable to the biomedical applications.

Keywords

References

  1. H.J. Lee, T.M. Hong, S.C. Lim, J.S. Won and S.G. Lee, "Preparation and characterization of PVDF/PU bicomponent nanofiber by electrospinning", Textile Sci. Eng. 52 (2015) 88.
  2. C. Pan, C. Yen, S. Wang, Y. Lai, L. Lin, J.C. Huang and S. Kuo, "Near-field electrospinning enhances the energy harvesting of hollow PVDF piezoelectric fibers", RSC Adv. 5 (2015) 85073.
  3. K. Jeong and S. Kim, "Characterization of the PVDF fibers fabricated by hybrid wet spinning", Compos. Res. 29 (2016) 145.
  4. E. Nilsson, A. Lund, C. Jonasson, C. Johansson and B. Hagstrom, "Poling and characterization of piezoelectric polymer fibers for use in textile sensors", Sens. Actuators A 201 (2013) 477.
  5. S.Y. Lee, S.B. Kim, S.J. Choi, J.Y. Bang and H.S. Kim, "Studies on electrode integrated piezoelectric polyvinylidene difluoride (PVDF) fiber", Textile Sci. Eng. 53 (2016) 279.
  6. G.T. Davis, J.E. McKinney, M.G. Broadhurst and S.C. Roth, "Electric-field-induced phase changes in poly(vinylidene fluoride)", J. Appl. Phys. 49 (1978) 4998.
  7. S.M. Damaraju, S. Wu, M. Jaffe and T.L. Arinzeh, "Structural changes in PVDF fibers due to electrospinning and its effect on biological function", Biomed. Mater. 8 (2013) 045007.
  8. B. Seol, J. Shin, G. Oh, D.Y. Lee and M. Lee, "Characteristics of PU/PEG hybrid scaffolds prepared by electrospinning", J. Biomed. Eng. Res. 38 (2017) 248.
  9. J.T. Kim, D.Y. Lee, T. Kim, M. Lee and N. Cho, "Biocompatibility of hyaluronic acid hydrogel prepared by porous hyaluronic acid microbead", Met. Mater. Intl. 20 (2014) 555.
  10. J. Kim, D.Y. Lee, E. Kim, J. Jang and N. Cho, "Tissue response to implant of hyaluronic acid hydrogel prepared by microbeads", Tissue Eng. Regen. Med. 11 (2014) 32.
  11. Y. Kim, S. Son, C. Chun, J. Kim, D.Y. Lee, H.J. Choi and T. Kim, "Effect of PEG addition on pore morphology and biocompatibility of PLLA scaffolds prepared by freeze drying", Biomed. Eng. Lett. 6 (2016) 287.
  12. S. Son, J. Choi, H. Cho, D. Kang, D.Y. Lee, J. Kim and J. Jang, "Synthesis and characterization of porous poly(${\epsilon}$-caprolactone)/silica nanocomposites", Polym. Korea 39 (2015) 323.
  13. C. Chun, D.Y. Lee, J. Kim, M. Kwon, Y. Kim and S. Kim, "Effect of molecular weight of hyaluronic acid on viscoelastic and particle texturing feel properties of HA dermal biphasic fillers", Biomater. Res. 20 (2016) 275.