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Electrically conductive nano adhesive bonding: Futuristic approach for satellites and electromagnetic interference shielding

  • Ganesh, M. Gokul (Department of Aerospace Engineering, Amrita School of Engineering, Coimbatore, Amrita Vishwa Vidyapeetham, Amrita University) ;
  • Lavenya, K. (Department of Aerospace Engineering, Amrita School of Engineering, Coimbatore, Amrita Vishwa Vidyapeetham, Amrita University) ;
  • Kirubashini, K.A. (Department of Aerospace Engineering, Amrita School of Engineering, Coimbatore, Amrita Vishwa Vidyapeetham, Amrita University) ;
  • Ajeesh, G. (Department of Aerospace Engineering, Amrita School of Engineering, Coimbatore, Amrita Vishwa Vidyapeetham, Amrita University) ;
  • Bhowmik, Shantanu (Department of Aerospace Engineering, Amrita School of Engineering, Coimbatore, Amrita Vishwa Vidyapeetham, Amrita University) ;
  • Epaarachchi, Jayantha Ananda (School of Mechanical and Electrical Engineering, Faculty of Health, Engineering and Sciences, University of Southern Queensland) ;
  • Yuan, Xiaowen (School of Engineering and Advanced Technology, Massey University)
  • Received : 2017.01.24
  • Accepted : 2017.05.30
  • Published : 2017.11.25

Abstract

This investigation highlights rationale of electrically conductive nano adhesives for its essential application for Electromagnetic Interference (EMI) Shielding in satellites and Lightning Strike Protection in aircrafts. Carbon Nano Fibres (CNF) were functionalized by electroless process using Tollen's reagent and by Plasma Enhanced Chemical Vapour Deposition (PECVD) process by depositing silver on CNF. Different weight percentage of CNF and silver coated CNF were reinforced into the epoxy resin hardener system. Scanning Electron Microscopy (SEM) micrographs clearly show the presence of CNF in the epoxy matrix, thus giving enough evidence to show that dispersion is uniform. Transmission Electron Microscopy (TEM) studies reveal that there is uniform deposition of silver on CNF resulting in significant improvement in interfacial adhesion with epoxy matrix. There is a considerable increase in thermal stability of the conductive nano adhesive demonstrated by Differential Scanning Calorimetry (DSC) and Thermogravimetric Analysis (TGA). Four probe conductivity meters clearly shows a substantial increase in the electrical conductivity of silver coated CNF-epoxy composite compared to non-coated CNF-epoxy composite. Tensile test results clearly show that there is a significant increase in the tensile strength of silver coated CNF-composites compared to non-coated CNF-epoxy composites. Consequently, this technology is highly desirable for satellites and EMI Shielding and will open a new dimension in space research.

Keywords

References

  1. Amoli, B.M., Trinidad, J., Hu, A. and Zhou, B. (2015), "Highly electrically conductive adhesives using silver nanoparticle (Ag NP)-decorated graphene: The effect of NPs sintering on the electrical conductivity improvement", J. Mater. Sci. Mater. Electr., 26(1), 598-600.
  2. Billias, M.G. and Borders, M.E. (1984), Patent US 4428867 A, Lockheed Corporation.
  3. Burton, D., Lake, P. and Palmer, A. Carbon Nanofiber Applications & Properties.
  4. Chen, D., Qiao, Z., Qiu, X., Tan, F., Chen, J. and Jiang, R. (2010), "Effect of silver nanostructures on the resistivity of electrically conductive adhesives composed of silver flakes", J. Mater. Sci. Mater. Electr., 21(5), 487-490.
  5. Datsyuk, V., Dagreou, S., Billon, L., Dupin, J.C. and Flahaut, E. (2005), "Double walled carbon nanotube/polymer composites via in situ nitrooxide mediated polymerization of amphiphilic block copolymers", Carbon, 43(4), 853-894.
  6. Gagne, M. and Therriault, D. (2014), "Lightning strike protection of composites", Progr. Aerosp. Sci., 64, 1-16. https://doi.org/10.1016/j.paerosci.2013.07.002
  7. Gohel, A., Zhu, Y.W., Sow, C.H. and Wee, A.T.S. (2005), "Field emission properties of N2 and Ar plasma treated multi wall carbon nanotubes", Carbon, 43(15), 2530-2535. https://doi.org/10.1016/j.carbon.2005.05.003
  8. Guadagno, L., Raimondo, M., Vertuccio, L., Mauro, M., Guerra, G., Lafdi, L., De Vivo, B., Lamberti, P., Spinelli, G. and Tucci, V. (2015), "Optimization of graphene-based materials outperforming host epoxy matrices", RSC Adv., 5(46), 36969-36978. https://doi.org/10.1039/C5RA04558D
  9. Guadagno, L., Raimondo, M., Vittoria, V., Vertuccio, L., Lafdi, L., De Vivo, B., Lamberti, P., Spinelli, G. and Tucci, V. (2013), "The role of carbon nanofiber defects on the electrical and mechanical properties of CNF-based resins", Nanotechnol., 24(30), 305704. https://doi.org/10.1088/0957-4484/24/30/305704
  10. Guadagno, L., Raimondo, M., Vittoria, V., Vertuccio, L., Naddeo, C., Russo, S., De Vivo, B., Lamberti, P., Spinelli, G. and Tucci, V. (2014), "Development of epoxy mixtures for application inaeronautics and aerospace", RSC Adv., 4(30), 15474-15488. https://doi.org/10.1039/C3RA48031C
  11. Hohne, G.W.H., Hemminger, W. and Flammershein. (1996), Differential Scanning Calorimetry: An Introduction for Practitioners, 1st Edition, Springer.
  12. Li, Y., Lu, D. and Wong, C.P. (2010), Electrically Conductive Adhesives with Nanotechnologies, 1st 17th Edition, Springer.
  13. Nobile, M.R., Raimondo, M., Lafdi, K., Fierro, A., Rosolia, S. and Guadagno, L. (2015), "Relationships between nanofiller morphology and viscoelastic properties in CNF/epoxy resins", Polym. Compos., 36(6), 1152-1160. https://doi.org/10.1002/pc.23362
  14. Sancaktar, E. and Bai, L. (2011), "Electrically conductive epoxy adhesives", Polym., 3, 1-3.
  15. Shaheen, J.M. and Leo, Q.J. (1979), Patent US 4147669 A, Rockwell Int. Corp.
  16. Simone, D., Angeliu, T., Tonapi, S., Gibson, D. and Zhang, J. (2007), Patent US 20070131912 A1.
  17. Tan, F., Qiao, X., Chen, J. and Wang, H. (2006), "Effects of coupling agents on the properties of epoxybased electrically conductive adhesives", J. Adhes. Adhes., 26(6), 409-413.
  18. Vietri, U., Guadagno, L., Raimondo, M., Vertuccio, L. and Lafdi, K. (2014), "Nanofilled epoxy adhesive for structural aeronautic materials", Compos. Part B: Eng., 61, 73-83. https://doi.org/10.1016/j.compositesb.2014.01.032
  19. Wu, H.P., Wu, X.J., Ge, M., Zhang, G.Q., Wang, Y. and Jiang, J. (2007), "Properties investigation on isotropic conductive adhesives filled with silver coated carbon nanotubes", Compos. Sci. Technol., 67(6), 1183-1186.

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