Membrane and Water Treatment

  • 제8권5호
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  • Pages.483-498
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  • 2017
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  • 2005-8624(pISSN)
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  • 2092-7037(eISSN)
테크노프레스 (Techno-Press)
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DOI QR코드

DOI QR Code

Study of enhanced physical and pervaporation properties in composite membrane

  • RajiniKanth, Vanarch (Department of Physics, College of Science, Engineering and Technology, University of South Africa) ;
  • Ravindra, Sakey (Department of Physics, College of Science, Engineering and Technology, University of South Africa) ;
  • Madalageri, Priya M (Department of Physics, College of Science, Engineering and Technology, University of South Africa) ;
  • Kajjari, Praveen B. (Department of Chemistry, Karnatak University) ;
  • Mulaba-Bafubiandi, Antoine F (Department of Extraction Metallurgy, Doornfontein Campus, Faculty of Engineering and the Built Environment, University of Johannesburg)
  • 투고 : 2016.03.21
  • 심사 : 2017.05.25
  • 발행 : 2017.09.25
⟨ 이전 논문 다음 논문 ⟩

초록

Novel mixed matrix membranes of Sodium Alginate (NaAlg) were developed by the incorporation ofunmodified, modified Phosphomolybdic acid (PMA) then cross-linked with glutaraldehyde externally. These membranes were prepared by the solution casting technique. Pervaporation (PV) experiments have been performed with pure NaAlg, unmodified NaAlg-PMA5, NaAlg-PMA10, modified NaAlg-mPMA5, and NaAlg-mPMA10 (wt. % of PMA 5 and 10) at 30, 40 and $50^{\circ}C$, to separate water-isopropanol feed mixtures containing 10-30 wt. % of water. Pervaporation results of NaAlg-mPMA10 produced a highest separation factor of 9028 with a flux of $0.269kg/m^2.h$ for 10 wt. % of water containing feed mixture. Both separation factor and flux for water increased significantly with increasing content of mPMA into NaAlg; a significant improvement in PV performance was observed for NaAlg-mPMA5 and NaAlg-mPMA10 membranes when compared to pure NaAlg& PMA-5, PMA-10 membrane.

키워드

참고문헌

  1. Adoor, S.G., Prathab, B., Manjeshwar, L.S. and Aminabhavi, T.M. (2007), "Mixed matrix membranes of sodium alginate and poly (vinyl alcohol) for pervaporation dehydration of isopropanol at different temperatures", Polym., 48, 5417-5430. https://doi.org/10.1016/j.polymer.2007.06.064
  2. Adoor, S.G., Rajineekanth, V., Nadagouda, M.N., Rao, K.C., Dionysiou, D.D. and Aminabhavi, T.M. (2013), "Exploration of nanocomposite membranes composed of phosphotungstic acid in sodium alginate for separation of aqueous-organic mixtures by pervaporation", Sep. Purif. Technol., 113, 64-74. https://doi.org/10.1016/j.seppur.2013.03.051
  3. Avagimova, N., Polotskaya, G., Saprykina, N., Toikka, A. and Pientka, Z. (2013), "Mixed matrix membranes based on polyamide/montmorillonite for pervaporation of methanol-toluene mixture", Sep. Purif. Technol., 48(17), 2513-2523
  4. Babanzadeh, S., Mehdipour-Ataei, S., and Mahjoub, A.R. (2012), "Preparation and characterization of novel polyimide/SiO2 nano-hybrid films by in situ polymerization", J. Inorg. Organomet. Polym., 22(6), 1404. https://doi.org/10.1007/s10904-012-9764-y
  5. Bai, Y., Dong, L., Zhang, C., Gu, J., Sun, Y., Zhang, L. and Chen, H. (2013), "ZIF-8 filled polydimethylsiloxane membranes for pervaporative separation of n-butanol from aqueous solution", Separ. Sci. Technol., 48(17), 2531-2539. https://doi.org/10.1080/01496395.2013.811424
  6. Bhat, S.D. and Aminabhavi, T.M. (2006), "Novel sodium alginate composite membranes incorporated with SBA-15 molecular sieves for the pervaporation dehydration of aqueous mixtures of isopropanol and 1, 4-dioxane at 30 C", Micropor. Mesopor. Mater., 91(1), 206-214. https://doi.org/10.1016/j.micromeso.2005.11.044
  7. Bhat, S.D., Mallikarjuna, N.N. and Aminabhavi, T.M. (2006), "Microporous alumino-phosphate (AlPO 4-5) molecular sieve-loaded novel sodium alginate composite membranes for pervaporation dehydration of aqueous-organic mixtures near their azeotropic compositions", J. Membr. Sci., 282, 473-483. https://doi.org/10.1016/j.memsci.2006.06.006
  8. Bhat, S.D., Naidu, B.V.K., Shanbhag, G.V., Halligudi, S.B., Sairam, M. and Aminabhavi, T.M. (2006), "Mesoporous molecular sieve (MCM-41)-filled sodium alginate hybrid nanocomposite membranes for pervaporation separation of water-isopropanol mixtures", Sep. Sci. Technol., 49, 56-63.
  9. Bhat, S.D., Sahu, A.K., Jalajakshi, A., Pitchumani, S., Sridhar, P., George, C. ... and Shukla, A.K. (2010), "PVA-SSA-HPA Mixed-Matrix-Membrane electrolytes for DMFCs fuel cells and energy conversion", J. Electrochem. Soc., 157(10), 1403-1412. https://doi.org/10.1149/1.3465653
  10. Bhat, S.D. and Aminabhavi, T.M. (2006), "Novel sodium alginate-Na+ MMT hybrid composite membranes for pervaporation dehydration of isopropanol, 1, 4-dioxane and tetrahydrofuran", Sep. Sci. Technol., 51, 85-94.
  11. Cao, S., Shi, Y. and Chen, G. (2000), "Influence of acetylation degree of cellulose acetate on pervaporation properties for MeOH/MTBE mixture", J. Membr. Sci., 165, 89-97. https://doi.org/10.1016/S0376-7388(99)00222-7
  12. Chanachai, A., Jiraratananon, R., Uttapap, D., Moon, G.Y., Anderson, W.A. and Huang, R.Y.M. (2000), "Pervaporation with chitosan/hydroxyethylcellulose (CS/HEC) blended membranes", J. Membr. Sci., 166, 271-280. https://doi.org/10.1016/S0376-7388(99)00269-0
  13. Fischer, F.G., Dorfel, H. and Hoppe-Seyler's. Z. (1955), "The paper chromatographic separation and determination of hexuronic acids", Physiol. Chem., 302, 224-234.
  14. Gao, Z., Yue, Y. and Li, W. (1996), "Application of zeolite-filled pervaporation membrane", Zeolites., 16, 70. https://doi.org/10.1016/0144-2449(95)00094-1
  15. Haung, A., Larean, B. and Smolder, O. (1966), Acta. Chem. Scand., 20, 183. https://doi.org/10.3891/acta.chem.scand.20-0183
  16. Keggin, J.F. (1993), "Structure of the molecule of 12-phosphotungestic acid", Nature, 131(3321), 908-909.
  17. Lu, S.Y., Chiu, C.P. and Huang, H.Y. (2000), "Pervaporation of acetic acid/water mixtures through silicalite filled polydimethylsiloxane membranes", J. Membr. Sci., 176(2), 159-167. https://doi.org/10.1016/S0376-7388(00)00434-8
  18. McGarvey, G.B. and Moffat, J.B. (1991), "Ion-exchange properties of microporous monovalent salts of 12-tungstophosphoric acid and 12-molybdophosphoric acid catalysts", J. Catal., 128, 69-83. https://doi.org/10.1016/0021-9517(91)90067-E
  19. Misono, M. (1987), "Acidic and catalytic properties of heteropoly compounds", Mater. Chem. Phys., 17(1-2), 103-120. https://doi.org/10.1016/0254-0584(87)90051-4
  20. Mohanapriya, S., Bhat, S.D., Sahu, A.K., Pitchumani, S., Sridhar, P. and Shukla, A.K. (2009), "A new mixed-matrix membrane for DMFCs", Energy. Environ. Sci., 2, 1210-1216. https://doi.org/10.1039/b909451b
  21. Moon, G.Y., Pal, R. and Huang, R.Y.M. (1999), "Novel two-ply composite membranes of Chitosan and sodium alginate for the pervaporation dehydration of isopropanol and ethanol", J. Membr. Sci., 156, 17-27. https://doi.org/10.1016/S0376-7388(98)00322-6
  22. Naidu, B., Bhat, S.D., Sairam, M., Wali, A.C., Sawant, D.P., Halligudi, S.B.... and Aminabhavi, T M. (2005), "Comparison of the pervaporation separation of a water-acetonitrile mixture with zeolite-filled sodium alginate and poly (vinyl alcohol)-polyaniline semi-interpenetrating polymer network membranes", J. Appl. Polym. Sci., 96, 1968-1978. https://doi.org/10.1002/app.21653
  23. Neumann, R. (1998), "Polyoxometalate complexes in organic oxidation chemistry", Prog. Inorg. Chem., 47, 317-370.
  24. Okuhara, T., Mizuno, N. and Misono, M. (1996), Catalytic chemistry of heteropoly compounds", Adv. Catal., 41, 113-252.
  25. Pizzio, L.R., Vazquez, P.G., Caceres, C.V. and Blanco, M.N. (2003), "Supported Keggin type heteropolycompounds for ecofriendly reactions", Appl. Catal. A: Gen., 256(1), 125-139. https://doi.org/10.1016/S0926-860X(03)00394-6
  26. Pope, M.T. (1983), Heteropoly and Isopoly Oxometalates, Springer-Verlag, New York.
  27. Soppimath, K.S., Aminabhavi, T.M., Kulkarni, A.R. and Rudzinski, W.E. (2001), "Biodegradable polymeric nanoparticles as drug delivery devices", J. Control. Rel., 70, 1-20. https://doi.org/10.1016/S0168-3659(00)00339-4
  28. Strachota, A., Tishchenko, G., Matejka, L. and Bleha, M. (2001), "Chitosan-oligo (silsesquioxane) blend membranes: preparation, morphology, and diffusion permeability", Inorg. Organomet. Polym., 11(3), 165. https://doi.org/10.1023/A:1015289611410
  29. Teli, S.B., Gokavi, G.S. and Aminabhavi, T.M. (2007), "Novel sodium alginate-poly (Nisopropylacrylamide) semi-interpenetrating polymer network membranes for pervaporation separation of water+ ethanol mixtures", Sep. Purif. Tech., 56, 150-157. https://doi.org/10.1016/j.seppur.2007.01.017
  30. Teli, S.B., Gokavi, G.S., Sairam, M. and Aminabhavi, T.M. (2007), "Mixed matrix membranes of poly (vinyl alcohol) loaded with phosphomolybdic heteropolyacid for the pervaporation separation of waterisopropanol mixtures", Coll. Surf. A: Physico. Chem. Eng. Aspect., 301(1), 55-62. https://doi.org/10.1016/j.colsurfa.2006.12.030
  31. Wang, Y.C., Fan, S.C., Lee, K.R., Li, C.L., Huang, S.H., Tsai, H.A. and Lai, J.Y. (2004), "Polyamide/SDSclay hybrid nanocomposite membrane application to water-ethanol mixture pervaporation separation", J. Membr. Sci., 239, 219-226. https://doi.org/10.1016/j.memsci.2004.03.037
  32. Zhang, L., Zhou, D., Wang, H. and Cheng, S. (1997), "Ion exchange membranes blended by cellulose cuoxam with alginate", J. Membr. Sci., 124, 195-201. https://doi.org/10.1016/S0376-7388(96)00227-X
  33. Zhang, X.K., Poojari, Y., Drechsler, L.E., Kuo, C.M., Fried, J.R. and Clarson, S.J. (2008), "Pervaporation of organic liquids from binary aqueous mixtures using poly (trifluoropropylmethylsiloxane) and poly (dimethylsiloxane) dense membranes", J. Inorg. Organ. Polym., 18, 246-252. https://doi.org/10.1007/s10904-007-9178-4