한국환경과학회지 (Journal of Environmental Science International)

  • 제26권8호
  • /
  • Pages.955-966
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  • 2017
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  • 1225-4517(pISSN)
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  • 2287-3503(eISSN)
한국환경과학회 (The Korean Environmental Sciences Society)
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중금속류 오염 토양 처리를 위한 복합 고화제(lime, DAP, 래들 슬래그) 성능 평가

Evaluation of the Performance of Multi-binders (lime, DAP and ladle slag) in Treating Metal(loid)s-contaminated Soils

  • 최지연 (경북대학교 건설환경에너지공학부) ;
  • 신원식 (경북대학교 건설환경에너지공학부)
  • Choi, Jiyeon (School of Architecture, Civil, Environmental and Energy Engineering, Kyungpook National University) ;
  • Shin, Won Sik (School of Architecture, Civil, Environmental and Energy Engineering, Kyungpook National University)
  • 투고 : 2017.06.08
  • 심사 : 2017.07.19
  • 발행 : 2017.08.31
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초록

Amendment of multi-binders was employed for the immobilization of metal(loid)s in field-contaminated soils to reduce the leaching potential. The effect of different types of multi-binders (lime/diammonium phosphate, diammonium phosphate/ladle slag and lime/ladle slag) on the solidification/stabilization of metal(loid)s (Pb, Zn, Cu and As) from the smelter soil and mine tailing soil were investigated. The amended soils were evaluated by measuring Toxicity Characterization Leaching Procedure (TCLP) leaching concentration of metal(loid)s. The results show that the leaching concentration of metal(loid)s decreased with the immobilization using multi-binders. In terms of TCLP extraction, the mixed binder was effective in the order of lime/ladle slag > diammonium phosphate/ladle slag > lime/diammonium phosphate. When the mixed binder amendment (0.15 g lime+0.15 g ladle slag for 1g smelter soil and 0.05 g lime+0.1 g ladle slag for 1 g mine tailing soil, respectively) was used, the leaching concentration of metal(loid)s decreased by 90%. However, As leaching concentration increased with diammonium phosphate/lime and diammonium phosphate/ladle slag amendment competitive anion exchange between arsenic ion and phosphate ion from diammonium phosphate. The Standard, Measurements and Testing programme (SM&T) analysis indicated that fraction 1 (F1, exchangeable fraction) decreased, while fraction 4 (F4, residual fraction) increased. The increased immobilization efficiency was attributed to the increase in the F4 of the SM&T extraction. From this work, it was possible to suggest that both arsenic and heavy metals can be simultaneously immobilized by the amendment of multi-binder such as lime/ladle slag.

키워드

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