DOI QR코드

DOI QR Code

PPTA/PVDF blend membrane integrated process for treatment of spunlace nonwoven wastewater

  • Li, Hongbin (School of Textiles Engineering, Henan University of Engineering, Henan Engineering Laboratory of New Textiles Development) ;
  • Shi, Wenying (School of Textiles Engineering, Henan University of Engineering, Henan Engineering Laboratory of New Textiles Development) ;
  • Qin, Longwei (School of Textiles Engineering, Henan University of Engineering, Henan Engineering Laboratory of New Textiles Development) ;
  • Zhu, Hongying (School of Textiles Engineering, Henan University of Engineering, Henan Engineering Laboratory of New Textiles Development) ;
  • Du, Qiyun (State Key Laboratory of Hollow Fiber Membrane Materials and Processes, Tianjin Polytechnic University) ;
  • Su, Yuheng (School of Textiles Engineering, Henan University of Engineering, Henan Engineering Laboratory of New Textiles Development) ;
  • Zhang, Haixia (School of Textiles Engineering, Henan University of Engineering, Henan Engineering Laboratory of New Textiles Development) ;
  • Qin, Xiaohong (School of Textiles Engineering, Henan University of Engineering, Henan Engineering Laboratory of New Textiles Development)
  • Received : 2016.08.25
  • Accepted : 2016.12.19
  • Published : 2017.07.25

Abstract

Hydrophilic and high modulus PPTA molecules were incorporated into PVDF matrix via the in situ polymerization of PPD and TPC in PVDF solution. PPTA/PVDF/NWF blend membrane was prepared through the immersion precipitation phase inversion method and nonwoven coating technique. The membrane integrated technology including PPTA/PVDF/NWF blend membrane and reverse osmosis (RO) membrane was employed to treat the polyester/viscose spunlace nonwoven process wastewater. During the consecutive running of six months, the effects of membrane integrated technology on the COD, ammonia nitrogen, suspended substance and pH value of water were studied. The results showed that the removal rate of COD, ammonia nitrogen and suspended substance filtered by PPTA/PVDF blend membrane was kept above 90%. The pH value of the permeate water was about 7.1 and the relative water flux of blend membrane remained above 90%. After the deep treatment of RO membrane, the permeate water quality can meet the water circulation requirement of spunlace process.

Keywords

Acknowledgement

Supported by : National Natural Science Foundation of China, University of Henan Province

References

  1. An, A.K., Guo, J.X., Jeong, S.H., Lee, E.J., Tabatabai, S.A.A. and Leiknes, M.T. (2016), "High flux and antifouling properties of negatively charged membrane for dyeing wastewater treatment by membrane distillation", Water Res., 103, 362-371. https://doi.org/10.1016/j.watres.2016.07.060
  2. Chan, W.F., Marand, E. and Martin, S.M. (2016), "Novel zwitterion functionalized carbon nanotube nanocomposite membranes for improved RO performance and surface anti-biofouling resistance", J. Membr. Sci., 509, 125-137. https://doi.org/10.1016/j.memsci.2016.02.014
  3. Chen, J.Y., Muller, D.H., Konig, C., Niessen, K. and Mussig, J. (2010), "Spunlaced flax/polypropylene nonwoven as auto interior material: Acoustical and fogging performance", J. Biob. Mat. Bioe., 4, 330-337. https://doi.org/10.1166/jbmb.2010.1097
  4. Chen, Y., Muller, D.H., Niessen, K. and Mussig, J. (2008), "Spunlaced flax/polypropylene nonwoven as auto interior material: Mechanical performance", J. Ind. Text., 1, 69-86.
  5. Hajiani, F., Hosseini, S.M., Ansari, N. and Jeddi, A.A.A. (2010), "The influence of water jet pressure settings on the structure and absorbency of spunlace nonwoven", Fibers Polym., 5, 798-804.
  6. Ishizaki, S., Fukushima, T., Ishii, S. and Okabe, S. (2016), "Membrane fouling potentials and cellular properties of bacteria isolated from fouled membranes in a MBR treating municipal wastewater", Water Res., 100, 448-457. https://doi.org/10.1016/j.watres.2016.05.027
  7. Jankowski, T. (2009), "Influence of structural characteristics on liquid aerosol filtration in multilayer nonwoven fabrics of the spunlace type", Fibers Text. East. Eur., 4, 87-92.
  8. Kalebek, N.A. and Babaarslan, O. (2010), "Effect of weight and apllied force on the friction coefficient of the spunlace nonwoven fabrics", Fibers Polym., 2, 277-284.
  9. Li, H.B., Shi, W.Y., Zhang, Y.F. and Zhou, R. (2015a), "Comparison study of the effect of blending method on PVDF/PPTA blend membrane structure and performance", Membr. Water Treat., 3, 205-224.
  10. Li, H.B., Shi, W.Y., Zhang, Y.F., Zhou, R. and Zhang, H.X. (2015b), "Preparation of hydrophilic PPTA/PVDF blend membranes by in situ polycondensation and its application in the treatment of landfill leachate", Appl. Surf. Sci., 346, 134-146. https://doi.org/10.1016/j.apsusc.2015.04.027
  11. Liu, F., Hashim, N.A., Liu, Y.T., Abed, M.R.M. and Li, K. (2011), "Progress in the production and modification of PVDF membranes", J. Membr. Sci., 375, 1-27. https://doi.org/10.1016/j.memsci.2011.03.014
  12. Martin, N., Davies, P. and Baley, C. (2016), "Evaluation of the potential of three non-woven flax fiber reinforcements: Spunlaced, needlepunched and paper process", Ind. Crops. Prod., 83, 194-205. https://doi.org/10.1016/j.indcrop.2015.10.008
  13. Midha, V.K., Dakuri, A. and Midha, V. (2013), "Studies on the properties of nonwoven surgical gowns", J. Ind. Text., 2, 174-190.
  14. Miguel, J. and Pulido, O. (2016), "A review on the use of membrane technology and fouling control for olive mill wastewater treatment", Sci. Total Environ., 563-564, 664-675. https://doi.org/10.1016/j.scitotenv.2015.09.151
  15. Shang, R., Verliefde, A.R.D., Hu, J.Y., Zeng, Z.Y., Lu, J., Kemperman, A.J.B., Deng, H.P., Nijmeijer, K., Heijman, S.G.J. and Rietveld, L.C. (2014), "Tight ceramic UF membrane as RO pre-treatment: The role of electrostatic interactions on phosphate rejection", Water Res., 48, 498-507. https://doi.org/10.1016/j.watres.2013.10.008