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Ionic Compositions of Fine Particulate Matter during Summer and Winter in the Downtown Area of Jejusi City in Jeju Island

제주시 도심지역에서 여름철과 겨울철의 미세먼지 중 수용성 이온 조성

  • Lee, Ki-Ho (Department of Environmental Engineering, Jeju National University) ;
  • Kim, Su-Mi (Research Institute of Health & Environment, Jeju Special Self-Governing Province) ;
  • Hu, Chul-Goo (Department of Environmental Engineering, Jeju National University)
  • 이기호 (제주대학교 환경공학과) ;
  • 김수미 (제주특별자치도 보건환경연구원) ;
  • 허철구 (제주대학교 환경공학과)
  • Received : 2017.02.21
  • Accepted : 2017.04.11
  • Published : 2017.05.31

Abstract

This study was carried out to elucidate the chemical compositions of water-soluble inorganic ions in $PM_{10}$ and $PM_{2.5}$ aerosols collected during summer and winter in downtown Jejusi city. The ratios of $NO_3^-$ to the total mass of ionic species in $PM_{10}$ and $PM_{2.5}$ aerosols largely increase in winter compared to summer, while $SO_4^{2-}$ ratios in both aerosols appear to follow the opposite trend. Moreover, concentrations of $Na^+$, $Mg^{2+}$, $Ca^{2+}$ and $Cl^-$ in $PM_{10}$ and $PM_{2.5-10}$ aerosols are higher in winter than in summer. The nitrate concentrations in $PM_{10}$ and $PM_{2.5}$ aerosols increase with an identical increase in excess ammonium during winter, however, nitrate formation during summer is not important owing to ammonium-poor conditions.

Keywords

References

  1. Cao, J., Shen, Z., Chow, J. C., Qi, G., Watson, J. G., 2009, Seasonal variations and sources of mass and chemical composition for $PM_{10}$ aerosol in Hangzhou, China, Particuology, 7, 161-168. https://doi.org/10.1016/j.partic.2009.01.009
  2. Chosunilbo, 2016, http://news.chosun.com/site/data/html_dir/2016/05/27/2016052700304.html
  3. Huang, X., Qiua, R., Chan, C. K., Pathak, R. K., 2011, Evidence of high $PM_{2.5}$ strong acidity in ammonia-rich atmosphere of Guangzhou, China: Transition in pathways of ambient ammonia to form aerosol ammonium at $ [NH_4{^+}]/[SO{_4}^{2-}]=1.5$, Atmos. Res., 99, 488-495. https://doi.org/10.1016/j.atmosres.2010.11.021
  4. IPCC, 2007, Climate change 2007: The physical science basis, Contribution of Working Group to the Fourth Assessment Report of the IPCC.
  5. Kim, N. K., Kim, Y. P., Kang, C. H., 2011, Long-term trend of aerosol composition and direct radiative forcing due to aerosols over Gosan: TSP, $PM_{10}$, and $PM_{2.5}$ data between 1992 and 2008, Atmos. Environ., 45, 6107- 6115. https://doi.org/10.1016/j.atmosenv.2011.08.051
  6. Ko, H.-J., Lim, E., Song, J.-M., Kim, W.-H., Kang, C.-H., Lee, H., Lee, C., 2015, Composition variation of atmospheric fine particulate matters in accordance with air mass transport pathways at background site of Korea in 2013, J. Korean Soc. Atmos. Environ., 31, 15-27. https://doi.org/10.5572/KOSAE.2015.31.1.015
  7. Lin, J. J., 2002, Characterization of water-soluble ion species in urban ambient particles, Environ. Int., 28, 55-61. https://doi.org/10.1016/S0160-4120(02)00004-1
  8. Pathak, R. K., Chan, C. K., 2005, Inter-particle and gas-particle interactions in sampling artifacts of $PM_{2.5}$ in filter-based samplers, Atmos. Environ., 39, 1597-1607.
  9. Pathak, R. K., Wu, W. S., Wang, T., 2009, Summertime $PM_{2.5}$ ionic species in four major cities in China: Nitrate formation in an ammonia-deficient atmosphere, Atmos. Chem. Phys., 9, 1711-1722. https://doi.org/10.5194/acp-9-1711-2009
  10. Raizenne, M., Neas, L. M., Damokosh, A. I., Dockery, D. W., Spengler, J. D., Koutrakis, P., Ware, J. H., Speizer, F. E., 1996, Health effects of acid aerosols on North American children: Pulmonary function, Environ. Health Perspect., 104, 506-514. https://doi.org/10.1289/ehp.96104506
  11. Shen, Z., Cao, J., Arimoto, R., Han, Z., Zhang, R., Han, Y., Liu, S., Okuda, T., Nakao, S., Tanaka, S., 2009, Ionic composition of TSP and $PM_{2.5}$ during dust storms and air pollution episodes at Xi'an, China, Atmos. Environ., 43, 2911-2918. https://doi.org/10.1016/j.atmosenv.2009.03.005
  12. Squizzato, S., Masiol, M., Brunelli, A., Pistollato, S., Tarabotti, E., Rampazzo, G., Pavoni, B., 2013, Factors determining the formation of secondary inorganic aerosol: A Case study in the Po Valley (Italy), Atmos. Chem. Phys., 13, 1927-1939. https://doi.org/10.5194/acp-13-1927-2013
  13. Yao, X., Chan, C. K., Fang, M., Cadle, S., Chan, T., Mulawa, P., He, K., Ye, B., 2002, The water-soluble ionic composition of $PM_{2.5}$ in Shanghai and Beijing, China, Atmos. Environ., 36, 4223-4234. https://doi.org/10.1016/S1352-2310(02)00342-4

Cited by

  1. Chemical Composition of Fine Particulate Matter in the Downtown Area of Jeju City vol.27, pp.7, 2018, https://doi.org/10.5322/JESI.2018.27.7.597