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Effect of Red-emitting Sr2.41F2.59B20.03O74.8:Eu0.12,Sm0.048 Phosphor on Color Rendering Index and Luminous Efficacy of White LEDs

  • Nguyen, Anh Q.D. (Nguyen Tat Thanh University) ;
  • Nguyen, Vinh H. (Nguyen Tat Thanh University) ;
  • Lee, Hsiao-Yi (Department of Electrical Engineering, National Kaohsiung University of Applied Sciences)
  • Received : 2016.11.12
  • Accepted : 2017.01.31
  • Published : 2017.04.25

Abstract

Color rendering index (CRI) and luminous efficacy (LE) are two key performance factors of white LEDs (WLED). While most recent works in optics focus on methodology to improve these factors, little attention has been dedicated to chemical composition of materials. This paper studies the effect of $Sr_{2.4}1F_{2.59}B_{20.03}O_{74.8}:Eu_{0.12},Sm_{0.048}$ phosphor (SrSm), in terms of concentration and particle size on CRI and LE of 8500 K - WLEDs. Importantly, the molar mass of the componential ions in SrSm are calculated to shed light on the connection between the chemical composition of the material of interest and the performance of WLEDs. Results show that CRI can be improved to a value of around 86 by boosting red-light components in WLEDs, for all 3 major configurations: conformal, in-cup, and remote phosphor. CRI value tends to decrease with larger size of particles, while LE value goes in the reverse direction. On the other hand, both CRI and LE appear to be reduced at higher concentration of SrSm. This light attenuation is analyzed by using the Lambert-Beer law and Mie-scattering theory.

Keywords

References

  1. J. W. Moon, B. G. Min, J. S. Kim, M. S. Jang, K. Min Ok, K.-Y. Han, and J. S. Yoo, "Optical characteristics and longevity of the line-emitting $K_2SiF_6:Mn^{4+}$ phosphor for LED application," Opt. Mater. Express 6, 782-792, (2016). https://doi.org/10.1364/OME.6.000782
  2. N. D. Q. Anh, M.-F. Lai, H.-Y. Ma, and H.-Y. Lee, "Enhancing of correlated color temperature uniformity for multi-chip white-light LEDs by adding $SiO_2$ in phosphor layer," J. Chinese Inst. Eng. 38, 297-303 (2014).
  3. B.-Y. Joo and J.-H. Ko, "Analysis of color uniformity of white LED lens packages for direct-lit LCD backlight applications," J. Opt. Soc. Korea 17, 506-512 (2013). https://doi.org/10.3807/JOSK.2013.17.6.506
  4. W.-S. Sun, C.-L. Tien, J.-W. Pan, T.-H. Yang, C.-H. Tsuei, and Y.-H. Huang, "Simulation and comparison of the lighting efficiency for household illumination with LEDs and fluorescent lamps," J. Opt. Soc. Korea 17, 376-383 (2013). https://doi.org/10.3807/JOSK.2013.17.5.376
  5. J. H. Oh, Y. J. Eo, S. J. Yang, and Y. R. Do, "High-Color-Quality multipackage phosphor-converted LEDs for yellow photolithography room lamp," IEEE Photonics J. 7, 1-9 (2015).
  6. P. C. Hung and J. Y. Tsao, "Maximum white luminous efficacy of radiation versus color rendering index and color temperature: Exact results and a useful analytic expression," J. Display Technol. 9, 405-412 (2013). https://doi.org/10.1109/JDT.2012.2224638
  7. S. Nizamoglu, T. Erdem, X. W. Sun, and H. V. Demir "Superior warm-white light-emitting diodes integrated with quantum dot nanophosphors for high luminous efficacy and color rendering," in Proc. IEEE CLEO (San Jose, California, USA, July 2011), pp. 1-2.
  8. Z.-T. Li, Y. Tang, Z.-Y. Liu, Y.-E. Tan, and B.-M. Zhu, "Detailed study on pulse-sprayed conformal phosphor configurations for LEDs," J. Display Technol. 9, 433-440 (2013). https://doi.org/10.1109/JDT.2012.2225019
  9. H. Chen and S. Y. Hui, "Dynamic prediction of correlated color temperature and color rendering index of phosphorcoated white light-emitting diodes." IEEE T. Ind. Electron. 61, 784-797 (2014). https://doi.org/10.1109/TIE.2013.2251736
  10. N. D. Q. Anh and H.-Y. Lee, "Improving the angular color uniformity and the lumen output for multi-chip white LED lamps by green $Ce_{0.67}$ $Tb_{0.33}$ $MgAl_{11}$ $O_{19}:Ce,Tb$ phosphor," J. Chinese Inst. Eng. 40, 871-875 (2016).
  11. M. Schratz, C. Gupta, T. J. Struhs, and K. Gray, "Reducing energy and maintenance costs while improving light quality and reliability with led lighting technology," in Proc. IEEE PPIC (Charlotte, USA, June 2013), pp. 43-49.
  12. H. Y. Peng, H. S. Hwang, and M. Devarajan, "Phosphor thickness effects on the optical performance of high power phosphor converted chip-on-board light-emitting diodes," in Proc. IEEE TENSYMP (Dalian, China, April 2014), pp. 293-296.
  13. W. M. Yen and M. J. Weber, Inorganic Phosphors: Compositions, Preparation and Optical Properties, (CRC Press, LLC, 2000 N.W. Corporate Blvd., Boca Raton, Florida 33431, 2004).
  14. Z. Qinghua, P. Zhiwu, W. Shubing, S. Qiang, and L. Shaozhe, "The luminescent properties of $Sm^{2+}$ in strontium tetraborates ($SrB_4O_7:Sm^{2+}$)," J. Phys. Chem. Solids 60, 515-520 (1999). https://doi.org/10.1016/S0022-3697(98)00304-7
  15. K. Jang, I. Kim, S. T. Park, Y. L. Huang, H. J. Seo, and C. D. Kim, "Reduction effect on the optical properties of $Sm^{2+}$doped in $SrB_4O_7$ and $SrB_6O_{10}$ crystals," J. Phys. Chem. Solids 67, 2316-2321 (2006). https://doi.org/10.1016/j.jpcs.2006.05.020
  16. R. Komatsu, H. Kawano, Z. Oumaru, K. Shinoda, and V. Petrov, "Growth of transparent $SrB_4O_7$ single crystal and its new applications," J. Crystal Growth 275, e843-e847 (2005). https://doi.org/10.1016/j.jcrysgro.2004.11.122
  17. R. Stefani, A. D. Maia, E. E. S. Teotonio, and M. A. F. Monteiro, M. C. F. C. Felinto, H. F. Brito, "Photoluminescent behavior of $SrB_4O_7$:RE2+ (RE = Sm and Eu) prepared by Pechini, combustion and ceramic methods," J. Solid State Chem. 179, 1086-1092, (2006). https://doi.org/10.1016/j.jssc.2006.01.006
  18. Q. H. Zeng, Z. W. Pei, S. B. Wang, and Q. Su, "The reduction of $Re^{3+}$ in $Srb_6O_{10}$ prepared in air and the luminescence of $Srb_6O_{10}:Re^{2+}$ (Re=Eu, Sm, Tm)," Spectrosc. Lett. 32, 895-912 (1999). https://doi.org/10.1080/00387019909350036
  19. S. Liu and X. B. Luo, LED Packaging for Lighting Applications: Design, Manufacturing and Testing, (Chemical Industry Press and John Wiley & Sons, Beijing, 2011), Chapter 3.
  20. Y. Shuai, N. T. Tran, J. P. You, and F. G. Shi, "Phosphor size dependence of lumen efficiency and spatial CCT uniformity for typical white LED emitters," IEEE ECTC., 2025-2028 (2012).
  21. Z.-Y. Liu, S. Liu, K. Wang, and X.-B Luo, "Measurement and numerical studies of optical properties of YAG:Ce phosphor for white light-emitting diode packaging," Appl. Opt. 49, 247-57 (2010). https://doi.org/10.1364/AO.49.000247