Asian Journal of Atmospheric Environment

  • 제11권1호
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  • Pages.15-28
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  • 2017
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  • 1976-6912(pISSN)
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  • 2287-1160(eISSN)
한국대기환경학회 (Korean Society for Atmospheric Environment)
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A Test of Relative Removal Properties of Various Offensive Odors by Zeolite

  • Adelodun, Adedeji A. (Department of Marine Science and Technology, School of Earth and Mineral Sciences, The Federal University of Technology) ;
  • Vellingiri, Kowsalya (Department of Civil and Environmental Engineering, Hanyang University) ;
  • Jeon, Byong-Hun (Department of Natural Resources and Environmental Engineering, Hanyang University) ;
  • Oh, Jong-Min (Department of Environmental Application Science, Kyung Hee University) ;
  • Kumar, Sandeep (Department of Bio and Nano Technology, Guru Jambheshwar University of Science and Technology) ;
  • Kim, Ki-Hyun (Department of Civil and Environmental Engineering, Hanyang University)
  • 투고 : 2016.11.06
  • 심사 : 2017.01.15
  • 발행 : 2017.03.31
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초록

The adsorptive removal properties of synthetic A4 zeolite were investigated against a total of 16 offensive odors consisting of reduced sulfur compounds (RSCs), nitrogenous compounds (NCs), volatile fatty acids (VFAs), and phenols/indoles (PnI). Removal of these odors was measured using a laboratory-scale impinger-based adsorption setup containing 25 g of the zeolite bed (flow rate of $100mL\;min^{-1}$). The high est and lowest breakthrough (%) values were shown for PnIs and RSCs, respectively, and the maximum and minimum adsorption capacity (${\mu}g\;g^{-1}$) of the zeolite was observed for the RSCs (range of 0.77-3.4) and PnIs (0.06-0.104), respectively. As a result of sorptive removal by zeolite, a reduction in odor strength, measured as odor intensity (OI), was recorded from the minimum of approximately 0.7 OI units (indole [from 2.4 to 1.6]), skatole [2.2 to 1.4], and p-cresol [5.1 to 4.4]) to the maximum of approximately 4 OI units (methanethiol [11.4 to 7.5], n-valeric acid [10.4 to 6.5], i-butyric acid [7.9 to 4.4], and propionic acid [7.2 to 3.7]). Likewise, when removal was examined in terms of odor activity value (OAV), the extent of reduction was significant (i.e., 1000-fold) in the increasing order of amy acetate, i-butyric acid, phenol, propionic acid, and ammonia.

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