Journal of Electrochemical Science and Technology

The Korean Electrochemical Society (한국전기화학회)
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Facile Synthesis of M-MOF-74 (M=Co, Ni, Zn) and its Application as an ElectroCatalyst for Electrochemical CO2 Conversion and H2 Production

  • Choi, Insoo (Fuel Cell Research Center, Korea Institute of Science and Technology) ;
  • Jung, Yoo Eil (Department of Energy and Chemical Engineering, Incheon National University) ;
  • Yoo, Sung Jong (Fuel Cell Research Center, Korea Institute of Science and Technology) ;
  • Kim, Jin Young (Fuel Cell Research Center, Korea Institute of Science and Technology) ;
  • Kim, Hyoung-Juhn (Fuel Cell Research Center, Korea Institute of Science and Technology) ;
  • Lee, Chang Yeon (Department of Energy and Chemical Engineering, Incheon National University) ;
  • Jang, Jong Hyun (Fuel Cell Research Center, Korea Institute of Science and Technology)
  • Received : 2016.11.09
  • Accepted : 2017.01.20
  • Published : 2017.03.31
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Abstract

Electrochemical conversion of $CO_2$ and production of $H_2$ were attempted on a three-dimensionally ordered, porous metal organic framework (MOF-74) in which transition metals (Co, Ni, and Zn) were impregnated. A lab-scale proton exchange membrane-based electrolyzer was fabricated and used for the reduction of $CO_2$. Real-time gas chromatography enabled the instantaneous measurement of the amount of carbon monoxide and hydrogen produced. Comprehensive calculations, based on electrochemical measurements and gaseous product analysis, presented a time-dependent selectivity of the produced gases. M-MOF-74 samples with different central metals were successfully obtained because of the simple synthetic process. It was revealed that Co- and Ni-MOF-74 selectively produce hydrogen gas, while Zn-MOF-74 successfully generates a mixture of carbon monoxide and hydrogen. The results indicated that M-MOF-74 can be used as an electrocatalyst to selectively convert $CO_2$ into useful chemicals.

Keywords

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