DOI QR코드

DOI QR Code

The investigation of pH threshold value on the corrosion of steel reinforcement in concrete

  • Pu, Qi (Suzhou Concrete and Cement Products Research Institute Co.,Ltd.) ;
  • Yao, Yan (China Building Materials Academy) ;
  • Wang, Ling (China Building Materials Academy) ;
  • Shi, Xingxiang (Suzhou Concrete and Cement Products Research Institute Co.,Ltd.) ;
  • Luo, Jingjing (Suzhou Concrete and Cement Products Research Institute Co.,Ltd.) ;
  • Xie, Yifei (Suzhou Concrete and Cement Products Research Institute Co.,Ltd.)
  • 투고 : 2016.03.21
  • 심사 : 2016.12.24
  • 발행 : 2017.03.25

초록

The aim of this study is to investigate the pH threshold value for the corrosion of steel reinforcement in concrete. A method was designed to attain the pH value of the pore solution on the location of the steel in concrete. Then the pH values of the pore solution on the location of steel in concrete were changed by exposing the samples to the environment (CO25%, RH 40%) to accelerate carbonation with different periods. Based on this, the pH threshold value for the corrosion of steel reinforcement had been examined by the methods of half-cell potential and electrochemical impedance spectra (EIS). The results have indicated that the pH threshold value for the initial corrosion of steel reinforcement in concrete was 11.21. However, in the carbonated concrete, agreement among whether steel corrosion was initiatory determined by the detection methods mentioned above could be found.

키워드

과제정보

연구 과제 주관 기관 : Opening Foundation of State Key Laboratory of Green Building Materials

참고문헌

  1. Behnood, A., Tittelboom, K.V. and Belie, N.D. (2016), "Methods for measuring pH in concrete", Constr. Build. Mater., 105, 176-188. https://doi.org/10.1016/j.conbuildmat.2015.12.032
  2. Cruz, J.M., Fita, I.C., Soriano, L., Paya, J. and Borrachero, M.V. (2013), "The use of electrical impedance spectroscopy for monitoring the hydration products of Portland cement mortars with high percentage of pozzolans", Cement Concrete Res., 50, 51-61. https://doi.org/10.1016/j.cemconres.2013.03.019
  3. Despas, C., Schnitzler, V. and Janvier, P. (2014), "High-frequency impedance measurement as a relevant tool for monitoring the apatitic cement setting reaction", Acta Biomater., 10(2), 940-950. https://doi.org/10.1016/j.actbio.2013.10.019
  4. Dong, B.Q., Qiu, Q.W. and Gu, Z.T. (2016), "Characterization of carbonation behavior of fly ash blended cement materials by the electrochemical impedance spectroscopy method", Cement Concrete Compos., 65, 118-127. https://doi.org/10.1016/j.cemconcomp.2015.10.006
  5. Dong, B.Q., Wang, Y.S., Ding, W.J. and Li, S.T. (2014), "Electrochemical impedance study on steel corrosion in the simulated concrete system with a novel self-healing microcapsule", Constr. Build. Mater., 56, 1-6. https://doi.org/10.1016/j.conbuildmat.2014.01.070
  6. Duarte, R.G., Castela, A.S., Neves, R. and Freire, L. (2014), "Corrosion behavior of stainless steel rebars embedded in concrete: An electrochemical impedance spectroscopy study", Electrochim. Acta, 124, 218-224. https://doi.org/10.1016/j.electacta.2013.11.154
  7. Duff, G.S., Morris, W., Raspini, I. and Saragovi, C. (2004), "A study of steel rebars embedded in concrete during 65 years", Corros. Sci., 46(9), 2143-2157. https://doi.org/10.1016/j.corsci.2004.01.006
  8. Han, B.G., Zhang, K., Yu, X., Kwon, E. and Ou, J.P. (2012), "Electrical characteristics and pressure-sensitive response measurements of carboxyl MWNT/cement composites", Cement Concrete Compos., 34(6), 794-800. https://doi.org/10.1016/j.cemconcomp.2012.02.012
  9. Huet, B., L'Hostis, V., Miserque, F. and Idrissi, H. (2005), "Electrochemical behavior of mild steel in concrete: Influence of pH and carbonate content of concrete pore solution", Electrochim. Acta, 51(1), 172-180. https://doi.org/10.1016/j.electacta.2005.04.014
  10. Kouril, M., Novak, P. and Bojko, M. (2010), "Threshold chloride concentration for stainless steels activation in concrete pore solutions", Cement Concrete Res., 40(3), 431-436. https://doi.org/10.1016/j.cemconres.2009.11.005
  11. Leemann, A., Nygaard, P., Kaufmann, J. and Loser, R. (2015), "Relation between carbonation resistance, mix design and exposure of mortar and concrete", Cement Concrete Compos., 62, 33-43. https://doi.org/10.1016/j.cemconcomp.2015.04.020
  12. Li, L. and Sagues, A.A. (2001), "Chloride corrosion threshold of reinforcing steel in alkaline solutions-open circuit immersion tests", Corros., 57(1), 19-28. https://doi.org/10.5006/1.3290325
  13. McPolin, D.O., Basheer, P.A.M. and Long, A.E. (2009), "Carbonation and pH in concretes manufactured with supplementary cementitious materials", J. Mater. Civil Eng., 21(5), 217-225. https://doi.org/10.1061/(ASCE)0899-1561(2009)21:5(217)
  14. Ortega, J.M., Sanchez, I. and Climent, M.A. (2015), "Impedance spectroscopy study of the effect of environmental conditions in the microstructure development of OPC and slag cement mortars", Arch. Civil Mech. Eng., 15(2), 569-583. https://doi.org/10.1016/j.acme.2014.06.002
  15. Papadakis, V.G. (2000), "Effect of supplementary cementing materials on concrete resistance against carbonation and chloride ingress", Cement Concrete Res., 30(2), 291-299. https://doi.org/10.1016/S0008-8846(99)00249-5
  16. Pradhan, B. (2014), "Corrosion behavior of steel reinforcement in concrete exposed to composite chloride-sulfate environment", Constr. Build. Mater., 72, 398-410. https://doi.org/10.1016/j.conbuildmat.2014.09.026
  17. Pu, Q., Jiang, L.H., Xu, J.X., Chu, H.Q., Xu, Y. and Zhang, Y. (2012), "Evolution of pH and chemical composition of pore solution in carbonated concrete", Constr. Build. Mater., 28(1), 519-524. https://doi.org/10.1016/j.conbuildmat.2011.09.006
  18. Villat, C., Tran, V.X. and Nelly, P.P. (2010), "Impedance methodology: A new way to characterize the setting reaction of dental cements", Dent. Mater., 26(12), 1127-1132. https://doi.org/10.1016/j.dental.2010.07.013
  19. Xu, J.X., Jiang, L.H. and Wang, J.X. (2009), "Influence of detection methods on chloride threshold value for the corrosion of steel reinforcement", Constr. Build. Mater., 23(5), 1902-1908. https://doi.org/10.1016/j.conbuildmat.2008.09.011
  20. Zhang, D.W., Cao, Z.G., Fan, L.B., Liu, S.G. and Liu, W.Z. (2014), "Evaluation of the influence of salt concentration on cement stabilized clay by electrical resistivity measurement method", Eng. Geol., 170, 80-88. https://doi.org/10.1016/j.enggeo.2013.12.010

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  1. Ingress of chloride ions with carbonation: parameter estimation and analytical simplification pp.2116-7214, 2018, https://doi.org/10.1080/19648189.2018.1528894
  2. Algorithms to measure carbonation depth in concrete structures sprayed with a phenolphthalein solution vol.9, pp.3, 2017, https://doi.org/10.12989/acc.2020.9.3.257
  3. Numerical model for local corrosion of steel reinforcement in reinforced concrete structure vol.27, pp.4, 2017, https://doi.org/10.12989/cac.2021.27.4.385
  4. Climatic Issue in an Advanced Numerical Modeling of Concrete Carbonation vol.13, pp.11, 2017, https://doi.org/10.3390/su13115994