Membrane and Water Treatment

  • 제8권1호
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  • Pages.73-88
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  • 2017
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  • 2005-8624(pISSN)
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  • 2092-7037(eISSN)
테크노프레스 (Techno-Press)
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DOI QR코드

DOI QR Code

Adsorption kinetic and mechanistic view of aqueous ferric ion onto bio-natural rice grains

  • Al-Anber, Mohammed A. (Department of Chemistry, Faculty of Science, Mu'tah University)
  • 투고 : 2015.11.29
  • 심사 : 2016.11.09
  • 발행 : 2017.01.25
⟨ 이전 논문 다음 논문 ⟩

초록

Adsorption kinetics of aqueous ferric ion ($Fe^{3+}$) onto bio-natural rice grains (BRG) have been studied in a batch system. The influence of contact time (0-180 minutes), the dosage of BRG adsorbent (10, 20, 40, and $60gL^{-1}$), and ambient temperature (27, 37, 47, and $57^{\circ}C$) for the adsorption system have been reported. The equilibrium time achieved after 20 minutes of adsorption contact time. The maximum removal of ferric ion is 99% by using $60gL^{-1}$ of BRG, $T=37^{\circ}C$, and $50mgL^{-1}$ ferric ion solution. Adsorption kinetic and diffusion models, such as pseudo-first order, pseudo-second order, and Weber-Morris intra-particle diffusion model, have been used to describe the adsorption rate and mechanism of the ferric ion onto BRG surface. The sorption data results are fitted by Lagergren pseudo-second order model ($R^2=1.0$). The kinetic parameters, rate constant, and sorption capacities have been calculated. The new information in this study suggests that BRG could adsorb ferric ion from water physiosorption during the first 5 minutes. Afterward, the electrostatic interaction between ferric ion and BGR-surface could take place as a very weak chemisorptions process. Thus, there is no significant change could be noticed in the FTIR spectra after adsorption. I recommend producing BGR as a bio-natural filtering material for removing the ferric ion from water.

키워드

참고문헌

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피인용 문헌

  1. A comparative study of thermochemical and cold plasma treatment on lignin-based activated carbon for adsorbing Fe(III) vol.5, pp.5, 2018, https://doi.org/10.1088/2053-1591/aac232