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Structural and physicochemical characterization of starch from Korean rice cultivars for special uses

특수용도 쌀품종 내 전분의 구조적 및 이화학적 특성

  • Lee, Seul (Division of Food and Nutrition and Research Institute for Human Ecology, Chonnam National University) ;
  • Lee, Eun-Jung (Department of BioFood Analysis, Korea Bio Polytechnic) ;
  • Chung, Hyun-Jung (Division of Food and Nutrition and Research Institute for Human Ecology, Chonnam National University)
  • 이슬 (전남대학교 식품영양과학부.생활과학연구소) ;
  • 이은정 (한국폴리텍대학 바이오식품분석과) ;
  • 정현정 (전남대학교 식품영양과학부.생활과학연구소)
  • Received : 2016.07.19
  • Accepted : 2016.08.11
  • Published : 2017.02.28

Abstract

Molecular structure, physicochemical properties, and in vitro digestibility of starch from Korean rice cultivars for special uses (Baegjinju 1, Hanareum, Deuraechan, and Goami 4) were investigated. The starch from Baegjinju 1 had the lowest amylose content (9.7%) and Hanareum, Deuraechan, and Goami 4 had intermediate amylose (20-25%) contents. Baegjinju 1 had a lower proportion of short amylopectin branch chains than the other rice starches. Hanareum had the lowest relative crystallinity and the highest intensity ratio of $1047cm^{-1}/1022cm^{-1}$ among the rice starches. The starch from Goami 4 had a higher pasting temperature and lower gelatinization enthalpy than the other rice starches. Peak viscosity of rice starch from Baegjinju 1 was substantially higher than peak viscosity of other rice starches. Rice starch from Baegjinju 1 had significantly higher rapidly digestible starch content and lower resistant starch content than other rice starches, whereas there was no significant difference in resistant starch content among the rice starches.

본 연구에서는 국내산 특수용도 쌀품종 내 전분의 분자 및 결정 구조적 특성과 소화 특성을 분석하고 상관성을 살펴봄으로써 향후 쌀가공식품들을 개발하는 기초자료로 활용하고자 하였다. 백진주1호 전분은 다른 쌀품종에 비하여 아밀로스 함량, 아밀로펙틴의 분자량, A 사슬 (DP 6-12), 페이스팅 온도, 치반점도, SDS 함량은 유의적으로 낮았으며 아밀로펙틴의 B1 사슬(DP 13-24), 상대적 결정성, 호화온도($T_o$, $T_p$, $T_c$), 호화 엔탈피(${\Delta}H$), 최고점도, 강하점도, RDS 함량이 유의적으로 높은 결과를 나타냈다. 소화율과 구조 및 이화학적 특성 간의 상관성을 분석한 결과 RDS 및 SDS는 아밀로스 함량, 결정성, 호화 온도와 높은 상관성을 보였으며 이는 쌀전분의 구조적 특성과 이화학적 특성의 차이가 전분의 소화율에 영향을 미친 것으로 생각된다. 국내에서 생산된 4가지 특수용도 쌀품종의 전분 분자 및 결정 구조적 특성, 이화학적 특성, 및 소화율 특성이 다르게 나타났으며 이러한 결과는 특수용도 쌀품종을 활용한 가공제품개발에 기초자료로 활용될 것으로 기대된다.

Keywords

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