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Properties of VN Coatings Deposited by ICP Assisted Sputtering: Effect of ICP Power

  • Chun, Sung-Yong (Department of Advanced Materials Science and Engineering, Mokpo National University)
  • Received : 2016.08.30
  • Accepted : 2016.11.22
  • Published : 2017.01.31

Abstract

Vanadium nitride (VN) coatings were deposited using inductively coupled plasma (ICP) assisted sputtering at different ICP powers. Microstructural, crystallographic and mechanical characterizations were performed by FE-SEM, AFM, XRD and nanoindentation. The results show that ICP has significant effects on coating's microstructure, structural and mechanical properties of VN coatings. With an increase in ICP power, coating microstructure evolved from a porous columnar structure to a highly dense one. Single- phase cubic (FCC) VN coatings with different preferential orientations and residual stresses were obtained as a function of ICP power. Average crystal grain sizes of single phase cubic (FCC) VN coatings were decreased from 10.1 nm to 4.0 nm with an increase in ICP power. The maximum hardness of 28.2 GPa was obtained for the coatings deposited at ICP power of 200 W. The smoothest surface morphology with Ra roughness of 1.7 nm was obtained in the VN coating sputtered at ICP power of 200 W.

Keywords

References

  1. U. Wiklund, B. Casas, and N. Stavlid, "Evaporated Vanadium Nitride as a Friction Material in Dry Sliding Against Stainless Steel," Wear, 261 [1] 2-8 (2006). https://doi.org/10.1016/j.wear.2005.09.003
  2. A. Matthews, S. Franklin, and K. Holmberg, "Tribological Coatings: Contact Mechanisms and Selection," J. Phys. D: Appl. Phys., 40 [18] 5463-75 (2007). https://doi.org/10.1088/0022-3727/40/18/S07
  3. F. Rose, B. Marchon, V. Rawat, D. Pocker, Q.-F. Xiao, and T. Iwasaki, "Ultrathin TiSiN Overcoat Protection Layer for Magnetic Media," J. Vac. Sci. Technol. A, 29 [5] 051502 (2011). https://doi.org/10.1116/1.3607423
  4. M. Hoseini, A. Jedenmalm, and A. Boldizar, "Tribological Investigation of Coatings for Artificial Joints," Wear, 264 [11] 958-66 (2008). https://doi.org/10.1016/j.wear.2007.07.003
  5. S. H. Kim, D. B. Asay, and M. T. Dugger, "Isolated Congenital Alveolar Synechiae: Review of Literature and Case Report: A Case Report," Nano Today, 2 22-9 (2007).
  6. F. Ge, P. Zhu, F. Meng, Q. Xue, and F. Huang, "Achieving Very Low Wear Rates in Binary Transition-Metal Nitrides: The Case of Magnetron Sputtered Dense and Highly Oriented VN Coatings," Surf. Coat. Technol., 248 81-90 (2014). https://doi.org/10.1016/j.surfcoat.2014.03.035
  7. J. C. Caicedo, G. Zambrano, W. Aperador, and L. Escobar- Alarcon, "Mechanical and Electrochemical Characterization of Vanadium Nitride (VN) Thin Films," Appl. Surf. Sci., 258 [1] 312-20 (2011). https://doi.org/10.1016/j.apsusc.2011.08.057
  8. O. Storz, H. Gasthuber, and M. Woydt "Tribological Properties of Thermal-sprayed Magn'eli-type Coatings with Different Stoichiometries ($Ti_nO-{2n-1}$)," Surf. Coat. Technol., 140 [2] 76-81 (2001). https://doi.org/10.1016/S0257-8972(01)01024-6
  9. S. Y. Chun, "Growing Behavior of Nanocrystalline TiN Films by Asymmetric Pulsed DC Reactive Magnetron Sputtering," J. Korean Ceram. Soc., 48 [5] 342-47 (2011). https://doi.org/10.4191/kcers.2011.48.5.342
  10. S. Y. Chun, "Effect of Inductively Coupled Plasma (ICP) Power on the Properties of Ultra Hard Nanocrystalline TiN Coatings," J. Korean Ceram. Soc., 50 [3] 212-17 (2013). https://doi.org/10.4191/kcers.2013.50.3.212
  11. S. Y. Chun, "Effect of Inductively Coupled Plasma on the Microstructure, Structure and Mechanical Properties of NbN Coatings," J. Kor. Inst. Surf. Eng., 48 [5] 205-10 (2015). https://doi.org/10.5695/JKISE.2015.48.5.205
  12. U. Helmersson, M. Lattemann, J. Bohlmark, A. P. Ehiasarian, and J. T. Gudmundsson, "Ionized Physical Vapor Deposition (IPVD): A Review of Technology and Applications," Thin Solid Films, 513 [1] 1-24 (2006). https://doi.org/10.1016/j.tsf.2006.03.033
  13. G. Abadias, "Stress and Preferred Orientation in Nitridebased PVD Coatings," Surf. Coat. Technol., 202 [11] 2223- 35 (2008). https://doi.org/10.1016/j.surfcoat.2007.08.029
  14. A. A. Elmustafa and D. S. Stone, "Nanoindentation and the Indentation Size Effect: Kinetics of Deformation and Strain Gradient Plasticity," J. Mech. Phys. Sol., 51 [2] 357-81 (2003). https://doi.org/10.1016/S0022-5096(02)00033-9

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