DOI QR코드

DOI QR Code

원자층 증착법에 의한 TiO2, Al2O3, 및 TiO2-Al2O3 나노라미네이트 박막이 316L Stainless Steel의 부식특성에 미치는 영향

Corrosion Properties of Atomic Layer Deposited TiO2, Al2O3 and TiO2-Al2O3 Nanolaminated Film Coated 316L Stainless Steel

  • 이우재 (부산대학교, 재료공학부) ;
  • 만지흠 (부산대학교, 재료공학부) ;
  • 김다영 (부산대학교, 재료공학부) ;
  • 장경수 ((주)서영, 나노융합사업팀) ;
  • 최현진 (부산테크노파크, 멤스나노부품생산센터) ;
  • 최우창 (부산테크노파크, 멤스나노부품생산센터) ;
  • 권세훈 (부산대학교, 재료공학부)
  • Lee, Woo-Jae (School of Materials Science and Engineering, Pusan National University) ;
  • Wan, Zhixin (School of Materials Science and Engineering, Pusan National University) ;
  • Kim, Da Young (School of Materials Science and Engineering, Pusan National University) ;
  • Jang, Kyung Su (Nano Convergence Team, Seo Yeong Co. Ltd.) ;
  • Choi, Hyun-Jin (MEMS/NANO Component Production Center, Busan Techno Park) ;
  • Choi, Woo-Chang (MEMS/NANO Component Production Center, Busan Techno Park) ;
  • Kwon, Se Hun (School of Materials Science and Engineering, Pusan National University)
  • 투고 : 2017.01.31
  • 심사 : 2017.02.21
  • 발행 : 2017.02.28

초록

$TiO_2$, $Al_2O_3$, and $TiO_2-Al_2O_3$ nanolaminated films were grown by atomic layer deposition (ALD) on the 316L stainless steel (SS316L) substrates at a temperature of $150^{\circ}C$. The growth kinetics of $ALD-TiO_2$ and $Al_2O_3$ thin films were systematically investigated in order to precisely control the thickness of each layers in the $TiO_2-Al_2O_3$ nanolaminated films using a high-resolution transmission electron microscopy. And, the exact deposition rates of $ALD-TiO_2$ on $Al_2O_3$ surface and $ALD-Al_2O_3$ on $TiO_2$ surface were revealed to be 0.0284 nm/cycle and 0.11 nm/cycle, respectively. At given growth conditions, the microstructures of $TiO_2$, $Al_2O_3$ and $TiO_2-Al_2O_3$ nanolaminated films were amorphous. The potentiodynamic polarization test revealed that the $TiO_2-Al_2O_3$ nanolaminated film coated SS316L had a best corrosion resistance, although all ALDcoated SS316L exhibited a clear improvement of the corrosion resistance compared with a bare SS316L.

키워드

참고문헌

  1. U.R.Evans, Electrochemical mechanism of atmospheric rusting, Nature 206 (1965) 980-982. https://doi.org/10.1038/206980a0
  2. C.X.Shan, X.Hou, and K.L.Choy, Corrosion resistance of $TiO_2$ films grown on stainless steel by atomic layer deposition, Surf. Coat. Technol 202 (2008) 2399-2402. https://doi.org/10.1016/j.surfcoat.2007.08.066
  3. M.Atik, P.Delimaneto, M.A.Aegerter, and L.A.Avaca, Sol-gel $TiO_2-SiO_2$ films as protective coatings against corrosion of 316L stainless steel in $H_2SO_4$ solutions, J. Appl. Electrochem 25 (1995) 142-148. https://doi.org/10.1007/BF00248171
  4. S.E.Potts, L.Schmalz, M.Fenker, B.Diaz, J.Swiatowska, V.Maurice, A.Seyeux, P.Marcus, G.Radnoczi, L.Toth, and W.M.M.Kessel, Ultra-Thin aluminium oxide films deposited by plasma-enhanced atomic layer deposition for corrosion protection, J. Electrochem. Soc 158 (2011) C132-C138. https://doi.org/10.1149/1.3560197
  5. R.Hofman, J.G.F.Westheim, I.Pouwwel, T.Fransen, and P.J.Gellings, FTIR and XPS studies on corrosion-resistant $SiO_2$ coatings as a function of the humidity during deposition, Surf. Interface Anal 24 (1996) 1-6. https://doi.org/10.1002/(SICI)1096-9918(199601)24:1<1::AID-SIA73>3.0.CO;2-I
  6. R.Matero, M.Ritala, M.Leskela, T.Salo, J.Aromaa, and O.Forsen, Atomic layer deposited thin films for corrosion profection, J. Phys. IV France 9 (1999) Pr8-493-Pr8-499.
  7. E.Marin, L.Guzman, A.Lanzutti, W.Ensinger, and L.Fedrizzi, Multilayer $Al_2O_3/TiO_2$ Atomic layer deposition coatings for the corrosion protection of stainless steel, Thin Solid Films 522 (2012) 283-288. https://doi.org/10.1016/j.tsf.2012.08.023
  8. E.Harkonen, B.Diaz, J.Swiatowska, V.Maurice, A.Seyeux, M.Vehkamaki, T.Sajavaara, M.Fenker, P.Marcus, and M.Ritala, Corrosion protection of steel with oxide nanolaminates grown by atomic layer deposition, J. Electrochem. Soc 158 (2011) C369-C378. https://doi.org/10.1149/2.061111jes
  9. S.K.Tiwari, R.K.Sahu, A.K.Pramanick, and R.Singh, Development of conversion coating on mild steel prior to sol gel nanostructured $Al_2O_3$ coating for enhancement of corrosion resistance, Surf. Coat. Technol 205 (2011) 4960-4967. https://doi.org/10.1016/j.surfcoat.2011.04.087
  10. Y.Muroya, A.Motoki, K.Shimanoe, T.Maeda, Y.Haruta, Y.Teraoka, and N.Yamazoe, Densification of $SiO_2-Al_2O_3-TiO_2$ based ceramic film coated on steel for high thermal stabilty and mechanical properties, Surf. Coat. Technol 201 (2006) 880-885. https://doi.org/10.1016/j.surfcoat.2005.12.045
  11. D.Pech, P.Steyer, and J.P.Millet, Electrochemical behaviour enhancement of stainless steels by a $SiO_2$ PACVD coating, Corros. Sci 50 (2008) 1492-1497. https://doi.org/10.1016/j.corsci.2008.01.015
  12. S.H.Ahn, Y.S.Choi, J.G.Kim, and J.G.Han, A study on corrosion resistance characteristics of PVD Cr-N coated steels by electrochemical method, Surf. Coat. Technol 150 (2002) 319-326. https://doi.org/10.1016/S0257-8972(01)01529-8
  13. Chenglong Liu, Guoqiang Lin, Dazhi Yang, and Min Qi, In vitro corrosion behavior of multilayered Ti/TiN coating on biomedical AISI 316L stainless steel, Surf. Coat. Technol 200 (2006) 4011-4016. https://doi.org/10.1016/j.surfcoat.2004.12.015
  14. B.Diaz, J.Swiatowska, V.Maurice, A.Seyeux, B.Normand, E.Harkonen, M.Ritala, and P.Marcus, Electrochemical and time-of-flight secondary ion mass spectrometry analysis of ultra-thin metal oxide ($Al_2O_3 \,and \,Ta2_O_5$) coatings deposited by atomic layer deposition on stainless steel, Electrochim. Acta 56 (2011) 10516-10523. https://doi.org/10.1016/j.electacta.2011.02.074
  15. X.Huai, S.Zhao, and W.Li, Corrosion resistance of $Al_2O_3$ coating on a steel substrate, Ceramic Processing Research 10 (2009) 618-620.
  16. L.Bamoulid, M.-T.Maurette, D.De Caro, A.Guenbour, A.Ben Bachir, L.Aries, S.El Hajjaji, F.Benoit-Marquie, and F.Ansart, An efficient protection of stainless steel against corrosion: Combination of a conversion layer and titanium dioxide deposit, Surf. Coat. Technol 202 (2008) 5020-5026. https://doi.org/10.1016/j.surfcoat.2008.05.011
  17. M.Marin, A.Lanzutti, L.Paussa, L.Guzman, and L.Fedrizzi, Longterm performance of atomic layer deposition coatings for corrosion protection of stainless steel, Mater. Corros 66 (2015) 907-914. https://doi.org/10.1002/maco.201408012
  18. J.H.Kim, J.Y.Kim and S.W.Kang, Film growth model of atomic layer deposition for multicomponent thin films, J. Appl. Phys 97 (2005) 093505-01-093505-5. https://doi.org/10.1063/1.1883728
  19. B.S.Boroujeny, Design and investigation of $TiO_2-SiO_2$ thin films on AISI 316L stainless steel for tribological properties and corrosion protection, J. Adv. Mater. and Proc 4 (2016) 3-14.
  20. D.S.R.Krishna, Y.Sun, Z.Chen, Magnetron sputtered $TiO_2$ films on a stainless steel substrate: Selective rutile phase formation and its tribological and anti-corrosion performance, Thin Solid Films 519 (2011) 4860-4864. https://doi.org/10.1016/j.tsf.2011.01.042
  21. W.M.Haynes, CRC Handbook of Chemistry and Physics, 95 th Ed, CRC Press, Boca Raton, FL (2015)