A Synthesis of UV Hard Coating Solution for Plastic Display Plate Using Poly(Urethane Acrylate) Siloxane Oligomer

Poly(Urethane Acrylate) Siloxane Oligomer를 이용한 플라스틱 디스플레이 기판용 UV 하드코팅 용액의 합성

  • Back, Sung Kyun (School of Energy, Materials, Chemical Engineering, Korea University of Technology and Education, Korea University of Technology Education) ;
  • Jang, Sun Ho (School of Energy, Materials, Chemical Engineering, Korea University of Technology and Education, Korea University of Technology Education) ;
  • Yoo, Seong Sik (School of Energy, Materials, Chemical Engineering, Korea University of Technology and Education, Korea University of Technology Education) ;
  • Cho, Ur Ryong (School of Energy, Materials, Chemical Engineering, Korea University of Technology and Education, Korea University of Technology Education)
  • 백성균 (한국기술교육대학교 응용화학공학부) ;
  • 장선호 (한국기술교육대학교 응용화학공학부) ;
  • 유성식 (한국기술교육대학교 응용화학공학부) ;
  • 조을룡 (한국기술교육대학교 응용화학공학부)
  • Received : 2017.09.14
  • Accepted : 2017.09.25
  • Published : 2017.09.30

Abstract

Poly(urethane acrylate) siloxane oligomers with Interpenetrating polymer networked nanoparticles were prepared to synthesize hard coating solution by reaction with isophorone diisocyanate(IPDI) of 1, 2, 3, 4 phr. The structures and molecular weights of the synthesized solutions were characterized by IR spectroscopy and gel permeation chromatography, respectively. In the cross-cut test for the adhesion, all the solutions showed good adhesion of 5B regardless of the content of IPDI and film thickness. The addition of 1 phr IPDI resulted in the best pencil hardness. The IPDI combined siloxane hard coating solution showed more flexibility than the siloxane solution. These results will yield the improvement in the siloxane solution using for plastic display plate.

Keywords

References

  1. M. Woutens, D. Wolfs, M Van der linde, J. Hovens, and A. Tinnemans, "Synthesis of a latex with bimodal particle size distribution for coating application using acrylic monomers", Prog. Org. Coat., Vol.51, pp.312-319, 2004. https://doi.org/10.1016/j.porgcoat.2004.07.020
  2. Y. Y. Yu and W.C. Chen, "Transparent organic-inorganic hybrid thin films prepared from acrylic polymer and aqueous monodispersed colloidal silica", Mater. Chem. & Phys., Vol.82, pp.388-395, 2003. https://doi.org/10.1016/S0254-0584(03)00259-1
  3. D. P. Kang, H. Y. Park, M. S. Ahn, and I. H. Myung, "Properties of Sol-Gel Materials Synthesized from Colloidal Silica and Alkoxy Silanes", Polymer(Korea), Vol.29, pp.242-247, 2005.
  4. J. V. Crivello and Z. Mao, "Preparation and Cationic Photopolymerization of Organic−Inorganic Hybrid Matrixes", Chem. Mater.,Vol. 9, pp.1562-1569, 1997. https://doi.org/10.1021/cm960595q
  5. J. Chen, R. Chareonsak, V. Puengpipat, and S. Marturunkal, "Organic/inorganic Composite Materials for Coating Applications", J. Appl. Polym. Sci., Vol.74, pp.1341-1345, 1999. https://doi.org/10.1002/(SICI)1097-4628(19991107)74:6<1341::AID-APP3>3.0.CO;2-4
  6. E. Rubio, J. Almaral, R. Ramirez-Bon, V. Castano, and V. Rodriguez, "Organic-inorganic Hybrid Coating (poly(methyl methacrylate)/monodisperse silica)", Opt. Mater., Vol.27, pp.1266-1269, 2005. https://doi.org/10.1016/j.optmat.2004.11.022
  7. J. M Urreaga, M. C. Matias, V. Lorenzo, and M. U. de la Orden, "Abrasion Resistance in the Tumble Test of sol-gel Hybrid Coatings for Ophthalmic Plastic lenses", Mater. Lett., Vol.45, pp.293-297, 2000. https://doi.org/10.1016/S0167-577X(00)00120-8
  8. D. H. Kim and D. W. Lee, "Scratch Resistant and Transparent UV-Protective Coating on Polycarbonate", J. Sol-Gel Sci. Tech., Vol.26, pp.783-787, 2003. https://doi.org/10.1023/A:1020774927773
  9. M. S. Kim, and U. R. Cho, "A Study on pattern Formation of Ultra Definition Display Panel Applying Phosphoric Acid", Journal of the Semiconductor & Display Technology., Vol.13, pp. 13-15, 2014.
  10. S. K. Back, S. H. Jang, and U. R. Cho, "Synthesis of Hard coating Solution for Plastic Display Plate", Journal of the Semiconductor & Display Technology., Vol.16, pp. 46-51, 2017.