Korean Journal of Soil Science and Fertilizer (한국토양비료학회지)

Korean Society of Soil Science and Fertilizer (한국토양비료학회)
권호 표지
DOI QR코드

DOI QR Code

Cation Exchange Capacity in Korean Soils Determined by the Copper(II) Acetate Spectrophotometry Method

  • Park, Won-Pyo (Major of Plant Resources and Environment, Jeju National University) ;
  • Chang, Kong-Man (Plant and Environment R&D Center, Samsung C&T) ;
  • Koo, Bon-Jun (Department of Biological Sciences, California Baptist University) ;
  • Hyun, Hae-Nam (Major of Plant Resources and Environment, Jeju National University)
  • Received : 2017.10.30
  • Accepted : 2017.11.28
  • Published : 2017.12.31
Download PDF
⟨ Previous Next ⟩

Abstract

Copper(II) acetate spectrophotometry method (CASM) was used for the rapid and convenient determination of cation exchange capacity (CEC) in soils. This method is composed of a single-step exchange reaction that adsorbs copper and is measured through spectrophotometry. The CEC of 16 Korean soils were measured using 1M ammonium acetate method (AAM) and the CASM. The CEC values determined by CASM and AAM were not significantly different, and were highly correlated ($r=0.966^{**}$). Due to the convenience, cost effectiveness, and time saving analysis of CASM, this method is recommended for most soil laboratories to measure CEC in Korean soils. However, CASM may not be applicable for soils that have a much higher CEC (greater than $20cmol_c\;kg^{-1}$).

Keywords

References

  1. Atanassova, I.D. 1995. Adsorption and desorption of Cu at high equilibrium concentrations by soil and clay samples from bulgaria. Environ. Pollut. 87:17-21. https://doi.org/10.1016/S0269-7491(99)80003-7
  2. Bergaya, F. and M. Vayer. 1997. CEC of clays: Measurement by adsorption of a copper ethylenediamine complex. Appl. Clay Sci. 12:275-280. https://doi.org/10.1016/S0169-1317(97)00012-4
  3. Brown, I.C. 1943. A rapid method of determining exchangeable hydrogen and total exchangeable bases of soils. Soil Sci. 56:353-358 (Abstr.). https://doi.org/10.1097/00010694-194311000-00004
  4. Chapman, H.D. 1965. Cation-exchange capacity, p. 891-901. In: C.A. Black et al. (ed.). Methods of soil analysis, Part 2. Vol. 9. American Society of Agronomy, Madison, WI. UAS.
  5. Chen, J., S. Yiacoumi, and T.G. Blaydes. 1996. Equilibrium and kinetic studies of copper adsorption by activated carbon. Sep. Technol. 6:133-146. https://doi.org/10.1016/0956-9618(96)00146-4
  6. Ciesielski, H. and T. Sterckeman. 1997. Determination of CEC and exchangeable cations in soils by means of cobalt hexamine trichloride. Effects of experimental conditions. Agronomie. 17:1-8.
  7. Ciesielski, H., T. Sterckeman, M. Santerne, and J.P. Willery. 1997. A comparison between three methods for the determination of cation exchange capacity and exchangeable cations in soils. Agronomie. 17:9-16. https://doi.org/10.1051/agro:19970102
  8. Dohrmann, R. 2006. Cation exchange capacity methodology II: A modified silver-thiourea method. Appl. Clay Sci. 34:31-37. https://doi.org/10.1016/j.clay.2005.12.006
  9. Gee, G.W. and J.W. Bauder. 1986. Particle-size analysis, p.383-411. In: A. Klute (ed.). Method of soil analysis, Part 1. Physical and mineralogical methods (2nd ed.). Agronomy Monograph no. 9, ASA-SSSA, Madison, WI. USA.
  10. Gillman, G.P. and E.A. Sumpter. 1986. Modification to the compulsive exchange method for measuring exchange characteristics of soils. Aust. J. Soil. Res. 24:61-66 (Abstr.). https://doi.org/10.1071/SR9860061
  11. Jung, B.G., J.W. Choi, E.S. Yun, J.H. Yoon, and Y.H. Kim. 2001. Monitoring on chemical properties of bench marked upland soils in Korea. Korean J. Soil Sci. Fert. 34:326-332.
  12. Kahr, G. and F.T. Medson. 1995. Determination of the cation exchange capacity and the surface area of bentonite, illite and kaolinite by methylene blue adsorption. Appl. Clay Sci. 9:327-336. https://doi.org/10.1016/0169-1317(94)00028-O
  13. Kang, S., A. Roh, S. Choi, Y. Kim, H. Kim, M. Choi, B. Ahn, H. Kim, H. Kim, J. Park, Y. Lee, S. Yang, J. Ryu, Y. Jang, M. Kim, Y. Sonn, C. Lee, S. Ha, D. Lee, and Y. Kim. 2012. Status and changes in chemical properties of paddy soil in Korea. Korean J. Soil Sci. Fert. 45:968-972. https://doi.org/10.7745/KJSSF.2012.45.6.968
  14. Khattak, Y.I. and M.A. Khan. 1995. Adsorption of copper from copper acetate and copper chloride solutions on carbon black "Spheron 9"---III.". Jour. Chem. Soc. Pak. 17:194-199.
  15. Kwon, E.Y. and K.R. Noh. 1990. Adsorption characteristics of Pb(II) an Cu(II) ions by domestic clays. Bull. Environ. Sci., Hanyang Univ. 11:45-54.
  16. Marosits, E., K. Polyák, and J. Hlavay. 2000. Investigation on the chemical bonding of copper ions on different soil samples. Microchem. J. 67:219-226. https://doi.org/10.1016/S0026-265X(00)00065-5
  17. Meier, L.P. and G. Kahr. 1999. Determination of the cation exchange capacity (CEC) of clay minerals using the complexes of copper(II) ion with triethylenetetramine and tetraethylenepentamine. Clays Clay Miner. 47:386-388. https://doi.org/10.1346/CCMN.1999.0470315
  18. Msaky, J.J. and R. Calvet. 1990. Adsorption behavior of copper and zinc in soils: Influence of pH on adsorption characteristics. Soil Sci. 150:513-522. https://doi.org/10.1097/00010694-199008000-00004
  19. NAAS, 2010. Analysis methods for soil chemical properties. NAAS. Suwon. Publication.
  20. NIAST. 1988. Methods of soil chemical analysis. National Institute of Agricultural Science and Technology, RDA, Suwon, Korea.
  21. O'Day, P.A., G.A. Parks, and G.E. Brown. 1994. Molecular structure and binding site of cobalt(II) surface complexes on kaolinite from x-ray adsorption spectroscopy. Clays Clay Miner. 3:337-355.
  22. Pratt, P.F. and N.A. Holowaychuk. 1954. A comparison of ammonium acetate, barium acetate, and buffered barium chloride methods of determining cation-exchange capacity. Soil Sci. Soc. Am. Proc. 18:365-368. https://doi.org/10.2136/sssaj1954.03615995001800040004x
  23. Silva, S., C. Baffi, S. Spalla, C. Cassinari, and P. Lodigiani. 2010. Method for the determination of CEC and exchangeable bases in calcareous soils. Agrochimica 56:103-114.
  24. Sparks, D.L. 1995. Environmental Soil Chemistry. Academic Press, SD, USA.
  25. Stadler, M. and P.W. Schindler. 1994. The effect of dissolved ligands on the sorption of Cu(II) by Ca-montmorillonite. Calys Clay Miner. 42:148-160. https://doi.org/10.1346/CCMN.1994.0420205
  26. Sumner, M.E. and W.P. Miller. 1996. Cation exchange capacity and exchange coefficients, p. 1201-1229. In: J. M. Bigham (ed.). Methods of Soil Analysis Part 3. Chemical Methods, ASA-SSSA, Madison, WI, USA.
  27. USDA. 2004. Soil Survey Laboratory Methods Manual Soil Survey Investigation Report No. 42 Version 4.0.
  28. Yoo, S.H. and H.N. Hyun. 1985. Behavior of cadmium, Zinc, and Copper in soils. I. Effect of organic matter treatment on adsorption of cadmium, zinc, and copper in soils. J. Korean Agric. Chem. Soc. 28:68-75.
  29. Yu, S., Z.L. He, C.Y. Huang, G.C. Chen, and D.V. Calvert. 2005. Effects of anions on the capacity and affinity of copper adsorption in two variable charge soils. Biogeochem. 75:1-18. https://doi.org/10.1007/s10533-003-5549-2