한국염색가공학회지 (Textile Coloration and Finishing)

  • 제29권4호
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  • Pages.195-201
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  • 2017
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  • 1229-0033(pISSN)
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  • 2234-036X(eISSN)
한국염색가공학회 (The Korean Society of Dyers and Finishers)
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프탈로시아닌계 안료의 함산소불소화가 수분산 특성에 미치는 영향

Effect of Oxyfluorination on Water Dispersion of Phthalocyanine Pigment

  • 이민규 (경북대학교 섬유시스템공학과) ;
  • 배진석 (경북대학교 섬유시스템공학과) ;
  • 김태경 (경북대학교 섬유시스템공학과) ;
  • 안승현 ((주)잉크테크) ;
  • 정민정 (충남대학교 응용화공학부) ;
  • 이영석 (충남대학교 응용화공학부) ;
  • 정의경 (경북대학교 섬유시스템공학과)
  • Lee, Min Kyu (Department of Textile System Engineering, Kyungpook National University) ;
  • Bae, Jin-Seok (Department of Textile System Engineering, Kyungpook National University) ;
  • Kim, Taekyeong (Department of Textile System Engineering, Kyungpook National University) ;
  • An, Seung-Hyun (InkTec Co., Ltd.) ;
  • Jung, Min-Jung (Department of Chemical Engineering and Applied Chemistry) ;
  • Lee, Young-Seak (Department of Chemical Engineering and Applied Chemistry) ;
  • Jeong, Euigyung (Department of Textile System Engineering, Kyungpook National University)
  • 투고 : 2017.11.12
  • 심사 : 2017.12.18
  • 발행 : 2017.12.27
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초록

To study the effect of oxyfluorination on water dispersion of phthalocyanine blue(C.I. pigment blue 15:3), the pigment was oxyfluorinated using various oxygen to fluorine ratio of the reactant gas. After the oxyfluorination of the phthalocyanine blue pigment, no significant change in FT-IR spectra was observed, whereas XPS spectra showed the introduction of oxygen and fluorine containing functional groups. This suggests that the oxyfluorination of the pigment only occurred on the surface of the pigment particle and resulted in no significant change in UV-Vis spectra of the pigment. However, the oxyflurinated pigments showed improved water dispersion, compared to the non-treated pigment. Especially, when the oxygen to fluorine ratio was 47:3, the water dispersion of the oxyfluorinated pigments significantly increased, compared to the non-treated pigments. This suggests that the oxyfluorination of the phthalocyanine blue pigment has a potential to be used as a water dispersion improving method.

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