Korean Journal of Soil Science and Fertilizer (한국토양비료학회지)

Korean Society of Soil Science and Fertilizer (한국토양비료학회)
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Competitive Adsorption and Subsequent Desorption of Sulfate in the Presence of Various Anions in Soils

  • Hong, Byeong-Deok (National Institute of Crop Science, RDA) ;
  • Lee, Kyo-seok (Department of Bio-Environmental Chemistry, Chungnam National University) ;
  • Lee, Dong-Sung (Department of Bio-Environmental Chemistry, Chungnam National University) ;
  • Rhie, Ja-Hyun (Department of Bio-Environmental Chemistry, Chungnam National University) ;
  • Bae, Hui-Su (Technical Review and Quality Management Institute, Korea Rural Community) ;
  • Seo, IL-Hwan (Department of Bio-Environmental Chemistry, Chungnam National University) ;
  • Song, Seung-Geun (Department of Bio-Environmental Chemistry, Chungnam National University) ;
  • Chung, Doug-Young (Department of Bio-Environmental Chemistry, Chungnam National University)
  • Received : 2016.10.06
  • Accepted : 2016.10.25
  • Published : 2016.10.31
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Abstract

In this experiment we investigated the influence of various anions including oxalic acid encountered as solution phase in soil on the adsorption and desorption of sulfate in Chungwon Bt soil. The effect of chloride and nitrate on the adsorption of sulfate was not significant, suggesting that sulfate was better able to compete for adsorption sites at concentrations studied, in contrast to the large reduction in the amount of chloride adsorbed in the presence of sulfate. The results of competition for sorption sites between sulfate and anion showed that the simultaneous presence of two anions in solution was effective in reduction of competing anion at a maximum value of adsorption, due to the similar adsorption mechanism for anion competition. Therefore, the variation in the buffer power of the acids will produce a change in the strength and amount of adsorption and the competitive ability.

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References

  1. Chao, T.T., M.E. Harward, and S.C. Fang. 1962. Adsorption and desorption phenomena of sulfate ions in soils. Soil Sci. Soc. Am. Proc. 26:234-237. https://doi.org/10.2136/sssaj1962.03615995002600030014x
  2. Chao, T.T., Harward, M.E., and S.C. Fang. 1963. Cationic effects on sulfate adsorption by soils. Soil Sci. Soc. Am. J. 29:35-38.
  3. Deb, D.L. and N.P. Datta. 1967. Effect of associating anions on phosphate retention in soil: Under variable Concentration. Plant Soil. 26:303-316. https://doi.org/10.1007/BF01880180
  4. Forster, S., G. Welp, and H.W. Scherer. 2012. Sulfur specification in bulk soil as influenced by long-term application of mineral and organic fertilizers. Plant Soil Environ. 58:316-321. https://doi.org/10.17221/32/2012-PSE
  5. Geelhoed, J.S., T. Hiemstra, and W.H. Van Riemsdijk. 1997. Phosphate and sulfate adsorption on goethite: Single anion and competitive adsorption. Geochim. Cosmochim. Acta. 61:2389-2396. https://doi.org/10.1016/S0016-7037(97)00096-3
  6. Haque, I. and D. Walmsley. 1973. Adsorption and desorption of sulphate in some soils of the West Indies. Geoderma 9:269-278. https://doi.org/10.1016/0016-7061(73)90028-1
  7. Hasan, S.M., R.L. Fox, and C.C. Boyd. 1970. Solubility and availability of sorbed sulphate in Hawaiian soils. Soil Sci. Soc. Am. Proc. 34:897-901. https://doi.org/10.2136/sssaj1970.03615995003400060024x
  8. Hingston, F.J., R.J. Atkinson, A.M. Posner, and J.P. Quirk. 1968. Specific adsorption of anions on geothite. Trans. 9th. Int. Congr. Soil Sci. 1:669-678.
  9. Hingston, F.J., A.M. Posner, and J.P. Quirk. 1971. Competitive adsorption of negatively charged ligand on oxide surfaces. Disc. Faraday. Soc. 52:334-342. https://doi.org/10.1039/df9715200334
  10. Hingston, F.J., A.M. Posner, and J.P. Quirk. 1972. Anion adsorption by goethite and gibbsite. 1. The role of the proton in determining adsorption envelopes. J. Soil Sci. 23:177-192. https://doi.org/10.1111/j.1365-2389.1972.tb01652.x
  11. Huang, P.M.A. Violante, J.M. Bollag, and P. Vityakon. 2005. Sorption/Desorption of Sulfate on/from Variable Charge Minerals and Soils: Competitive Effects of Organic and Inorganic Ligands. In: Soil Abiotic and Biotic Interactions and the Impact on the Ecosystem and Human Welfare. Science Publishers. pp. 15-221.
  12. Insskeep, W.P. 1989. Adsorption of sulfate by kaolinite and amorphous iron oxide in the presence of organic ligands. J. Environ. Qual. 18:379-285.
  13. Kamprath, E.J., W.L. Nelson, and J. W. Fitts. 1956. The effect of pH, sulfate and phosphate concentrations on the adsorption of sulfate in soils. Soil Sci. Soc. Am. Proc. 20:463-466 https://doi.org/10.2136/sssaj1956.03615995002000040005x
  14. Lopez-Hernandez, Siergert, D.G., and J.V. Rodriguez. 1986. Competitive adsorption of phosphate with malate and oxalate by tropical soils. Soil Sci. Soc. Am. J. 50:1460-1462. https://doi.org/10.2136/sssaj1986.03615995005000060016x
  15. Liu, F., J. He, C. Colombo, A. Violante. 1999. Competitive adsorption of sulfate and oxalate on goethite in the absence or presence of phosphate. Soil Sci. 164:180-189. https://doi.org/10.1097/00010694-199903000-00004
  16. Marion, S.P. and A.W. Thomas. 1946. The effect of diverse anions on the pH value of maximum precipitation of aluminum hydroxide. J. Colloid. Sci. 1:221-233 https://doi.org/10.1016/0095-8522(46)90044-X
  17. Martinez, C.E., A.W. Kleinschmidt, and M.A. Tabatabai. 1998. Sulfate adsorption by variable charge soils: effect of lowmolecularweight organic acids. Biol. Fertil. Soils 26:157-163. https://doi.org/10.1007/s003740050361
  18. Nagarajah, S., A.M. Posner, and Quirk, J.P. 1968. Desorption of phosphate from kaolinite by citrate and bicarbonate. Soil Sci. Soc. Proc. J. 32:507-510. https://doi.org/10.2136/sssaj1968.03615995003200040025x
  19. Nagarajah, S., A.M. Posner, and J.P. Quirk. 1970. Competitive adsorption of phosphate with polygalaturonate and the other organic anions on kaolinite and oide surfaces. Nature (London). 228:83-85. https://doi.org/10.1038/228083a0
  20. Samira, A., M. Ben, S. Hawaa, Elferjani, Faiza A. H. Fatma, and F. Abdelnabi. 2009. Determination of available nitrate, phosphate and sulfate in soil samples. Int. J. PharmTech Res. 1:598-604.
  21. Scherer, H.W. 2001. Sulphur in crop production. Eur. J. Agron. 14:81-111. https://doi.org/10.1016/S1161-0301(00)00082-4
  22. Scherer H.W. 2009. Sulfur in soils. J. Plant Nutr. Soil Sci. 172:326-335. https://doi.org/10.1002/jpln.200900037
  23. Scherer, H.W., G. Welp, and S. Forster. 2012. Sulfur fractions in particle-size separates as influenced by long-term application of mineral and organic fertilizers. Plant Soil Environ. 58:242-248. https://doi.org/10.17221/78/2012-PSE
  24. Scott, N.M. 1976. Sulphate contents and sorption in Scottish soils. J. Sci. Food Agic. 27:367-372. https://doi.org/10.1002/jsfa.2740270411
  25. Seth, R. 1998. Anion adsorption and desorption characteristics of a piedmont ultisol: some implications for the fate of sulfate deposition. Water Air Soil Pollut. 101:333-347. https://doi.org/10.1023/A:1004916724390
  26. Sokolova, T.A. and S.A. Alekseeva. 2008. Adsorption of sulfate ions by soils. Eurasian Soil Sci. 41:140-148. https://doi.org/10.1134/S106422930802004X
  27. Sumner, M.E. 2000. Handbook of Soil Science. CRC Press, Boca Raton, FL.
  28. Violante, A., C. Colombom, and A. Buondononno. 1991. Competitive desorption of phosphate and oxalate by aluminum oxides. Soil Sci. Soc. Am. J. 55:65-70. https://doi.org/10.2136/sssaj1991.03615995005500010011x
  29. Zhao, F., and S.P. McGrath. 1994. Extractable sulphate and organic sulphur in soils and their availability to plants. Plant Soil 164:243-250. https://doi.org/10.1007/BF00010076
  30. Zhao, F.J., M.J. Hawkesford, A.G.S. Warrilow, S.P. McGrath, and D.T. Clarkson. 1996. Response of two wheat varieties to sulfur addition and diagnosis of sulfur deficiency. Plant Soil. 181:317-327. https://doi.org/10.1007/BF00012066