Resources Recycling (자원리싸이클링)

The Korean Institute of Resources Recycling (한국자원리싸이클링학회)
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Recovery of High Purity Tin from Waste Solution of the Tin Plating by Ion-exchange and Cyclone-electrowinning

주석도금폐액으로부터 이온교환 및 사이클론 전해채취를 이용한 고순도 주석의 회수

  • Kang, Yong-Ho (Research & Development Center, Incheon Chemical Ltd.) ;
  • Shin, Gi-Wung (Research & Development Center, Incheon Chemical Ltd.) ;
  • Ahn, Jae-Woo (Department of Advanced Materials Sci. & Eng., Daejin University)
  • Received : 2016.05.27
  • Accepted : 2016.07.07
  • Published : 2016.08.31
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Abstract

A research for the recovery of the metal with high purity from the waste tin plating solution was carried out. First, tin plating waste solution was tested to remove the organic substances and metallic impurities such as Fe, Zn, Na etc. using ion exchange resin having iminodiacetic functional groups (Lewatit TP 207). Second, the tin solution was purified to obtain the high purity tin solution using ion exchange resin having ethylhexyl-phosphate functional groups (Lewatit VPOC 1026). Finally, 99.98% of the high purity of tin metal can be recovered from the purified solution by cyclone type electrowinning method.

주석도금폐액으로부터 고순도 주석 금속을 회수하는 연구를 실시하였다. 먼저 주석도금폐액을 Iminodiacetic 관능기를 가진 이온교환수지(Lewatit TP 207)를 사용하여 1차적으로 유기물 및 Fe, Zn, Na 등의 불순물을 제거하였고, 2차적으로 Ethylhexyl-phosphate의 관능기를 가진 이온교환수지(Lewatit VPOC 1026)를 사용하여 잔류하고 있는 불순물들을 모두 제거하여 고순도의 주석용액으로 회수하였다. 회수된 주석용액으로부터 고순도 금속주석으로 회수하기 위하여 사이클론식 전해방법을 사용하였으며, 전해채취 결과 약 99.98% 순도의 주석을 회수할 수 있었다.

Keywords

References

  1. B. S. KIM and T. S. KIM and H. S. Lee, 2014 : Handbook of Korea rare metals 2014.
  2. Sun, E. Y. L., 1991 "The recovery of metal from electronic scrap." JOM, 43(4), pp.53-61.
  3. Ki-Woong Lee et al., 2014 " Separation and recovery of tin indium from spent ITO sludge" J. of Korean Inst. of Resources Recycling, 23(2), pp.53-60. https://doi.org/10.7844/kirr.2014.23.2.53
  4. J. Y. Lee, 2004 "Method for Recycling Tin Oxide or Tin from Plating Tin Waste Liquid ," Kor. Patent, 10-2004-0107786.
  5. Jae-Woo Ahn and Jae-Seong Seo, 2009 "Nitric acid leaching of electronic scraps and the removal of free nicric acid from the leaching solution for the recovery of copper and tin." J. of Korean Inst. of Resources Recycling, 18(5), pp.44-51.
  6. K. S. Ryu and J. S. Kim, 2007 "Method of Leaching from Sludge Contained Tin and/or Tin Oxide" Kor. Patent,10-2007-0101110.
  7. Gi-Wung Shin et al, 2015 : "Recovery of tin from waste tin plating solution by ion exchange resin" J. of Korean Inst. of Resources Recycling, 24(3), pp. 51-58.
  8. Soo-Kyung Kim et al, 2005 : " Electrowinning of Platinum using a modified cyclone reactor" J. of the Korean Society for Geosystem Engineering, 42(1), pp. 35-44.
  9. Soo-Kyung Kim et al, 2006 : " Hydrodynamic analysis for Electrowinning of Palladium using a modified cyclone reactor" J. of the Korean Society for Geosystem Engineering, 43(3), pp. 250-257.
  10. Myeong-sik Kang et al, 2016 : "Electrowinning of tin from acdic sulfate effluent using a cyclone electrolytic cell." J. of Korean Inst. of Resources Recycling, 25(2), pp. 25-32. https://doi.org/10.7844/kirr.2016.25.2.25
  11. P. A. Treasure, "Perfomance characterics of the EMEW$^{(R)}$ Cell" Electrochemical Society Processing Volume 2003-18, pp. 367-378.
  12. Wei Jin et al, 2015 : "Electrolytic recovery of bismuth and copper as a powder from acidic sulfate effluents using an emew$^{(R)}$ cell" RCS Advances, 5(62), pp. 50372-50378.
  13. V. Escobar, T. Treasure and R. E. Dixon, 2003 : "High current density emew copper electrowinning" Proceedings of the TMS Fall Extraction and Processing Conference, Chicago: The Minerals, Metals and Materials Society, pp.1369-1380.
  14. Jeremy Robinson, Ian Ewart, Michael Moats and Shijie Wang, 2013 : "High Current Density Electrowinning of Nickel in EMEW$^{(R)}$ Cells" Ni-Co 2013, The Minerals, Metals & Materials Society, pp. 191-199.
  15. GUO Xue-yi, SHI Wen-tang, LI Dong, TIAN Qing-hua, 2010 : "Recovery of copper and nickel from electroplating sludge by cyclone electrowinning" The Chinese Journal of Nonferrous Metals, 20(12), pp. 2425-2430.