Korean Chemical Engineering Research

  • 제54권5호
  • /
  • Pages.636-647
  • /
  • 2016
  • /
  • 0304-128X(pISSN)
  • /
  • 2233-9558(eISSN)
한국화학공학회 (The Korean Institute of Chemical Engineers)
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Immobilization of the Thenoyltrifluoroacetone on Sodium Dodecyl Sulfate Modified Magnetite Nanoparticles for Magnetic Solid Phase Extraction of Pb (II) from Water Samples

  • Sadeghi, Meysam (Young Researchers and Elite Club, Ahvaz Branch, Islamic Azad University) ;
  • Yekta, Sina (Department of Chemistry, Faculty of Basic Sciences, Islamic Azad University) ;
  • Babanezhad, Esmaeil (Department of Applied Chemistry, Faculty of Pharmaceutical Chemistry, Pharmaceutical Sciences Branch, Islamic Azad University)
  • 투고 : 2016.04.22
  • 심사 : 2016.08.02
  • 발행 : 2016.10.01
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초록

Magnetite nanoparticles ($Fe_3O_4$ NPs) were synthesized by co-precipitating method under optimized condition. The $Fe_3O_4$ NPs coated with sodium dodecyl sulfate-thenoyltrifluoroacetone ($Fe_3O_4$ NPs-SDS-TTFA) were then exerted as the magnetic solid phase extraction (MSPE) adsorbent for the extraction process prior to introducing to a flame atomic adsorption spectrometry (FAAS). The synthesized $Fe_3O_4$ NPs-SDS-TTFA were applied for the extraction of Pb(II) ions from different water samples. The characterization studies of nanoparticles were performed via scanning electron microscopy-energy dispersive micro-analysis (SEM-EDAX), X-ray diffraction (XRD) and vibrating sample magnetometer (VSM) techniques. The substantial parameters affecting the extraction efficiency were surveyed and optimized. A dynamic linear range (DLR) of $10-400{\mu}g\;L^{-1}$ was obtained and the limit of detection (LOD, n=7) and relative standard deviation (RSD%, n= 6, $C=20{\mu}g\;L^{-1}$) were found to be $2.3{\mu}g\;L^{-1}$ and 1.9%, respectively. According to the results, the proposed method successfully applied for the extraction of Pb(II) ions from different environmental water samples and satisfactory results achieved.

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  1. vol.40, pp.20, 2017, https://doi.org/10.1080/10826076.2017.1402186