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High Strength Electrospun Nanofiber Mats via CNT Reinforcement: A Review

  • Pant, Bishweshwar (Department of Chemistry, Inha University) ;
  • Park, Mira (Department of Organic Materials and Fiber Engineering, Chonbuk National University) ;
  • Park, Soo-Jin (Department of Chemistry, Inha University) ;
  • Kim, Hak Yong (Department of Organic Materials and Fiber Engineering, Chonbuk National University)
  • 투고 : 2016.08.17
  • 심사 : 2016.08.31
  • 발행 : 2016.08.31

초록

The development of electrospun nanofibers with improved mechanical properties is of great scientific and technological interest because of their wide-range of applications. Reinforcement of carbon nanotubes (CNTs) into the polymer matrix is considered as a promising strategy for substantially enhancing the mechanical properties of resulting CNTs/polymer composite mats on account of extraordinary mechanical properties of CNTs such as ultra-high Young's modulus and tensile strengths. This paper summarizes the recent developments on electrospun CNTs/polymer composite mats with an emphasis on their mechanical properties.

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참고문헌

  1. Lu, X., Zhang, W., Wang, C., Wen, T.-C., and Wei, Y., "Onedimensional Conducting Polymer Nanocomposites: Synthesis, Properties and Applications", Progress in Polymer Science, Vol. 36, 2011, pp. 671-712. https://doi.org/10.1016/j.progpolymsci.2010.07.010
  2. Kuchibhatla, S.V.N.T., Karakoti, A.S., Bera, D., and Seal, S., "One Dimensional Nanostructured Materials", Progress in Materials Science, Vol. 52, 2007, pp. 699-913. https://doi.org/10.1016/j.pmatsci.2006.08.001
  3. Zach, M.P., Ng, K.H., and Penner, R.M., "Molybdenum Nanowires by Electrodeposition", Science, Vol. 290, 2000, pp. 2120-2123. https://doi.org/10.1126/science.290.5499.2120
  4. Hu, J., Odom, T.W., and Lieber, C.M., "Chemistry and Physics in One Dimension: Synthesis and Properties of Nanowires and Nanotubes", Accounts of Chemical Research, Vol. 32, 1999, pp. 435-445. https://doi.org/10.1021/ar9700365
  5. Pant, B., Pant, H.R., Pandeya, D.R., Panthi, G., Nam, K.T., Hong, S.T., Kim, C.S., and Kim, H.Y., "Characterization and Antibacterial Properties of Ag NPs Loaded Nylon-6 Nanocomposite Prepared by One-step Electrospinning Process", Colloids and Surfaces A: Physicochemical and Engineering Aspects, Vol. 395, 2012, pp. 94-99.
  6. Xu, C.Y., Inai, R., Kotaki, M., and Ramakrishna, S., "Aligned Biodegradable Nanofibrous Structure: A Potential Scaffold for Blood Vessel Engineering", Biomaterials, Vol. 25, 2004, pp. 877-886. https://doi.org/10.1016/S0142-9612(03)00593-3
  7. Huang, Z.-M., Zhang, Y.Z., Kotaki, M., and Ramakrishna, S., "A Review on Polymer Nanofibers by Electrospinning and Their Applications in Nanocomposites", Composites Science and Technology, Vol. 63, 2003, pp. 2223-2253. https://doi.org/10.1016/S0266-3538(03)00178-7
  8. Zhang, H., Wu, C., Zhang, Y., White, C.J.B., Xue, Y., Nie, H., and Zhu, L., "Elaboration, Characterization and Study of a Novel Affinity Membrane Made from Electrospun Hybrid Chitosan/ nylon-6 Nanofibers for Papain Purification", Journal of Materials Science, Vol. 45, 2010, pp. 2296-2304. https://doi.org/10.1007/s10853-009-4191-3
  9. Kumbar, S.G., Nukavarapu, S.P., James, R., Nair, L.S., and Laurencin, C.T., "Electrospun Poly(lactic acid-co-glycolic acid) Scaffolds for Skin Tissue Engineering", Biomaterials, Vol. 29, 2008, pp. 4100-4107. https://doi.org/10.1016/j.biomaterials.2008.06.028
  10. Sill, T.J., and von Recum, H.A., "Electrospinning: Applications in Drug Delivery and Tissue Engineering", Biomaterials, Vol. 29, 2008, pp. 1989-2006. https://doi.org/10.1016/j.biomaterials.2008.01.011
  11. Ding, Y., Hou, H., Zhao, Y., Zhu, Z., and Fong, H., "Electrospun Polyimide Nanofibers and Their Applications", Progress in Polymer Science, http://dx.doi.org/10.1016/j.progpolymsci.2016.06.006, 2016.
  12. Ezhilvalavan, S., Branicio, P.S., Kong, L.B., Sundarrajan, S., Tan, K.L., Lim, S.H., and Ramakrishna, S., International Conference on Materials for Advanced Technologies (ICMAT2013), Symposium W - Advanced Structural and Functional Materials for Protection Electrospun Nanofibers for Air Filtration Applications, Procedia Engineering, Vol. 75, 2014, pp. 159-163. https://doi.org/10.1016/j.proeng.2013.11.034
  13. Pant, B., Barakat, N.A.M., Pant, H.R., Park, M., Saud, P.S., Kim, J.-W., and Kim, H.-Y., "Synthesis and Photocatalytic Activities of CdS/$TiO_2$ Nanoparticles Supported on Carbon Nanofibers for High Efficient Adsorption and Simultaneous Decomposition of Organic Dyes", Journal of Colloid and Interface Science, Vol. 434, 2014, pp. 159-166. https://doi.org/10.1016/j.jcis.2014.07.039
  14. Chigome, S., Darko, G., and Torto, N., "Electrospun Nanofibers as Sorbent Material for Solid Phase Extraction", Analyst, Vol. 136, 2011, pp. 2879-2889. https://doi.org/10.1039/c1an15228a
  15. Leung, W.W.-F., Hung, C.-H., and Yuen, P.-T., "Effect of Face Velocity, Nanofiber Packing Density and Thickness on Filtration Performance of Filters with Nanofibers Coated on a Substrate", Separation and Purification Technology, Vol. 71, 2010, pp. 30-37. https://doi.org/10.1016/j.seppur.2009.10.017
  16. Lv, Y.-Y., Xu, W., Lin, F.-W., Wu, J., and Xu, Z.-K., "Electrospun Nanofibers of Porphyrinated Polyimide for the Ultra-sensitive Detection of Trace TNT", Sensors and Actuators B: Chemical, Vol. 184, 2013, pp. 205-211. https://doi.org/10.1016/j.snb.2013.04.094
  17. Verreck, G., Chun, I., Rosenblatt, J., Peeters, J., Dijck, A.V., Mensch, J., Noppe, M., and Brewster, M.E., "Incorporation of Drugs in an Amorphous State into Electrospun Nanofibers Composed of a Water-insoluble, Nonbiodegradable Polymer", Journal of Controlled Release, Vol. 92, 2003, pp. 349-360. https://doi.org/10.1016/S0168-3659(03)00342-0
  18. Mohammadzadehmoghadam, S., Dong, Y., and Jeffery Davies, I., "Recent Progress in Electrospun Nanofibers: Reinforcement Effect and Mechanical Performance", Journal of Polymer Science Part B: Polymer Physics, Vol. 53, 2015, pp. 1171-1212.
  19. Wang, X., Ding, B., Sun, G., Wang, M., and Yu, J., "Electrospinning/ netting: A Strategy for the Fabrication of Threedimensional Polymer Nano-fiber/nets", Progress in Materials Science, Vol. 58, 2013, pp. 1173-1243. https://doi.org/10.1016/j.pmatsci.2013.05.001
  20. Pant, H.R., Bajgai, M.P., Nam, K.T., Seo, Y.A., Pandeya, D.R., Hong, S.T., and Kim, H.Y., "Electrospun Nylon-6 Spider-net Like Nanofiber Mat Containing $TiO_2$ Nanoparticles: A Multifunctional Nanocomposite Textile Material", Journal of Hazardous Materials, Vol. 185, 2011, pp. 124-130. https://doi.org/10.1016/j.jhazmat.2010.09.006
  21. Pant, B., Pant, H.R., Barakat, N.A.M., Park, M., Han, T.-H., Lim, B.H., and Kim, H.-Y., "Incorporation of Cadmium Sulfide Nanoparticles on the Cadmium Titanate Nanofibers for Enhanced Organic Dye Degradation and Hydrogen Release", Ceramics International, Vol. 40, 2014, pp. 1553-1559. https://doi.org/10.1016/j.ceramint.2013.07.042
  22. Pant, H.R., Risal, P., Park, C.H., Tijing, L.D., Jeong, Y.J., and Kim, C.S., "Core-shell Structured Electrospun Biomimetic Composite Nanofibers of Calcium Lactate/nylon-6 for Tissue Engineering", Chemical Engineering Journal, Vol. 221, 2013, pp. 90-98. https://doi.org/10.1016/j.cej.2013.01.072
  23. Pant, B., Pant, H.R., Barakat, N.A.M., Park, M., Jeon, K., Choi, Y., and Kim, H.-Y., "Carbon Nanofibers Decorated with Binary Semiconductor ($TiO_2$/ZnO) Nanocomposites for the Effective Removal of Organic Pollutants and the Enhancement of Antibacterial Activities", Ceramics International, Vol. 39, 2013, pp. 7029-7035. https://doi.org/10.1016/j.ceramint.2013.02.041
  24. Doshi, J., and Reneker, D.H., Selected Papers from the Special Technical Session "Electrostatics in Polymer Processing and Charge Monitoring", 1993 IEEE Industry Applications Society Meeting Electrospinning Process and Applications of Electrospun Fibers, Journal of Electrostatics, Vol. 35, 1995, pp. 151-160.
  25. Matthews, J.A., Wnek, G.E., Simpson, D.G., and Bowlin, G.L., "Electrospinning of Collagen Nanofibers", Biomacromolecules, Vol. 3, 2002, pp. 232-238. https://doi.org/10.1021/bm015533u
  26. Lee, K.H., Kim, H.Y., Khil, M.S., Ra, Y.M., and Lee, D.R., "Characterization of Nano-structured Poly($\varepsilon$-caprolactone) Nonwoven Mats via Electrospinning", Polymer, Vol. 44, 2003, pp. 1287-1294. https://doi.org/10.1016/S0032-3861(02)00820-0
  27. Nair, L.S., Bhattacharyya, S., Bender, J.D., Greish, Y.E., Brown, P.W., Allcock, H.R., and Laurencin, C.T., "Fabrication and Optimization of Methylphenoxy Substituted Polyphosphazene Nanofibers for Biomedical Applications", Biomacromolecules, Vol. 5, 2004, pp. 2212-2220. https://doi.org/10.1021/bm049759j
  28. Mittal, G., Dhand, V., Rhee, K.Y., Park, S.-J., and Lee, W.R., "A Review on Carbon Nanotubes and Graphene as Fillers in Reinforced Polymer Nanocomposites", Journal of Industrial and Engineering Chemistry, Vol. 21, 2015, pp. 11-25. https://doi.org/10.1016/j.jiec.2014.03.022
  29. Al-Saleh, M.H., and Sundararaj, U., "Review of the Mechanical Properties of Carbon Nanofiber/polymer Composites", Composites Part A: Applied Science and Manufacturing, Vol. 42, 2011, pp. 2126-2142. https://doi.org/10.1016/j.compositesa.2011.08.005
  30. Salalha, W., Dror, Y., Khalfin, R.L., Cohen, Y., Yarin, A.L., and Zussman, E., "Single-Walled Carbon Nanotubes Embedded in Oriented Polymeric Nanofibers by Electrospinning", Langmuir, Vol. 20, 2004, pp. 9852-9855. https://doi.org/10.1021/la048536b
  31. Dror, Y., Salalha, W., Khalfin, R.L., Cohen, Y., Yarin, A.L., and Zussman, E., "Carbon Nanotubes Embedded in Oriented Polymer Nanofibers by Electrospinning", Langmuir, Vol. 19, 2003, pp. 7012-7020. https://doi.org/10.1021/la034234i
  32. Su, Z., Ding, J., and Wei, G., "Electrospinning: A Facile Technique for Fabricating Polymeric Nanofibers Doped with Carbon Nanotubes and Metallic Nanoparticles for Sensor Applications", RSC Advances, Vol. 4, 2014, pp. 52598-52610. https://doi.org/10.1039/C4RA07848A
  33. Oberlin, A., Endo, M., and Koyama, T., "Filamentous Growth of Carbon through Benzene Decomposition", Journal of Crystal Growth, Vol. 32, 1976, pp. 335-349. https://doi.org/10.1016/0022-0248(76)90115-9
  34. Iijima, S., "Helical Microtubules of Graphitic Carbon", Nature, Vol. 354, 1991, pp. 56-58. https://doi.org/10.1038/354056a0
  35. Baughman, R.H., Zakhidov, A.A., and de Heer, W.A., "Carbon Nanotubes--the Route Toward Applications", Science, Vol. 297, 2002, pp. 787-792. https://doi.org/10.1126/science.1060928
  36. Arash, B., Wang, Q., and Varadan, V.K., "Mechanical Properties of Carbon Nanotube/polymer Composites", Scientific Reports, Vol. 4, 2014, pp. 6479. https://doi.org/10.1038/srep06479
  37. Kaseem, M., Hamad, K., and Ko, Y.G., "Fabrication and Materials Properties of Polystyrene/carbon Nanotube (PS/CNT) Composites: A Review", European Polymer Journal, Vol. 79, 2016, pp. 36-62. https://doi.org/10.1016/j.eurpolymj.2016.04.011
  38. Coleman, J.N., Khan, U., and Gun'ko, Y.K., "Mechanical Reinforcement of Polymers Using Carbon Nanotubes", Advanced Materials, Vol. 18, 2006, pp. 689-706. https://doi.org/10.1002/adma.200501851
  39. Safadi, B., Andrews, R., and Grulke, E.A., "Multiwalled Carbon Nanotube Polymer Composites: Synthesis and Characterization of Thin Films", Journal of Applied Polymer Science, Vol. 84, 2002, pp. 2660-2669. https://doi.org/10.1002/app.10436
  40. Liao, K., and Li, S., "Interfacial Characteristics of a Carbon Nanotube-polystyrene Composite System", Applied Physics Letters, Vol. 79, 2001, pp. 4225-4227. https://doi.org/10.1063/1.1428116
  41. Koziol, K.K.K., Boncel, S., Shaffer, M.S.P., and Windle, A.H., "Aligned Carbon Nanotube-polystyrene Composites Prepared by in situ Polymerisation of Stacked Layers", Composites Science and Technology, Vol. 71, 2011, pp. 1606-1611. https://doi.org/10.1016/j.compscitech.2011.07.007
  42. Patole, A.S., Patole, S.P., Yoo, J.-B., An, J.-H., and Kim, T.-H., "Fabrication of Polystyrene/multiwalled Carbon Nanotube Composite Films Synthesized by in situ Microemulsion Polymerization", Polymer Engineering & Science, Vol. 53, 2013, pp. 1327-1336. https://doi.org/10.1002/pen.23385
  43. Yao, J., Bastiaansen, C., and Peijs, T., "High Strength and High Modulus Electrospun Nanofibers", Fibers, Vol. 2, 2014, pp. 158. https://doi.org/10.3390/fib2020158
  44. Ko, F., Gogotsi, Y., Ali, A., Naguib, N., Ye, H., Yang, G.L., Li, C., and Willis, P., "Electrospinning of Continuous Carbon Nanotube- Filled Nanofiber Yarns", Advanced Materials, Vol. 15, 2003, pp. 1161-1165. https://doi.org/10.1002/adma.200304955
  45. Kim, G.M., Michler, G.H., and Potschke, P., "Deformation Processes of Ultrahigh Porous Multiwalled Carbon Nanotubes/ polycarbonate Composite Fibers Prepared by Electrospinning", Polymer, Vol. 46, 2005, pp. 7346-7351. https://doi.org/10.1016/j.polymer.2005.06.008
  46. Ge, J.J., Hou, H., Li, Q., Graham, M.J., Greiner, A., Reneker, D.H., Harris, F.W., and Cheng, S.Z.D., "Assembly of Well- Aligned Multiwalled Carbon Nanotubes in Confined Polyacrylonitrile Environments: Electrospun Composite Nanofiber Sheets", Journal of the American Chemical Society, Vol. 126, 2004, pp. 15754-15761. https://doi.org/10.1021/ja048648p
  47. Sen, R., Zhao, B., Perea, D., Itkis, M.E., Hu, H., Love, J., Bekyarova, E., and Haddon, R.C., "Preparation of Single-Walled Carbon Nanotube Reinforced Polystyrene and Polyurethane Nanofibers and Membranes by Electrospinning", Nano Letters, Vol. 4, 2004, pp. 459-464. https://doi.org/10.1021/nl035135s
  48. H. Hou, J.J. Ge, J. Zeng, Q. Li, D.H. Reneker, A. Greiner, S.Z.D. Cheng, "Electrospun Polyacrylonitrile Nanofibers Containing a High Concentration of Well-Aligned Multiwall Carbon Nanotubes", Chemistry of Materials, Vol. 17, 2005, pp. 967-973. https://doi.org/10.1021/cm0484955
  49. McCullen, S.D., Stano, K.L., Stevens, D.R., Roberts, W.A., Monteiro- Riviere, N.A., Clarke, L.I., and Gorga, R.E., "Development, Optimization, and Characterization of Electrospun Poly(lactic acid) Nanofibers Containing Multi-walled Carbon Nanotubes", Journal of Applied Polymer Science, Vol. 105, 2007, pp. 1668-1678. https://doi.org/10.1002/app.26288
  50. Baji, A., Mai, Y.-W., Wong, S.-C., Abtahi, M., and Du, X., "Mechanical Behavior of Self-assembled Carbon Nanotube Reinforced Nylon 6,6 Fibers", Composites Science and Technology, Vol. 70, 2010, pp. 1401-1409. https://doi.org/10.1016/j.compscitech.2010.04.020
  51. Ozden-Yenigun, E., Menceloglu, Y.Z., and Papila, M., "MWCNTs/P(St-co-GMA) Composite Nanofibers of Engineered Interface Chemistry for Epoxy Matrix Nanocomposites", ACS Applied Materials & Interfaces, Vol. 4, 2012, pp. 777-784. https://doi.org/10.1021/am2014162
  52. Liu, L., Zhou, Y., and Pan, S., "Experimental and Analysis of the Mechanical Behaviors of Multi-walled Nanotubes/polyurethane Nanoweb Reinforced Epoxy Composites", Journal of Reinforced Plastics and Composites, Vol. 32, 2013, pp. 823-834. https://doi.org/10.1177/0731684413480007
  53. Gao, J., Li, W., Shi, H., Hu, M., and Li, R.K.Y., "Preparation, Morphology, and Mechanical Properties of Carbon Nanotube Anchored Polymer Nanofiber Composite", Composites Science and Technology, Vol. 92, 2014, pp. 95-102. https://doi.org/10.1016/j.compscitech.2013.12.008
  54. Tijing, L.D., Choi, W., Jiang, Z., Amarjargal, A., Park, C.-H., Pant, H.R., Im, I.-T., and Kim, C.S., "Two-nozzle Electrospinning of (MWNT/PU)/PU Nanofibrous Composite Mat with Improved Mechanical and Thermal Properties", Current Applied Physics, Vol. 13, 2013, pp. 1247-1255. https://doi.org/10.1016/j.cap.2013.03.023
  55. Chen, D., Liu, T., Zhou, X., Tjiu, W.C., and Hou, H., "Electrospinning Fabrication of High Strength and Toughness Polyimide Nanofiber Membranes Containing Multiwalled Carbon Nanotubes", The Journal of Physical Chemistry B, Vol. 113, 2009, pp. 9741-9748.
  56. Lu, P., and Hsieh, Y.-L., "Multiwalled Carbon Nanotube (MWCNT) Reinforced Cellulose Fibers by Electrospinning", ACS Applied Materials & Interfaces, Vol. 2, 2010, pp. 2413-2420. https://doi.org/10.1021/am1004128
  57. Ayutsede, J., Gandhi, M., Sukigara, S., Ye, H., Hsu, C.-M., Gogotsi, Y., and Ko, F., "Carbon Nanotube Reinforced Bombyx mori Silk Nanofibers by the Electrospinning Process", Biomacromolecules, Vol. 7, 2006, pp. 208-214. https://doi.org/10.1021/bm0505888
  58. Jeon, K.S., Nirmala, R., Navamathavan, R., and Kim, H.Y., "Mechanical Behavior of Electrospun Nylon66 Fibers Reinforced with Pristine and Treated Multi-walled Carbon Nanotube Fillers", Ceramics International, Vol. 39, 2013, pp. 8199- 8206. https://doi.org/10.1016/j.ceramint.2013.04.003
  59. Jose, M.V., Steinert, B.W., Thomas, V., Dean, D.R., Abdalla, M.A., Price, G., and Janowski, G.M., "Morphology and Mechanical Properties of Nylon 6/MWNT Nanofibers", Polymer, Vol. 48, 2007, pp. 1096-1104. https://doi.org/10.1016/j.polymer.2006.12.023

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