DOI QR코드

DOI QR Code

용체화처리된 Mg-4%Zn 합금의 부식 저항성에 미치는 미량 Ca 첨가의 영향

Effect of Trace Amount of Ca on Corrosion Resistance of Solutionized Mg-4%Zn Alloy

  • 전중환 (한국생산기술연구원 뿌리산업기술연구소 융합공정신소재그룹) ;
  • 황인제 (한국생산기술연구원 뿌리산업기술연구소 융합공정신소재그룹)
  • Jun, Joong-Hwan (Advanced Process and Materials R&D Group, Korea Institute of Industrial Technology) ;
  • Hwang, In-Je (Advanced Process and Materials R&D Group, Korea Institute of Industrial Technology)
  • 투고 : 2016.05.06
  • 심사 : 2016.05.19
  • 발행 : 2016.07.30

초록

Influence of trace amount of Ca addition on the corrosion resistance was comparatively investigated in solutionized Mg-4%Zn and Mg-4%Zn-0.1%Ca alloys. In as-cast state, the alloys were characterized by primary ${\alpha}-(Mg)$ dendrite with MgZn intermetallic compound particles. After solution-treatment, both alloys consisted of single ${\alpha}-(Mg)$ phase by dissolution of the compound particles into the matrix. It was found from the immersion and electrochemical corrosion tests that the Mg-4%Zn alloy had better corrosion resistance than the Mg-4%Zn-0.1%Ca alloy. Morphological and compositional analyses on the surface corrosion products indicate that the incorporation of Ca oxide with low PBR value into the surface corrosion products would be responsible for the decreased corrosion resistance of the Ca-containing alloy.

키워드

참고문헌

  1. B. L. Mordike and T. Ebert : Mater. Sci. Eng. A 302 (2001) 37. https://doi.org/10.1016/S0921-5093(00)01351-4
  2. S. Zhang, X. Zhang, C. Zhao, J. Li, Y. Song, C. Xie, H. Tao, Y. Zhang, Y. He, Y. Jiang and Y. Bian : Acta Biomater. 6 (2010) 626. https://doi.org/10.1016/j.actbio.2009.06.028
  3. Y. Sun, B. Zhang, Y. Wang, L. Geng and X. Jiao : Mater. Des. 34 (2012) 58. https://doi.org/10.1016/j.matdes.2011.07.058
  4. D. Zander and N. A. Zumdick : Corros. Sci. 93 (2015) 222. https://doi.org/10.1016/j.corsci.2015.01.027
  5. G. Song : Corros. Sci. 49 (2007) 1696. https://doi.org/10.1016/j.corsci.2007.01.001
  6. S. S. A. El-Rahman : Pharmacol. Res. 47 (2003) 189. https://doi.org/10.1016/S1043-6618(02)00336-5
  7. N. Yumiko, T. Yukari, T. Yasuhide. S. Tadashi and I. Yoshio : Fundam. Appl. Toxicol. 37 (1997) 106. https://doi.org/10.1006/faat.1997.2322
  8. W. Yang, P. Zhang, J. Liu and Y. Xue : J. Rare Earth 24 (2006) 369. https://doi.org/10.1016/S1002-0721(06)60126-9
  9. J. Hanawalt, C. Nelson and J. Peloubet : Trans. AIME 147 (1942) 273.
  10. M. M. Avedesian and H. Baker : Magnesium and Magnesium Alloys, ASM International, p. 15.
  11. S. S. Li, B. Tang and D. B. Zeng : J. Alloys Compd. 437 (2007) 317. https://doi.org/10.1016/j.jallcom.2006.07.117
  12. M. B. Kannan and R. K. Raman : Biomater. 29 (2008) 2306. https://doi.org/10.1016/j.biomaterials.2008.02.003
  13. H. R. Bakhsheshi-Rad, E. Hamzah, A. Fereidouni-Lotfabadi, M. Daroonparvar, M. A. M. Yajid, M. Mezbahul-Islam, M. Kasiri-Asgarani and M. Medraj : Mater. Corros. 65 (2014) 1178. https://doi.org/10.1002/maco.201307588
  14. F. Rosalbino, S. De Negri, A. Saccone, E. Angelini and S. Delfino : J. Mater. Sci Mater. Med. 21 (2010) 1091. https://doi.org/10.1007/s10856-009-3956-1
  15. Z. Xu, C. Smith, S. Chen and J. Sankar : Mater. Sci. Eng. B 176 (2011) 1660. https://doi.org/10.1016/j.mseb.2011.06.008
  16. L. Geng, B. P. Zhang, A. B. Li and C. C. Dong : Mater. Lett. 63 (2009) 557. https://doi.org/10.1016/j.matlet.2008.11.044
  17. Y. Song, E. H. Han, D. Shan, C. D. Yim and B. S. You : Corros. Sci. 60 (2012) 238. https://doi.org/10.1016/j.corsci.2012.03.030
  18. M. Mandal, A. P. Moon, G. Deo, C. L. Mendis and K. Mondal : Corros. Sci. 78 (2014) 172. https://doi.org/10.1016/j.corsci.2013.09.012
  19. M. C. Zhao, P. Schmutz, S. Brunner, M. Liu, G. L. Song and A. Atrens : Corros. Sci. 51 (2009) 1277. https://doi.org/10.1016/j.corsci.2009.03.014
  20. Z. Shi, M. Liu and A. Atrens : Corros. Sci. 52 (2010) 579. https://doi.org/10.1016/j.corsci.2009.10.016
  21. Z. Shi and A. Atrens : Corros. Sci. 53 (2011) 226. https://doi.org/10.1016/j.corsci.2010.09.016
  22. X. Gao and J. F. Nie : Scripta Mater. 57 (2007) 655. https://doi.org/10.1016/j.scriptamat.2007.06.005
  23. K. Kubok, L. Lityzska-Dobrzynska, Wojewoda-Budka, A. Goral and A. Debski : Arch. Met. Mater. 58 (2013) 329.
  24. S. Izumi, M. Yamasaki and Y. Kawamura : Corros. Sci. 51 (2009) 395. https://doi.org/10.1016/j.corsci.2008.11.003
  25. Y, Song, E. H. Han, D. Shan, C. D. Yim and B. S. You : Corros. Sci. 65 (2012) 322. https://doi.org/10.1016/j.corsci.2012.08.037
  26. R. Ambat, N. N. Aung and W. Zhou : J. Appl. Electrochem. 30 (2000) 865. https://doi.org/10.1023/A:1004011916609
  27. M. S. Kim : J. Corros. Sci. Soc. Korea 1 (1980) 24.
  28. N. B. Pilling and R. E. Bedworth : J. Inst. Met. 29 (2912) 529.
  29. R. W. Revie : Uhlig's Corrosion Handbook, The Electrochemical Society, Inc., p. 259.