DOI QR코드

DOI QR Code

시멘트계 혼화재로서 POFA의 수화반응 특성에 관한 실험적 연구

An Experimental Study on Hydration Properties of POFA as a Cementitious Mineral Admixture

  • 투고 : 2016.01.07
  • 심사 : 2016.07.11
  • 발행 : 2016.07.30

초록

Palm Oil Fuel Ash (POFA), a pozzolanic material based on biomass, have been studied in many countries. However, researches about microstructure of POFA are insufficient. Therefore, in this study, hydration properties of POFA were assessed by using many test and Flyash was set as control group. Type 1 portland cement was replaced by POFA and Flyash at 0%, 10%, 20% by weight of binder. A water to binder ratio(W/B) of 0.5 was used for all cement mortar with POFA and Flyash according to KS L ISO 679 and Compressive Strength, Mercury Intrusion Porosimetry(MIP), TG/DTA, X-ray Diffraction(XRD) and Scanning Electron Microscope(SEM) were conducted. The results showed that mortars with POFA had bigger engineering performance than ones with Flyash and the mortar with POFA at 10% by weight of binder had the highest compressive strength due to formation of $CaOH)_2$ and C-S-H in the early ages and dense structures. Formation of $Ca(OH)_2$ and C-S-H was confirmed by using TG/DTA, XRD and SEM. Dense structures were confirmed by MIP. Through all the results, it was concluded that the best replacement ratio of POFA was 10% by weight of binder.

키워드

과제정보

연구 과제 주관 기관 : 한국연구재단

참고문헌

  1. Akashi O., Hanaoka T., Matsuoka, Y., & Kainuma, M. (2011). A projection for global CO2 emissions from the industrial sector through 2030 based on activity level and technology changes. Energy, 36(4), 1855-1867. https://doi.org/10.1016/j.energy.2010.08.016
  2. Aprianti, E., Shafigh, P., Bahri, S., & Farahani, J. (2015). Supplementary cementitious materials origin from agricultural wastes-A review. Construction and Building Materials, 74(15), 176-187. https://doi.org/10.1016/j.conbuildmat.2014.10.010
  3. Awal, A., & Hussin, W. (2011). Effect of Palm Oil Fuel Ash in Controlling Heat of Hydration of Concrete. Procedia Engineering, 14, 2650-2657. https://doi.org/10.1016/j.proeng.2011.07.333
  4. Chindaprasirt, P., Jaturapitakkul, C., & Sinsiri, T. (2007). Effect of fly ash fineness on microstructure of blended cement paste. Construction and Building Materials, 21(7), 1534-1541. https://doi.org/10.1016/j.conbuildmat.2005.12.024
  5. Jaturapitakkul, C., Tangpagasit, J., Songmue, S., & Kiattikomol, K. (2011). Filler effect and pozzolanic reaction of ground palm, oil fuel ash. Construction and Building Materials, 25(11), 4287-4293. https://doi.org/10.1016/j.conbuildmat.2011.04.073
  6. Jaturapitakkul, C., Kiattikomol, K., Tangchirapat, W., & Saeting, T. (2007). Evaluation of the sulfate resistance of concrete containing palm oil fuel ash. Construction and Building Materials, 21(7), 1399-1405. https://doi.org/10.1016/j.conbuildmat.2006.07.005
  7. Lee, C., Song, H., Ann, K., & Ismail, M. (2009). Material characteristic of POFA Concrete and Its Application to Corrosion Resistance Evaluation. Journal of the Korea Concrete Institute, 21(5), 565-572. https://doi.org/10.4334/JKCI.2009.21.5.565
  8. Lee, S. (2003). Pozzolan Reaction. Cement, 158, 40-44.
  9. Metz, B., Davidson, O., Bosch, P., Dave, R., & Mayer, L. (2007). Climate change 2007. Contribution of working Group 111 to the fourth assessment report of the intergovernmental panel on climate change. Cambridge, United Kingdom and New York, NY, USA, University Press.
  10. Madurwar, M., Ralegaonkar, R. & Mandavgane, S. (2013). Application of agro-waste for sustainable construction materials: A review. Construction and Building Materials, 38, 872-878. https://doi.org/10.1016/j.conbuildmat.2012.09.011
  11. Mehta. P. K. (1973). Concrete, Structure, properties and materials. Prentice Hall, Vol. 1, p25.
  12. Mendoza, O., Giraldo, C., Camargo, S., & Tobon, J. (2015) Structural and nano-mechanical properties of Calcium Silicate Hydrate (C-S-H) formed from alite hydration in the presence of sodium and potassium hydroxide. Cement and Concrete Research, 74, 88-94. https://doi.org/10.1016/j.cemconres.2015.04.006
  13. Noorvand, H., Ali, A., Demirboga, R., Noorvand, H., & Farzadnia, N. (2013). Physical and chemical characteristics of unground palm oil fuel ash cement mortars with nanosilica. Construction and Building Materials, 48, 1104-1113. https://doi.org/10.1016/j.conbuildmat.2013.07.070
  14. Ranjbar, N., Behnia, A., Alsubari, B., Birgani, P., & Jumaat, M. (2015). Durability and mechanical properties of self-compacting concrete incorporating palm oil fuel ash. Journal of Cleaner Production, 112(1), 1-8. https://doi.org/10.1016/j.jclepro.2015.06.081
  15. Rajak, M., Majid, Z., & Ismail, M. (2015). Morphological characteristics of hardened cement pastes incorporating nano-palm oil fuel ash. Procedia Manufacturing, 2, 512-518. https://doi.org/10.1016/j.promfg.2015.07.088
  16. Sata, V., Jaturapitakkul, C., & Kiattikomol, K. (2007). Influence of pozzolan from various by-product materials on mechanical properties of high-strength concrete. Construction and Building Materials, 21(7), 1589-1598. https://doi.org/10.1016/j.conbuildmat.2005.09.011
  17. Sinsiri, T., Kroehong, W., Jaturapitakkul, C., & Chindaprasirt, P. (2012). Assessing the effect of biomass ashes with different finenesses on the compressive strength of blended cement paste. Materials and Design, 42, 424-433. https://doi.org/10.1016/j.matdes.2012.06.030
  18. Tangchirapat, W., Saeting, T., Jaturapitakkul, C., Kiattikomol, K., & Siripanichgorn, A. (2007). Use of waste ash from palm oil industry in concrete. Waste Management, 27, 81-88. https://doi.org/10.1016/j.wasman.2005.12.014
  19. Tangchirapat, W., & Jaturapitakkul, C. (2010). Strength, drying shrinkage, and water permeability of concrete incorporating ground palm oil fuel ash. Cement & Concrete Composites, 32, 767-774. https://doi.org/10.1016/j.cemconcomp.2010.08.008
  20. Tangchirapat, W., Jaturapitakkul, C., & Chindaprasirt, P. (2009). Use of palm oil fuel ash as a supplementary cementitious material for producing high strength concrete. Construction and Building Materials, 23(7), 2641-2646. https://doi.org/10.1016/j.conbuildmat.2009.01.008
  21. Tay, J., & Show, K. (1995) Use of ash derived from oil-palm waste incineration as a cement replacement material. Resources, Conservation and Recycling Journal, 13(1), 27-36. https://doi.org/10.1016/0921-3449(94)00012-T

피인용 문헌

  1. Microstructural and Strength Characteristics of High-Strength Mortar Using Nontraditional Supplementary Cementitious Materials vol.31, pp.4, 2019, https://doi.org/10.1061/(ASCE)MT.1943-5533.0002626