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식물추출액을 이용한 흑연으로부터 그래핀 생산 특성

Characteristics of Graphene Production from Graphite using Plant Extracts

  • 정용재 (충북대학교 공과대학 화학공학과) ;
  • 류호준 (충북대학교 공과대학 화학공학과) ;
  • 최초롱 (충북대학교 공과대학 화학공학과) ;
  • 안상현 (충북대학교 공과대학 화학공학과) ;
  • 김우중 (충북대학교 공과대학 화학공학과) ;
  • 김동호 (충북대학교 공과대학 화학공학과) ;
  • 최병서 (충북대학교 공과대학 화학공학과) ;
  • ;
  • 김범수 (충북대학교 공과대학 화학공학과)
  • Jeong, Yongjae (Department of Chemical Engineering, College of Engineering, Chungbuk National University) ;
  • Ryu, Hojun (Department of Chemical Engineering, College of Engineering, Chungbuk National University) ;
  • Choi, Chorong (Department of Chemical Engineering, College of Engineering, Chungbuk National University) ;
  • An, Sanghyeon (Department of Chemical Engineering, College of Engineering, Chungbuk National University) ;
  • Kim, Woojung (Department of Chemical Engineering, College of Engineering, Chungbuk National University) ;
  • Kim, Dongho (Department of Chemical Engineering, College of Engineering, Chungbuk National University) ;
  • Choi, Byeongseo (Department of Chemical Engineering, College of Engineering, Chungbuk National University) ;
  • Salunke, Bipinchandra K. (Department of Chemical Engineering, College of Engineering, Chungbuk National University) ;
  • Kim, Beom Soo (Department of Chemical Engineering, College of Engineering, Chungbuk National University)
  • 투고 : 2016.08.29
  • 심사 : 2016.11.09
  • 발행 : 2016.12.31

초록

Recently, numerous studies have utilized graphene in biomedical applications such as drug delivery, cancer therapy, and bioimaging. In this study, graphene was eco-friendly prepared by liquid phase exfoliation of graphite using plant extracts in water. Initially, 12 different plants or plant parts were screened for the characteristic graphene peak at near 268 nm using UV-Vis spectrophotometric analyses. The ability to form stable black graphene dispersion was highest using Xanthium strumarium extract. Transmission electron microscopy images showed that about 5 layer-graphene was produced from 1 g/L of graphite, while more than 5 layers were formed from 2 g/L of graphite. The optimum X. strumarium concentration for graphene production was 2 g/100 mL.

키워드

참고문헌

  1. Chang, H. and H. Wu (2013) Graphene-based nanomaterials: Synthesis, properties, and optical and optoelectronic applications. Adv. Funct. Mater. 23: 1984-1997. https://doi.org/10.1002/adfm.201202460
  2. Jariwala, D., V. K. Sangwan, L. J. Lauhon, T. J. Marks, and M. C. Hersam (2013) Carbon nanomaterials for electronics, optoelectronics, photovoltaics, and sensing. Chem. Soc. Rev. 42: 2824-2860. https://doi.org/10.1039/C2CS35335K
  3. An, J. E. and Y. G. Jeong (2013) Structure and electric heating performance of graphene/epoxy composite films. Eur. Polym. J. 49: 1322-1330. https://doi.org/10.1016/j.eurpolymj.2013.02.005
  4. Shen, H., L. Zhang, M. Liu, and Z. Zhang (2012) Biomedical applications of graphene. Theranostics 2: 283-294. https://doi.org/10.7150/thno.3642
  5. Novoselov, K. S., et al. (2006) Unconventional quantum Hall effect and Berry's phase of 2π in bilayer graphene. Nature Phys. 2: 177-180. https://doi.org/10.1038/nphys245
  6. Yan, Z., et al. (2011) Growth of bilayer graphene on insulating substrates. ACS Nano 5: 8187-8192. https://doi.org/10.1021/nn202829y
  7. Tetlow, H., J. Posthuma de Boer, I. J. Ford, D. D. Vvedensky, J. Coraux, and L. Kantorovich (2014) Growth of epitaxial graphene: Theory and experiment. Phys. Rep. 542: 195-296. https://doi.org/10.1016/j.physrep.2014.03.003
  8. Hernandez, Y., et al. (2008) High-yield production of graphene by liquid-phase exfoliation of graphite. Nature Nanotechnol. 3: 563-568. https://doi.org/10.1038/nnano.2008.215
  9. Lotya, M., P. J. King, U. Khan, S. De, and J. N. Coleman (2010) High-concentration, surfactant-stabilized graphene dispersions. ACS Nano 4: 3155-3162. https://doi.org/10.1021/nn1005304
  10. Chabot, V., B. Kim, B. Sloper, C. Tzoganakis, and A. Yu (2013) High yield production and purification of few layer graphene by gum arabic assisted physical sonication. Sci. Rep. 3: 1378. https://doi.org/10.1038/srep01378
  11. Gravagnuolo, A. M., et al. (2015) In situ production of biofunctionalized few-layer defect-free microsheets of graphene. Adv. Funct. Mater. 25: 2771-2779. https://doi.org/10.1002/adfm.201500016
  12. Zhou, X. and Z. Liu (2010) A scalable, solution-phase processing route to graphene oxide and graphene ultralarge sheets. Chem. Commun. 46: 2611-2613. https://doi.org/10.1039/b914412a
  13. Park, S. and R. S. Ruoff (2009) Chemical methods for the production of graphenes. Nature Nanotechnol. 4: 217-224. https://doi.org/10.1038/nnano.2009.58
  14. Tung, V. C., M. J. Allen, Y. Yang, and R. B. Kaner (2009) Highthroughput solution processing of large-scale graphene. Nature Nanotechnol. 4: 25-29. https://doi.org/10.1038/nnano.2008.329
  15. Song, J. Y. and B. S. Kim (2009) Rapid biological synthesis of silver nanoparticles using plant leaf extracts. Bioprocess Biosyst. Eng. 32: 79-84. https://doi.org/10.1007/s00449-008-0224-6
  16. Song, J. Y., H.-K., Jang, and B. S. Kim (2009) Biological synthesis of gold nanoparticles using Magnolia kobus and Diopyros kaki leaf extracts. Process Biochem. 44: 1133-1138. https://doi.org/10.1016/j.procbio.2009.06.005
  17. Song, J. Y., E.-Y., Kwon, and B. S. Kim (2010) Biological synthesis of platinum nanoparticles using Diopyros kaki leaf extract. Bioprocess Biosyst. Eng. 33: 159-164. https://doi.org/10.1007/s00449-009-0373-2
  18. Lee, H.-J., J. Y., Song, and B. S. Kim (2013) Biological synthesis of copper nanoparticles using Magnolia kobus leaf extract and their antibacterial activity. J. Chem. Technol. Biotechnol. 88: 1971-1977.
  19. Lee, G. and B. S. Kim (2014) Biological reduction of graphene oxide using plant leaf extracts. Biotechnol. Prog. 30: 463-469. https://doi.org/10.1002/btpr.1862
  20. Salunke, B. K. and B. S. Kim (2016) Facile synthesis of graphene using biological method. RSC Adv. 6: 17158-17162. https://doi.org/10.1039/C5RA25977K
  21. Paton, K. R., et al. (2014) Scalable production of large quantities of defect-free few-layer graphene by shear exfoliation in liquids. Nature Mater. 13: 624-630. https://doi.org/10.1038/nmat3944
  22. Kamboj, A. and A. K. Saluja (2010) Phytopharmacological review of Xanthium strumarium L.(Cocklebur). Int. J. Green Pharm. 4: 129. https://doi.org/10.4103/0973-8258.69154