DOI QR코드

DOI QR Code

Analysis of newly designed CDI cells by CFD and its performance comparison

  • Kwon, Se Hwan (Department of Advanced Materials and Chemical Engineering, Hannam University) ;
  • Rhim, Ji Won (Department of Advanced Materials and Chemical Engineering, Hannam University)
  • Received : 2015.10.28
  • Accepted : 2016.01.13
  • Published : 2016.03.25

Abstract

In this study, computational fluid dynamics (CFD) analysis was conducted to investigate the flow pattern and to find the occurrence of dead zones in an existing capacitive deionization (CDI) cell. Newly designed cells-specifically designed to avoid dead zones-were analyzed by CFD in accordance with the flow rates of 15, 25 and 35 ml/min. Next, the separation performances between the existing and newly designed cell were compared by conducting CDI experiments in terms of salt removal efficiency at the same flow rates. Then, the computational and experimental results were compared to each other. The salt removal efficiencies of the hexagon flow channel 1 (HFC1) and hexagon flow channel 2 (HFC2) were increased 88-124% at 15 ml/min and 49-50% at 25 ml/min, respectively. There was no difference between the existing cell and the foursquare flow cell (FFC) at 35 ml/min.

Keywords

Acknowledgement

Supported by : National Research Foundation of Korea (NRF)

References

  1. Biesheuvel, P.M. and van der Wal, A. (2010), "Membrane capacitive deionization", J. Membr. Sci., 346(2), 256-262. https://doi.org/10.1016/j.memsci.2009.09.043
  2. Caudle, D.D., Tucker, J.H., Cooper, J.L., Arnold, B.B. and Papastamataki, A. (1966), "Electrochemical demineralization of water with carbon electrodes", Research Report; Oklahoma University Research Institute.
  3. Faisal, A.A., Amal, A.A.G., Irfan, S. and Nidal, H. (2014), "Application of capacitive deionization in water desalination : A review", Desalination, 342, 3-15. https://doi.org/10.1016/j.desal.2014.02.031
  4. Fontalvo, J., Fourcade, E., Cuellar, P.C., Wijers, J.G. and Keurentjes, J.T.F. (2006), "Study of the hydrodynamics in a pervaporation module and implications for the design of multi-tubular systems", J. Membr. Sci., 281(1-2), 219-227. https://doi.org/10.1016/j.memsci.2006.03.042
  5. Ghidossi, R., Veyret, D. and Moulin, P. (2006), "Computational fluid dynamics applied to membranes: state of the art and opportunities", Chem. Eng. Process, 45(6), 437-454. https://doi.org/10.1016/j.cep.2005.11.002
  6. Khoiruddin, K., Hakim, A.N. and Wenten, I.G. (2014), "Advances in electrodeionization technology for ionic separation-A review", Memb. Water Treat., Int. J., 5(2), 87-108. https://doi.org/10.12989/mwt.2014.5.2.087
  7. Lee, J., Park, K., Eum, H. and Lee, C. (2006), "Desalination of a thermal power plant wastewater by membrane capacitive deionization", Desalination, 196(1-3), 125-134. https://doi.org/10.1016/j.desal.2006.01.011
  8. Lee, J.H., Bae, W.S. and Choi, J.H. (2010), "Electrode reactions and adsorption/desorption performance related to the applied potential in potential in a capacitive deionization process", Desalination, 258(1-3), 159-163. https://doi.org/10.1016/j.desal.2010.03.020
  9. Lee, J.Y., Seo, S.J., Yun, S.H. and Moon, S.H. (2011), "Preparation of ion exchanger layered electrodes for advanced membrane capacitive deionization (MCDI)", Water Res., 45(17), 5375-5380. https://doi.org/10.1016/j.watres.2011.06.028
  10. Li, Y.L. and Tung, K.L. (2008a), "CFD simulation of fluid flow through spacer-filled membrane module: selecting suitable cell types for periodic boundary conditions", Desalination, 233(1-3), 351-358. https://doi.org/10.1016/j.desal.2007.09.061
  11. Li, Y.L. and Tung, K.L. (2008b), "The effect of curvature of a spacer-filled channel on fluid flow in spiralwound membrane modules", J. Membr. Sci., 319(1-2), 286-297. https://doi.org/10.1016/j.memsci.2008.03.069
  12. Li, H. and Zou, L. (2011), "Ion-exchange membrane capacitive deionization: A new strategy for brackish water desalination", Desalination, 275(1-3), 62-66. https://doi.org/10.1016/j.desal.2011.02.027
  13. Lin, Z., Jin, X.H., Zhi, J.Z., Huan, L.C. and Zu, R.P. (2006), "Effect of pervaporation module structure on separation performance", Desalination, 193(1-3), 166-170. https://doi.org/10.1016/j.desal.2005.07.050
  14. Park, N.S. (2008), "Fabrication of porous carbon electrode and its application to capacitive deionization (CDI) process", Master Dissertations; University of Gongju, Gongju, Korea. [In Korean]
  15. Pei, X., Jorg, E.D., Dean, H. and Gary, W. (2008), "Treatment of brackish produced water using carbon aerogel-based capacitive deionization technology", Water Res., 42(10-11), 2605-2617. https://doi.org/10.1016/j.watres.2008.01.011
  16. Rahimi, M., Madaeni, S.S. and Abbasi, K. (2005), "CFD modeling of permeate flux in cross-flow microfiltration membrane", J. Membr. Sci., 255(1-2), 23-31. https://doi.org/10.1016/j.memsci.2005.01.024
  17. Schwinge, J., Neal, P.R., Wiley, D.E., Fletcher, D.F. and Fane, A.G. (2004), "Spiral wound modules and spacers: Review and analysis", J. Membr. Sci., 242(1-2), 129-153. https://doi.org/10.1016/j.memsci.2003.09.031
  18. Shirazi, M.M.A., Karkari, A., Ismail, A.F. and Matsuura, T. (2016), "Computational Fluid Dynamic (CFD) opportunities applied to the membrane distillation process: State-of-the-art and perspectives", Desalination, 377, 73-90. https://doi.org/10.1016/j.desal.2015.09.010
  19. Takaba, H. and Nakao, S. (2005), "Computational fluid dynamics study on concentration polarization in $H_2$/CO separation membranes", J. Membr. Sci., 249(1-2), 83-88. https://doi.org/10.1016/j.memsci.2004.09.038
  20. Turek, M., Mitko, K., Bandura-Zaiska, B., Ciecierska, K. and Dydo, P. (2013), "Ultra-pure water production by integrated electrodialysis-ion exchange/electrodeionization", Memb. Water Treat., Int. J., 4(4), 237-249. https://doi.org/10.12989/mwt.2013.4.4.237

Cited by

  1. Effect of external force on buckling of cytoskeleton intermediate filaments within viscoelastic media vol.25, pp.3, 2020, https://doi.org/10.12989/cac.2020.25.3.205
  2. Scale-up and Modelling of Flow-electrode CDI Using Tubular Electrodes vol.203, pp.None, 2021, https://doi.org/10.1016/j.watres.2021.117498