Journal of Integrative Natural Science (통합자연과학논문집)

The Basic Science Institute Chosun University (조선대학교 기초과학연구원)
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Crystal Structure Analysis of 4-Chloro-2{[(2-hydroxy-5-methylphenyl)amino]methyl}5-methylphenol

  • Sharmila, P. (Department of Physics, Presidency College) ;
  • Rajesh, R. (Department of Chemistry, Pondicherry University) ;
  • Venkatesan, R. (Department of Chemistry, Pondicherry University) ;
  • Ganapathy, Jagadeesan (Department of Physics, Presidency College) ;
  • Aravindhan, S. (Department of Physics, Presidency College)
  • Received : 2016.11.06
  • Accepted : 2016.12.25
  • Published : 2016.12.31
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Abstract

The crystal structure of the saliciline derivatives 4-chloro-2{[(2-hydroxy-5-methylphenyl)amino]methyl}5-methylphenol ($C_{15}H_{15}ClNO_2$) has been determined from single crystal X-ray diffraction data. In the title compound crystallizes in the monoclinic space group P21/c with unit cell dimension $a=11.5241(2){\AA}$, $b=8.733(2){\AA}$ and $c=13.649(2){\AA}$ [${\alpha}=90^{\circ}$, ${\beta}=130.876(2)^{\circ}$ and ${\gamma}=90^{\circ}$]. the title compound are essentially planar conformation. The compound lies across a crystallographic inversion centre and adopts E configurations with respect to the C-N bonds. The crystal packing of the molecules of compound is stabilized through weak O-H...O inter molecular interactions.

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References

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