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Characteristics of the Mg and In co-doped ZnO Thin Films with Various Substrate Temperatures

RF 마그네트론 스퍼터를 이용하여 제작한 MIZO 박막의 특성에 미치는 기판 온도의 영향

  • Jeon, Kiseok (Solar Cell R&D Center, Applied Optics & Energy R&D Group, Korea Institute of Industrial Technology) ;
  • Jee, Hongsub (Solar Cell R&D Center, Applied Optics & Energy R&D Group, Korea Institute of Industrial Technology) ;
  • Lim, Sangwoo (Department of Chemical and Biomolecular Engineering, Yonsei University) ;
  • Jeong, Chaehwan (Solar Cell R&D Center, Applied Optics & Energy R&D Group, Korea Institute of Industrial Technology)
  • 전기석 (한국생산기술연구원 광에너지융합그룹) ;
  • 지홍섭 (한국생산기술연구원 광에너지융합그룹) ;
  • 임상우 (연세대학교 화공생명공학과) ;
  • 정채환 (한국생산기술연구원 광에너지융합그룹)
  • Received : 2016.11.21
  • Accepted : 2016.11.23
  • Published : 2016.12.31

Abstract

Mg and In co-doped ZnO (MIZO) thin films with transparent conducting characteristics were successfully prepared on glass substrates by RF magnetron sputtering technique. The Influence of different substrate temperature (from RT to $400^{\circ}C$) on the structural, morphological, electrical, and optical properties of MIZO thin films were investigated. The MIZO thin film prepared at the substrate temperature of $350^{\circ}C$ showed the best electrical characteristics in terms of the carrier concentration ($4.24{\times}10^{20}cm^{-3}$), charge carrier mobility ($5.01cm^2V^{-1}S^{-1}$), and a minimum resistivity ($1.24{\times}10^{-4}{\Omega}{\cdot}cm$). The average transmission of MIZO thin films in the visible range was over 80% and the absorption edges of MIZO thin films were very sharp. The bandgap energy of MIZO thin films becomes wider from 3.44 eV to 3.6 eV as the substrate temperature increased from RT to $350^{\circ}C$. However, Band gap energy of MIZO thin film was narrow at substrate temperature of $400^{\circ}C$.

Keywords

References

  1. D.S. Ginley, C. Bright, "Transparent Conducting Oxides", MRS Bulletin, Vol.25, pp.15-18, 2000.
  2. I. Hamberg, C. G. Granqvist, "Evaporated Sn-doped $In_2O_3$ films: Basic optical properties and applications to energy- efficient windows", Appl. Phys. Vol.60, pp.R123-R159, 1986. https://doi.org/10.1063/1.337534
  3. Z.C. Jin, I. Hamberg, C. G. Granqvist, "Optical properties of sputter-deposited ZnO:Al thin films", J. Appl. Phys. Vol.64. pp.5117-5131, 1988. https://doi.org/10.1063/1.342419
  4. J. Steinhauser, S. Fay, N. Oliveira, E. Vallat-Sauvain, C. Ballif, "Transition between grain boundary and intragrain scattering transport mechanisms in boron-doped zinc oxide thin films" Appl. Phys. Lett., Vol.90, pp.142107-1421077-3, 2007. https://doi.org/10.1063/1.2719158
  5. K. L. Chopra, S. Major and D. K. Pandya, "Transparent conductors - A status review", Thin Solid Films, Vol.102, pp.1 -46, 1983. https://doi.org/10.1016/0040-6090(83)90256-0
  6. K.T. Ramakrishna Reddy, P. Prathap, N. Revathi, A.S.N. Reddy, R. W. Miles, "Mg-composition induced effects on the physical behavior of sprayed $Zn_{1-x}$MgxO films", Thin solid Films, Vol.518, pp.1275-1278, 2009. https://doi.org/10.1016/j.tsf.2009.04.071
  7. X. Zhang, H. Ma, Q. Wang, J. Ma, F. Zong, H. Xiao, F.Ji and S. Hou, "Structural and optical properties of $Mg_{x}Zn_{1-x}O$ thin films deposited by magnetron sputtering", Physica. B, Condensed matter., Vol.364, pp.157-161, 2005. https://doi.org/10.1016/j.physb.2005.04.005
  8. F. Maldonado, A. Steshans, "Al-doped ZnO : Electronic, electridcal and structural properties", J. Phy. Chem. Solids, Vol.71,pp.784-787, 2010. https://doi.org/10.1016/j.jpcs.2010.02.001
  9. J. Wienke, A.S. Booij, "ZnO:In deposition by spray pyrolysis - Influence of the growth conditions on the electrical and optical properties Original", Thin solid Films, Vol.516, pp.4508-4512, 2008. https://doi.org/10.1016/j.tsf.2007.05.078
  10. D. H. Kim, N. G. Cho, H. G. Kim, W. Y. Cho,,"Structural and Electrical Properties of Indium Doped ZnO Thin Films Fabricated by RF Magnetron Sputtering", J. Electrochem. Soc., Vol.154, pp.H939-H943, 2007. https://doi.org/10.1149/1.2775171
  11. E. J. Luna-Arredondo, A. Maldonado, R. Asomoza, D.R. Acosta, M.A. Melendez-Lira, M. de la L. Olvera, "Indium-doped ZnO thin films deposited by the sol-gel technique", Thin solid Films, Vol.490, pp.132-136, 2005. https://doi.org/10.1016/j.tsf.2005.04.043
  12. G. Machado, D. N. Guerra, D. Leinen, J. R. Ramos-Barrado, R.E. Marotti, E.A. Dalchiele, "Indium doped zinc oxide thin films obtained by electrodeposition", Thin solid Films, Vol. 490, pp.124-131, 2005. https://doi.org/10.1016/j.tsf.2005.04.042
  13. P. Y. Kim, J. Y. Lee, H. Y. Lee,"Structure and Properties of IZO Transparent Conducting Thin Films Deposited by PLD Method", J. KOREAN PHYS. SOC., Vol.53, pp.207-211, 2008. https://doi.org/10.3938/jkps.53.207
  14. I. Y. Kim, K. V. Gurav, S. W. Shin, K. S. Jeon, P. S. Patil, J. H. Moon, D. S. Lee, J. H. Kim, "Characteristics Of Quaternary Flexible Mg and Ga Co-Doped ZnO Thin Films Fabricated Using Rf Magnetron Sputtering", Sci. Adv. Mater. Vol.8, pp.610-617, 2016. https://doi.org/10.1166/sam.2016.2515
  15. K. S. Jeon, M. P. Surawanshi, I. Y. Kim, J. S. Jang, J. H. Yun, J. H. Moon, J. H. Kim, "Transparent Conductive and Wide Band Gap Characteristics of Quaternary Mg and Al Co-doped ZnO Thin Films Preapred by Radio Frequency Sputtering Method", Sci. Adv. Mater. Vol.8, pp.669-674, 2016. https://doi.org/10.1166/sam.2016.2527
  16. Y. K. Hyun, J. W. Choi, D. H. Lee, "Characteristics f ZnO films deposited onto Al/Si substrates by r.f. magnetron sputtering", Thin Solid Films, Vol.302, pp.116-121, 1997. https://doi.org/10.1016/S0040-6090(96)09568-5
  17. R. D. Shannon, "Revised effective ionic radii and systematic studies of interatomic distances in halides and chalcogenides", Acta. Crystallogr A., Vol.32, pp.751-767, 1976. https://doi.org/10.1107/S0567739476001551
  18. D.Y. Ku, I.H. Kim, I. Lee, K.S. Lee, T.S. Lee, J.-h. Jeong, B. Cheong, Y.-J. Baik, W.M. Kim, "Structural and electrical properties of sputtered indium-zinc oxide thin films", Thin Solid Films, Vol.515, pp.1364-1369, 2006. https://doi.org/10.1016/j.tsf.2006.03.040
  19. X. Si, Y. Liu, X. Wu, W. Lei, J. lin, T. Gao, L. Zheng, "Al-Mg co-doping effect on optical and magnetic properties of ZnO nanopowders", Phys. Lett. A, Vol.379, pp.1445-1448, 2015. https://doi.org/10.1016/j.physleta.2015.03.025
  20. Y. K. Moon, S. H. Kim, J. W. Park, "The influence of substrate temperature on the properties of aluminum-doped zinc oxide thin films deposited by DC magnetron sputtering", J Mater Sci: Mater Electron, Vol.17, pp.973-977, 2006. https://doi.org/10.1007/s10854-006-9039-x
  21. S. A. Vanalakar, S. S. Mail, M. P. Suranasshi, P. S. Patil, "QUANTUM SIZE EFFECT IN CHEMOSYNTHESIZED NANOSTRUCTURED CdS THIN FILMS.", Digest J. Nanomater. Biostruct., Vol.5, pp.805-810, 2010.
  22. K. H. Ri, Y. Wang, W. L. Zhou, J. X. Gao, X. J. Wang, "The structural properties of Al doped ZnO films depending on the thickness and their effect on the electrical properties", J. Yu, Appl. Surf. Sci., Vol.258, pp.1283-1289, 2011. https://doi.org/10.1016/j.apsusc.2011.07.022