Korean Chemical Engineering Research

  • 제54권1호
  • /
  • Pages.36-43
  • /
  • 2016
  • /
  • 0304-128X(pISSN)
  • /
  • 2233-9558(eISSN)
한국화학공학회 (The Korean Institute of Chemical Engineers)
권호 표지
DOI QR코드

DOI QR Code

Synthesis And Ionic Conductivity of Siloxane Based Polymer Electrolytes with Propyl Butyrate Pendant Groups

  • 투고 : 2014.11.24
  • 심사 : 2015.06.09
  • 발행 : 2016.02.01
PDF 다운로드
⟨ 이전 논문 다음 논문 ⟩

초록

Hydrosilylation reactions of 2.4.6.8-tetrahydro-2.4.6.8-tetramethylcyclotetrasiloxane with allyl butyrate catalyzed by Karstedt's, $H_2PtCl_6$ and Pt/C catalyst were studied and 2.4.6.8-tetra (propyl butyrate)-2.4.6.8-tetramethylcyclotetrasiloxane was obtained. The reaction order, activation energies and rate constants were determined. Ringopening polymerization of 2.4.6.8-tetra (propyl butyrate)-2.4.6.8-tetramethylcyclotetrasiloxane in the presence of $CaF_2$, LiF, KF and anhydrous potassium hydroxide in $60-70^{\circ}C$ temperature range was carried out and methylsiloxane oligomers with regular arrangement of propyl butyrate pendant groups were obtained. The synthesized products were studied by FTIR and NMR spectroscopy. The polysiloxanes were characterized by wide-angle X-ray, gel-permeation chromatography and DSC analyses. Via sol-gel processes of oligomers doped with lithium trifluoromethylsulfonate or lithium bis (trifluoromethylsulfonyl)imide, solid polymer electrolyte membranes were obtained. The dependences of ionic conductivity of obtained polyelectrolytes on temperature and salt concentration were investigated, and it was shown that electric conductivity of the polymer electrolyte membranes at room temperature changed in the range $3.5{\times}10^{-4}{\sim}6.4{\times}10^{-7}S/cm$.

키워드

참고문헌

  1. Cardiano, P., Sergi, S. and Lazzari, M., P. Piraino, Polymer, 43, 6635(2002). https://doi.org/10.1016/S0032-3861(02)00677-8
  2. Guizard, C., Bac, A., Barboiu, M. and Hovnanian, N., Sep Purif. Tech., 25, 167(2001). https://doi.org/10.1016/S1383-5866(01)00101-0
  3. Mukbaniani, O., Tatrishvili, T., Titvinidze, G. and Mukbaniani, N., J. Appl. Polym. Sci., 104, 2168(2007). https://doi.org/10.1002/app.24740
  4. Gray, F. M. and Armand, M., Polymer electrolytes, in Handbook of Battery Materials. Besenhard J. O., Ed., Wiley-VCH, Weinheim (1999).
  5. Karatas, Y., Kaskhedikar, N., Burjanadze, M. and Wiemhofer, H.-D., Macromol. Chem. Phys., 207, 419(2006). https://doi.org/10.1002/macp.200500470
  6. Morales, E. and Acosta, J. L., Electrochim. Acta, 45, 1007(1999). https://doi.org/10.1016/S0013-4686(99)00303-5
  7. Zhang, Z. C., Sherlock, D., West, R., Amine, K. and Lyons, L. J., Macromol., 36, 8907(2003). https://doi.org/10.1021/ma035175i
  8. Funke, K., Heimann, B., Vereing, M. and Wilmer, D. J., Electrochem. Soc., 148, A395(2001). https://doi.org/10.1149/1.1359193
  9. Allcock, H. R., Olmeijer, D. L. and O'Connor, S. J. M., Macromol., 31, 753(1998). https://doi.org/10.1021/ma971666p
  10. Gray, F. M. and Armand, M., Polymer electrolytes, in Handbook of Battery Materials. J.O. Besenhard, Ed., Wiley-VCH, Weinheim (1999).
  11. Hooper, R., Lyons, L. J., Moline, D. A. and West, R., Silicon Chemistry, 1, 121(2002). https://doi.org/10.1023/A:1020690025625
  12. Hooper, R., Lyons, L. J., Moline, D. A. and West, R., Organometallics, 18, 3249(1999). https://doi.org/10.1021/om990261l
  13. Iwahara, T., Kusakabe, M., Chiba, M. and Yonezawa, K., J. Polym. Sci. A, 31, 2617(1993). https://doi.org/10.1002/pola.1993.080311023
  14. Mukbaniani, O., Tatrishvili, T., Markarashhvili, E. and Esartia, I., Georgian Chem. J., 2, 153(2011).
  15. Tartakovskaia, L. M., Makarov, I. G., Kazakova, V. M., Kopilov, V. M. and Zhdanov, A. A., Izv. AN USSR, Ser. Chim., 12, 2818(1980).
  16. Andrianov, K. A., Tartakovskaia, L. M., Kopilov, V. M. and Sementsova, Zh. N., Zhur. Obshch. Khim., 45, 112(1975).
  17. Corey, E. J. and Snider, B. B., J. Amer. Chem. Soc., 94, 6190 (1972). https://doi.org/10.1021/ja00772a043
  18. Tartakovskaia, L. M., Kopilov, V. M. and Zhdanov, A. A., Vysokomol. Soed., 26, 234(1984).
  19. Zhang, Z. and Fang, Sh., Electrochim Acta, 45, 2131(2000). https://doi.org/10.1016/S0013-4686(99)00435-1