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Spherodization of Granuled Cr2O3 Fine Ceramic Powder by Plasma Spray

플라즈마 분사 처리에 의한 Cr2O3 조립분말의 구상화에 대한 연구

  • Lee, Dong Won (Materials Implementation Department, Korea Institute of Materials Science) ;
  • Lee, Hak Sung (Materials Modeling and Characterization Department, Korea Institute of Materials Science) ;
  • Yu, Ji-Hun (Powder Technology Department, Korea Institute of Materials Science) ;
  • Wang, Jei-Pil (Department of Metallurgical Engineering, Pukyong National University)
  • 이동원 (재료연구소 소재실용화연구실) ;
  • 이학성 (재료연구소 재료설계분석실) ;
  • 유지훈 (재료연구소 분말기술실) ;
  • 왕제필 (국립부경대학교 금속공학과)
  • Received : 2016.11.15
  • Accepted : 2016.12.12
  • Published : 2016.12.31

Abstract

Spray dried $Cr_2O_3$ powder having an agglomerated structure of particles was twice treated into a plasma flame to increase its apparent density. The powder subjected to the first densification treatment did not show the entirely melted state keeping inner particle hollows, and it was fully melted after the second processing only. The powder size as a result of the second treatment decreased, and the apparent density as well as flowability were increased due to melting and surface smoothing effects. But a part of particles after the second densified treatment showed the hollow structure, especially those which were above $30{\mu}m$ in size. This densification behavior of the powder has been qualitatively discussed in terms of the thermal conductivity and inner gas pressure within aggregates exposed to the plasma flame.

Spray dried $Cr_2O_3$ 분말은 겉보기밀도를 향상시키기 위해 plasma flame에 투입하여 실험을 진행 하였다. 첫번째 고밀도화 공정에서의 분말은 입자내부 공간까지 완전히 용해되어지지 않았으며, 두번째 공정 이후 완전히 용해가 되었다. 두번째 공정 결과 분말 입도는 작아졌으며, 용해 및 표면 연화에 의해 겉보기 밀도와 유동도는 향상이 되었다. 두번째 고밀도화 공정이 후 부분적으로 입자들이 $30{\mu}m$ 이상의 hollow structure을 보여주고 있다. 분말의 이러한 고밀도화는 plasma flame에 의해 응집되어진 응집체내의 열전도율 및 내부 가스압의 관점에서 정량적으로 논의 하였다.

Keywords

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