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Effects of roasting conditions on the physicochemical properties of Coffea arabica beans

배전조건이 아라비카 커피의 이화학적 성질에 미치는 영향

  • Suh, Yeon-Soo (Department of Food and Nutrition, Gangneung-Wonju National University) ;
  • Lee, Seung-Heon (Hak-san Co., Ltd.) ;
  • Shang, Yafang (Department of Chemical Engineering and Food Processing, Hefei University of Technology) ;
  • Lee, Won-Jong (Department of Food and Nutrition, Gangneung-Wonju National University)
  • Received : 2015.06.03
  • Accepted : 2015.08.20
  • Published : 2015.10.30

Abstract

Effects of roasting on physical (weight, volume, density and color) and chemical properties (total phenol, caffeine, chlorogenic acid and antioxidant properties) of three Arabica coffee beans (Brazil Bourbon, Indonesia Mandheling and Kenya Tatu) were investigated. A steady weight loss, volume increase, and bean density decrease were observed during the roasting process. The $L^*$, $a^*$, and $b^*$ values tended to decrease as the roasting temperature and time increased. Caffeine level was approximately 0.73% in green beans, and increased to 40-67% for darker roasts. Green beans contained the highest chlorogenic acid content, which decreased as the roasting temperature and time increased. The light- and medium-roasted coffee showed the highest total phenolol contents. The antioxidant activities were measured using DPPH and ABTS. The light-roasted coffee beans showed the highest antioxidant activities, and an approximately 36-51% loss in antioxidant activity was observed after further roasting. The flavor patterns of roasted coffee beans were analyzed using an electronic nose system based on gas chromatography. This analysis demonstrated that an electronic nose system can be applied to identify the green bean variety and the degree of roasting.

아라비카 커피 생두 3종(브라질 버번, 인도네시아 만델링, 케냐 타투)을 배전 온도 $181{\sim}215^{\circ}C$의 범위에서 8.15~11.83분의 조건에서 약배전, 중배전, 강배전으로 배전하여 물리적 특성, 이화학적 성질, 항산화력 등을 조사하였다. 배전 온도가 증가함에 따라 무게와 밀도가 감소하였고, $L^*$, $a^*$, $b^*$값이 감소하였다. 총 페놀함량은 생두보다는 배전후의 원두에서 더 높았으며, 약배전과 중배전에서 가장 높았다. 카페인 함량은 강배전한 시료에서 가장 높았다. 클로로겐산은 생두에서 가장 높았으며, 배전의 강도가 강해짐에 따라 감소하였다. ABTS와 DPPH 라디칼 소거능은 생두보다는 배전 후의 원두에서 더 높았으며, 배전의 강도가 강해짐에 따라 감소하였다. 따라서 항산화력을 유지하기 위해서는 지나치게 높은 온도에서 배전하는 것보다는 낮은 온도에서 약배전하는 것이 바람직한 것으로 사료된다. GC를 기초로 한 전자코를 활용하여 커피의 향기패턴을 분석한 결과 품종과 배전정도에 따른 향기패턴의 차이를 잘 구분할 수 있었다.

Keywords

References

  1. Smith AW (1985) Introduction. In: Coffee. Volume 1: Chemistry. Clarke RJ, Macrae R(Editors), Elsevier Applied Science, London, England, p 1-41
  2. Sivetz M, Fonte E (1963) Coffee Processing Technology. Avi Publishing Co, Westport, Connecticut, USA, p 320-349
  3. Baik HJ, Ko YS (1996) Studies on the aroma components of roasted and ground coffee. Korean J Food Sci Technol, 28, 15-18
  4. Czerny M, Grosch W (2000) Potent odorants of raw Arabica coffee : their changes during roasting. J Agric Food Chem, 48, 868-872 https://doi.org/10.1021/jf990609n
  5. Baggenstoss J, Poisson J, Kaegi R, Perren R, Escher F (2008) Coffee roasting and aroma formation : application of different time-temperature conditions. J Agric Food Chem, 56, 5836-5846 https://doi.org/10.1021/jf800327j
  6. Mayer F, Czerny M, Grosch W (1999) Influence of provenance and roast degree on the composition of potent odorants in Arabica coffees. Eur Food Res Technol, 209, 242-250 https://doi.org/10.1007/s002170050487
  7. Cho AR, Park KW, Kim KM, Kim SY, Han J (2014) Influence of roasting conditions on the antioxidant characteristics of Colombian coffee (Coffea arabica L.) beans. J Food Biochem, 38, 271-280 https://doi.org/10.1111/jfbc.12045
  8. Kim KJ, Park SK (2006) Changes in major chemical constituents of green coffee beans during the roasting. Korean J Food Sci Technol, 38, 153-158
  9. Karakaya S, El SN, Tas AA (2001) Antioxidant activity of some foods containing phenolic compounds. Int J Food Sci Nutr, 52, 501-508 https://doi.org/10.1080/09637480020027000-6-6
  10. Namba T, Matsuse T (2002) A historical study of coffee in Japanese and Asian countries : forcusing the medicinal uses in Asian traditional medicines. J Japan Hist Pharm, 37, 65-75
  11. Yukawa GS, Mune M, Otani H, Tone Y, Liang XM, Iwahashi H, Sakamoto W (2004) Effects of coffee consumption on oxidative susceptibility of low-density lipoproteins and serum lipid levels in humans. Biochem, 69, 70-74
  12. Naidu MM, Sulochanamma G, Sampathu SR, Srinivas P (2008) Studies on extraction and antioxidant potential of green coffee. Food Chem, 107, 377-384 https://doi.org/10.1016/j.foodchem.2007.08.056
  13. Suh YS, Lee SH, Shang Y, Yoon JR, Lee WJ (2014) Changes in antioxidant activities and flavor patterns of Coffea arabica beans during roasting. Korean J Food Preserv, 21, 224-230 https://doi.org/10.11002/kjfp.2014.21.2.224
  14. Loufti A, Coradeschi S, Mani GK, Shankar P (2014) Elecronic noses for food industry, a review. J Food Eng, 144, 103-111
  15. AOAC (1995) Official Method of Analysis. Association of Official Analytical Chemists, Washington DC, p 1137-1139
  16. Hecimovic H, Belscak-Cvitanovic A, Horzic D, Komess D (2011) Comparative study of polyphenols and caffeine in different coffee varieties affected by the degree of roasting. Food Chem, 129, 991-1000 https://doi.org/10.1016/j.foodchem.2011.05.059
  17. Blois MS (1958) Antioxidant determination by the use of a stable free radical. Nature, 181, 1199-2000 https://doi.org/10.1038/1811199a0
  18. Re R, Pellegrini N, Proteggente A, Pannala A, Yang M, Rice-Evans C (1999) Antioxidant activity applying an improved ABTS radical cation decolorization assay. Free Radic Biol Med, 26, 1231-1237 https://doi.org/10.1016/S0891-5849(98)00315-3
  19. Kim HK, Hwang SY, Yoon SB, Chun DS, Kong SK, Kang KO (2007) A study of the characteristics of different coffee beans by roasting and extracting condition. Korean J Food Nutr, 20, 14-19
  20. Tfouni ASV, Serrate CS, Carreiro LB, Camargo MCR, Teles CRA, Cipolli KMVAB, Furlani RPZ (2012) Effect of roasting on chlorogenic acids, caffeine and polycyclic aromatic hydrocarbons levels in two Coffea cultivas : Coffea arabica cv. Catuai Amarelo IAC-62 and Coffea canephora cv. Apoata IAC-2258. Int Food Sci Technol, 47, 406-415 https://doi.org/10.1111/j.1365-2621.2011.02854.x
  21. ICO (2005) OTA risk management : Guidelines for green coffee buying. Report of the quality committee, International Coffee Organization, ED-1939/05
  22. Alessandrini L, Romani S, Pinnavaia G, Rosa MD (2008) Near infrared spectroscopy : an analytical tool to predict coffee roasting degree. Anal Chim Acta, 625, 95-102 https://doi.org/10.1016/j.aca.2008.07.013
  23. Oosterveld A, Harmsen JS, Voragen HA (2003) Extraction and characterization of polysaccharides from green and roasted coffee beans. Carbohyd Polym, 52, 258-296
  24. Franca AS, Oliveira LS, Oliveira RCS, Agresiti PCM, Augusti R, Mendonca JCF, Silva XA (2009) A preliminary evaluation of the effect of processing temperature on coffee roasting degree assessment. J Food Eng, 92, 345-352 https://doi.org/10.1016/j.jfoodeng.2008.12.012
  25. Pittia P, Dalla Rosa M, Lerici CR (2001) Textural changes of coffee beans as affected by roasting conditions. LWT-Food Sci Technol, 34, 168-175 https://doi.org/10.1006/fstl.2000.0749
  26. Jokanovic MR, Dzinic NR, Cvetkovic BR, Grujic S, Odzakovic B (2012) Changes of physical properties of coffee beans during roasting. Acta Periodica Technologica, 43, 21-31
  27. Choi YM (2009) Sensory characteristics of coffee in relation to the processing and classification of green coffee. MS Thesis. Kyung Hee University, Seoul, Korea
  28. Illy A, Viani R (2004) Espresso Coffee : The Science of Quality. 2nd ed, Academic Press, San Diego, CA, USA, p 91-95
  29. Sivetz M, Desrosier NW (1979) Coffee Technology. AVI Publishing Co. Westport, Connecticut, USA, p 415-565
  30. Park SJ, Moon SW, Kim EJ, Kang BS (2011) Optimization of roasting conditions for coffee beans by response surface methodology. Korean J Food Preserv, 18, 178-183 https://doi.org/10.11002/kjfp.2011.18.2.178
  31. Borrelli RC, Visconti A, Mennella C, Anese M, Fogliano V (2002) Chemical characterization and antioxidant properties of coffee melanoidins. J Agric Food Chem, 50, 6527-6533 https://doi.org/10.1021/jf025686o
  32. Casal S, Oliveira MB, Ferreira MA (2000) HPLC/diodearray applied to the thermal degradation of trigonelline, nicotinic acid and caffeine in coffee. Food Chem, 68, 481-485 https://doi.org/10.1016/S0308-8146(99)00228-9
  33. Macrae R (1985) Nitrogenous compounds. In: Coffee, Volume 1: Chemistry. Clarke RJ, Macrae R(Editors), Elsevier Applied Science, London, England, p 115-152
  34. Farah A, Monteiro MC, Calado V, Franca AS, Trugo LC (2006) Correlation between cup quality and chemical attributes of Brazilian coffee. Food Chem, 98, 371-380
  35. Farah A, Donangelo CM (2006) Phenolic compound in coffee. Braz J Plant Physiol, 18, 23-26 https://doi.org/10.1590/S1677-04202006000100003
  36. Chism GW, Haard NF (1996) Characteristics of edible plant tissues. In: Food Chemistry. Fennema OR(Editor), Dekker, NY, USA, p 944-1007
  37. Tomaino A, Cimino F, Zimbalatti V, Venuti V, Sulfaro V, De Pasqual A, Saija A (2005) Influence of heating on antioxidant activity and the chemical composition of some spice essential oils. Food Chem, 89, 549-554 https://doi.org/10.1016/j.foodchem.2004.03.011
  38. Clifford MN, Wight J (1976) The measurement of feruloylquinic acids and caffeoylquinic acids in coffee beans. J Sci Food Agric, 27, 73-84 https://doi.org/10.1002/jsfa.2740270112
  39. Trugo LC, Macrae R (1984) Chrorogenic acid composition of instant coffee. Analyst, 109, 263-266 https://doi.org/10.1039/an9840900263
  40. Mazzafera P, Robinson SP (2000) Characterization of polyphenol oxidase in coffee. Phytochem, 55, 285-296 https://doi.org/10.1016/S0031-9422(00)00332-0
  41. Amorium HV, Cruz AR, St. Angelo AJ, Dias RM, Mello, M, Teixeira AA, Gutierrez LE, Ory RL (1977) Biochemical, physical and organoleptical changes during raw coffee quality deterioration. Paper presented at the 8th International Coffee Symposium, November 28-December 3, Abidjan, Cote d'Ivoire
  42. Kim JY, Han YS (2009) Influence of roasting time on antimicrobial and antioxidative effects of coffee extract. Korean J Food Cookery Sci, 25, 496-505
  43. Perrone D, Farah A, Donangelo CM, de Paulis T, Martin PR (2008) Comprehensive analysis of major and minor chlorogenic acids and lactones in economically relevant Brazilian coffee cultivars. Food Chem, 106, 859-86 https://doi.org/10.1016/j.foodchem.2007.06.053

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