한국섬유공학회지 (Textile Science and Engineering)

  • 제52권4호
  • /
  • Pages.258-263
  • /
  • 2015
  • /
  • 1225-1089(pISSN)
  • /
  • 2288-6419(eISSN)
한국섬유공학회 (The Korean Fiber Society)
권호 표지
DOI QR코드

DOI QR Code

PLA/PMMA/PBAT 블렌드의 상용성 및 조성에 의한 특성 연구

Study of Properties for Compatibility and Composition of PLA/PMMA/PBAT Blends

  • 한지연 (인하대학교 대학원 유기응용재료공학과) ;
  • 차주희 (인하대학교 대학원 유기응용재료공학과) ;
  • 안승재 (인하대학교 대학원 유기응용재료공학과) ;
  • 전한용 (인하대학교 유기응용재료공학과)
  • Han, Ji-Yeon (Department of Applied Organic Materials Engineering, Inha University Graduate School) ;
  • Cha, Ju-Hee (Department of Applied Organic Materials Engineering, Inha University Graduate School) ;
  • Ahn, Seung-Jae (Department of Applied Organic Materials Engineering, Inha University Graduate School) ;
  • Jeon, Han-Yong (Department of Applied Organic Materials Engineering, Inha University)
  • 투고 : 2015.07.08
  • 심사 : 2015.08.07
  • 발행 : 2015.08.31
⟨ 이전 논문 다음 논문 ⟩

초록

The viscoelastic behavior and tensile properties of PLA blends and PLA/PMMA/PBAT blends were measured, and an image analysis was performed, to examine the compatibility of PLA, PBAT, and PMMA. PLA/PMMA blends were found to exhibit a high level of compatibility for all compositions. The thermal stability, modulus, and tensile strength of these blends increased with PMMA content. Also, the glass transition temperature and tensile strength of PLA/PMMA blends varied between the values for neat PLA and PMMA, indicating a high degree of compatibility. On the other hand, ternary blends of PLA, PMMA, and PBAT exhibited a low modulus than PLA/PMMA blends; their compatibility improved with PMMA content because of PMMA acting as a compatibilizer for PLA/PBAT blends.

키워드

참고문헌

  1. A. M. Gajria, V. Dave, R. A. Gross, and S. P. McCarthy, "Miscibility and Biodegradablility of Blends of Poly(lactic acid) and Poly(vinyl acetate)", Polymer, 1996, 37, 437-444. https://doi.org/10.1016/0032-3861(96)82913-2
  2. J. B. Lee, Y. K. Lee, G. D. Choi, S. W. Na, T. S. Park, and W. N. Kim, "Compatibilizing Effects for Improving Mechanical Properties of Biodegradable Poly(lactic acid) and Polycarbonate Blends", Polym. Degrad. Stabil., 2011, 96, 553-560. https://doi.org/10.1016/j.polymdegradstab.2010.12.019
  3. Y. Wang, S. M. Chiao, T.-F. Hung, and S.-Y. Yang, "Improvement in Toughness and Heat Resistance of Poly(lactic acid)/Polycarbonate Blend Through Twin-screw Blending: Influence of Compatibilizer Type", J. Appl. Polym. Sci., 2012, 125, E402-E412. https://doi.org/10.1002/app.36920
  4. B. Imre, K. Renner, and B. Pukanszky, "Interactions, Structure and Properties in Poly(lactic acid)/thermoplastic Polymer Blends", Exp. Polym. Lett., 2014, 8, 2-14. https://doi.org/10.3144/expresspolymlett.2014.2
  5. H. Chen, M. Pyda, and P. Cebe, "Non-isothermal Crystallization of PET/PLA Blends", Thermochimica Acta, 2009, 492, 61-66. https://doi.org/10.1016/j.tca.2009.04.023
  6. N. Ploypetchara, P. Suppakul, D. Atong, and C. Pechyen, "Blends of Polypropylene/poly(lactic acid) for Medical Packaging Application: Physicochemical, Thermal, Mechanical, and Barrier Properties", Energy Procedia, 2014, 56, 201-210. https://doi.org/10.1016/j.egypro.2014.07.150
  7. P. Choudhary, S. Mohanty, S. K. Nayak, and L. Unnikrishnan, "Poly(L-lactide)/polypropylene Blends: Evaluation of Mechanical, Thermal, and Morphological Characteristics", J. Appl. Polym. Sci., 2011, 121, 3223-3237. https://doi.org/10.1002/app.33866
  8. G. Zhang, J. Zhang, S. Wang, and D. Shen, "Miscibility and Phase Structure of Binary Blends of Polylactide and Poly(methyl methacrylate)", J. Polym. Sci. Part B: Polym. Phys., 2003, 41, 23-30. https://doi.org/10.1002/polb.10353
  9. C. Samuel, J. M. Raquez, and P. Dubois, "PLLA/PMMA Blends: A Shear-induced Miscibility with Tunable Morphologies and Properties?", Polymer, 2013, 54, 3931-3939. https://doi.org/10.1016/j.polymer.2013.05.021
  10. D. Cossement, R. Gouttebaron, V. Cornet, P. Viville, M. Hecq, and R. Lazzaroni, "PLA-PMMA Blends: A Study by XPS and OoF-SIMS", Appl. Surface Sci., 2006, 252, 6636-6639. https://doi.org/10.1016/j.apsusc.2006.02.225
  11. W. Liangyan, J. Xiabin, C. Haibo, H. Xiuli, Y. Lixin, and H, Yubin, "Blends of Linear and Long-chain Branched Poly(Llactide) s with High Melt Strength and Fast Crystallization Rate", Ind. Eng. Chem. Res., 2012, 51, 10088-10099. https://doi.org/10.1021/ie300526u
  12. J. Long, L. Bo, and Z. Jiwen, "Properties of Poly(lactic acid)/poly(butylene adipate-co-terephthalate)/nanoparticle Ternary Composites", Ind. Eng. Chem. Res., 2009, 48, 7592-7602.
  13. J. H. Cha, S. J. Ann, and H. Y Jeon, "Analysis of Dynamic and Creep Behaviors of PLA Blends with Blending Ratio", Polymer (Korea), 2015, 39, 556-571.
  14. A. Teamsinsungvon, Y. Rusakulpiwat, and K. Jurukumjorn, "Mechanical and Morphological Properties of Poly(lactic acid)/poly(butylene adipate-co-terephthalate)/Calcium Carbonate Composite", 18th International Conference on Composite Materials, Edinburgh, Scotland, 2009.
  15. Y. S. Choi and H. Y. Jeon, "Analysis of Morphology and Viscoelastic Behavior of LCP/PET Blends by Repeated Extrusion", Polymer(Korea), 2015, 39, 475-479.