DOI QR코드

DOI QR Code

Room-temperature synthesis of cobalt nanoparticles and their use as catalysts for Methylene Blue and Rhodamine-B dye degradation

  • 투고 : 2015.03.07
  • 심사 : 2015.06.30
  • 발행 : 2015.06.25

초록

Air stable nanoparticles were prepared from cobalt sulphate using tetra butyl ammonium bromide as surfactant and sodium borohydride as reductant at room temperature. The cobalt nanocolloids in aqueous medium were found to be efficient catalysts for the degradation of toxic organic dyes. Our present study involves degradation of Methylene Blue and Rhodamine-B using cobalt nanoparticles and easy recovery of the catalyst from the system. The recovered nanoparticles could be recycled several times without loss of catalytic activity. Palladium nanoparticles prepared from palladium chloride and the same surfactant were found to degrade the organic dyes effectively but lose their catalytic activity after recovery. The cause of dye colour discharge by nanocolloids has been assigned based on our experimental findings.

키워드

참고문헌

  1. Arslan, I. (2001), "Treatability of a simulated disperse dye-bath by ferrous iron coagulation, ozonation, and ferrous iron-catalyzed ozonation", J. Hazard. Mater., 85, 229-241. https://doi.org/10.1016/S0304-3894(01)00232-1
  2. Arslan, I., Balcioglu, I.A. and Bahnemann, D.W. (2000), "Heterogeneous photocatalytic treatment of simulated dyehouse effluents using novel $TiO_2$-photocatalysts", Appl. Catal. B:Environ., 26, 193-206. https://doi.org/10.1016/S0926-3373(00)00117-X
  3. Cao, F., Deng, R.P., Tang, J.K., Song, S.Y., Lei, Y.Q. and Zhang, H.J. (2011),"Cobalt and Nickel with various morphologies: mineralizer-assisted synthesis, formation mechanism, and magnetic properties", Cryst. Eng. Comm., 13, 223-229. https://doi.org/10.1039/C0CE00074D
  4. CaO, Y.B., Zhang, X., Fan, J.M., Hu, P., Bai, L.Y., Zhang, H.B., Yuan, F.L. and Chen, Y.F. (2011), "Synthesis of Hierarchical Co micro/nano-composites with hexagonal plate and polyhedron shapes and their catalytic activities in Glycerol hydrogenolysis", Cryst. Growth Des., 11, 472-479. https://doi.org/10.1021/cg101254k
  5. Dakhlaoui, A., Smiri, L.S., Babadjiam, G., Schoenstein, F., Molinie, P. and Jouini, N. (2008), "Controlled elaboration and magnetic properties of submicrometric cobalt fiers", J. Phys. Chem. C, 112, 14348-14354. https://doi.org/10.1021/jp804461s
  6. Dutta, A.K., Maji, S.K. and Adhikary, B. (2014), "$Fe_2O_3$ nanoparticles: An easily recoverable effective photo-catalyst for the degradation of rose Bengal and methylene blue dyes in the waste-water treatment plant", Mater. Res. Bull., 49, 28-34. https://doi.org/10.1016/j.materresbull.2013.08.024
  7. Fan, J., Guo, Y., Wang, J. and Fan, M.H. (2009), "Rapid decolorization of azo dye methyl orange in aqueous solution by nanoscale zerovalent iron particles", J. Hazard. Mater., 166, 904-910. https://doi.org/10.1016/j.jhazmat.2008.11.091
  8. Guo, L., Liang, F., Wen, X.G., Yang, S.H., He, L., Zheng, W.Z., Chen, C.P. and Zhong, Q.P. (2007), "Uniform Magnetic chains of hollow cobalt mesospheres from one-pot synthesis and their assembly in solution", Adv. Funct. Mater., 17, 425-430. https://doi.org/10.1002/adfm.200600415
  9. Jana, N.R., Sau, T.K. and Pal, T. (1999), "Growing small silver particles as redox catalyst", J. Phys. Chem. B, 103, 115-121. https://doi.org/10.1021/jp982731f
  10. Kalwar, N.H., Sirajuddin, Soomro, R.A., Sherazi, S.T.H., Hallam, K.R. and Khaskheli, A.R. (2014), "Synthesis and characterization of highly efficient nickel nanocatalysts and their use in degradation of organic dyes", Internat. J. Metals, 20, 10-14.
  11. Kojima, Y., Suzuki, K.I., Fukumoto, K., Sasaki, M., Yamamoto, T., Kawai, Y. and Hayashi, H. (2002), "Hydrogen generation using sodium borohydride solution and metal catalysts coated on metal oxide", Int. J. Hyd. Eng., 27, 1029-1034. https://doi.org/10.1016/S0360-3199(02)00014-9
  12. Kositzi, M., Antoniadis, A., Poulios, I., Kiridis, I. and Malato, S. (2004), "Solar photocatalytic treatment of simulated dyestuff effluents", Sol. Energy, 77, 591-600. https://doi.org/10.1016/j.solener.2004.04.018
  13. Liang, X.M. and Zhao, L.J. (2012), "Room temperature synthesis of air-stable cobalt nanoparticles and their highly efficient adsorption ability for Congo red", RSC Adv., 2, 5485-5487. https://doi.org/10.1039/c2ra20240a
  14. Liu, C.Y., Jiang, Z.J. and Sun, L.W. (2005),"Catalytic properties of silver nanoparticles supported on silica spheres", J. Phys. Chem. B, 109, 1730-1735. https://doi.org/10.1021/jp046032g
  15. Liu, S.H., Gao, H.T., Ye, E.Y., Low, M., Lim, S., Zhang, S.Y., Lieu, X.H., Tripathy, S., Tremel, W. and Han, M.Y. (2010), "Graphitically encapsulated cobalt nanocrystal assemblies", Chem. Commun., 46, 4749-4751. https://doi.org/10.1039/c0cc00242a
  16. Mondal, A., Das, A., Adhikhari, B. and Mukherjee, D.K. (2014), "Palladium nanoparticles in ionic liquids: reusable catalysts for aerobic oxidation of alcohols", J. Nanopart. Res., 16, 1-10.
  17. Mondal, A., Adhikhari, B. and Mukherjee, D.K. (2015), "Room temperature synthesis of air stable Cobalt nanoparticles and their use as catalyst for Methyl Orange dye degradation", Coll. Surf. A: Physiochem. Eng. Aspect., 482, 248-257. https://doi.org/10.1016/j.colsurfa.2015.05.011
  18. Patil, S.S. and Shinde, V.M. (1988), "Biodegradation studies of aniline and nitrobenzene in aniline plant waste water by gas chromatograph", Environ. Sci. Technol., 22, 1160-1165. https://doi.org/10.1021/es00175a005
  19. Sanchez-Martin, J., Gonzalez-Velasco, M., Beltran-Heredia,J., Gragera-Carvajal, J. and Salguero-Fernandez, J. (2010), "Novel tannin-based adsorption in removing cationic dye (Methylene Blue) from aqueous solution. Kinetics and equilibrium studies", J. Hazard. Mater., 172, 9-16.
  20. Sauer, T., Neto, G.C., Jose, H.J. and Moreira, R.F.P.M. (2002), "Kinetics of Photocatalytic degradation of a reactive dye in a $TiO_2$ slurry reactor", J. Photochem. Photobiol. A: Chem., 149,147-154. https://doi.org/10.1016/S1010-6030(02)00015-1
  21. Shao, M.W., Wang, F.X., Cheng, L., Chen, D.Y., Fu, Y. and Ma, D. (2009), "Si/Pd nanostructure with high catalytic activity in degradation of eosin Y", Mater. Res. Bull., 44, 126-129. https://doi.org/10.1016/j.materresbull.2008.03.024
  22. Shih, Y.H., Tso, C.P. and Tung, L.Y. (2010), "Rapid degradation of methyl orange with nanoscale zerovalent iron particles", J Environ. Eng. Manag., 20, 137-143.
  23. Soomro, R.A., Sherazi, S.T.H., Sirajuddin, Memon, N., Shah, M.R., Kalwar, N.H., Hallam, K.R. and Shah, A. (2014),"Synthesis of air stable copper nanoparticles and their use in catalysis", Adv. Mat. Lett., 5, 191-198. https://doi.org/10.5185/amlett.2013.8541
  24. Wang, X., Yuan, F.L., Hu, P., Hu, L.J. and Bai, L.Y. (2008),"Self assembled growth of hollow spheres with octahedron-like Co nanocrystals via one-pot solution fabrication", J. Phys. Chem. C, 112, 8773-8778. https://doi.org/10.1021/jp0775404
  25. Xia, L.X., Zhao, H., Liu, G., Hu, X., Liu, Y., Li, J., Yang, D. and Wang, X. (2011), "Degradation of dyes using hollow copper microspheres as catalyst", Coll. Surf. A: Physiochem. Eng. Aspect., 384, 358-362. https://doi.org/10.1016/j.colsurfa.2011.04.016
  26. Zhang, P., An, Q., Guo, J. and Wang, C.C. (2013), "Synthesis of mesoporous magnetic Co-NPS/carbon nanocomposites and their adsorption property for methyl orange from aqueous solution", J. Coll. Interf. Sci., 389, 10-15. https://doi.org/10.1016/j.jcis.2012.08.022
  27. Zhang, W., Hu, H., Shao, M.W., Lu, L., Wang, H. and Wang, S. (2007), "Synthesis of layer deposited silicon nanowires, modification with Pd nanoparticles, and their excellent catalytic activity and stability in the reduction of methylene blue", J. Phys. Chem. C, 111, 3467-3470. https://doi.org/10.1021/jp066440f

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